Abstract
A series of Triton X-100 (TX-100) reverse micelles was prepared in isooctane and characterized with respect to size, polarity, and electric conductivity. Three typical azo dyes including methyl orange (MO), Acid Black 234 (AB 234) and Reactive Red 195 (RR 195) were selected and solubilized in the water phase to investigate their interaction with TX-100 reverse micelles. Effect of water content on the spectra of these dyes in the micelles was also examined. It has been revealed from the experimental results that at low water content, MO and AB 234 may be located in the polar core but outside the water pool of the micelles. Increasing water content leads to their gradual movement towards the water pools. AB 234 may bind to the micelles more closely than MO, especially at high water content. Moreover, the stronger interaction between RR 195 and TX-100 result in the complex formation. Higher water content enhances the transition from bound RR 195 to free RR 195. It can be concluded that the spectral characteristics of the three dyes in the micelles are very different owing to the space limitation and the polarity evolution of the microenvironment of the micelles.
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Liu D, Ma J, Cheng H, Zhao Z (1998) Colloids Surf A 135:157
De TK, Maitra A (1995) Adv Colloid Interf Sci 59:95
Dhar S, Rana DK, Sarkar A, Mandal TK, Ghosh S, Bhattacharya SC (2009) Colloids Surf A 349:117
Jaramillo N, Paucar C, García C (2014) J Mater Sci 49:3400
Sawada K, Ueda M (2003) Dyes Pigments 58:37
Sawada K, Ueda M (2003) Dyes Pigments 58:99
Sawada K, Ueda M (2003) Color Technol 119:182
Sawada K, Ueda M, Kajiwara K (2004) Dyes Pigments 63:251
Ueda M, Kimura A, Wakida T, Yoshimura Y, Schelly ZA (1994) J Colloid Interface Sci 163:515
Sawada K, Ueda M (2004) J Chem Technol Biotechnol 79:376
Sawada K, Ueda M (2004) J Chem Technol Biotechnol 79:369
Kumar C, Balasubramanian D (1979) J Colloid Interface Sci 69:271
Kumar C, Balasubramanian D (1980) J Colloid Interface Sci 74:64
Kumar C, Balasubramanian D (1980) J Phys Chem 84:1895
Zhu DM, Feng KI, Schelly ZA (1992) J Phys Chem 96:2382
Das SK, Ganguly BN (1997) J Colloid Interface Sci 192:184
Qi L, Ma J (1998) J Colloid Interface Sci 197:36
Das D, Nath DN (2007) J Phys Chem B 111:11009
Dutta RK, Bhat SN (1996) Colloids Surf A 106:127
Mukhopadhyay M, Varma CS, Bhowmik BB (1990) Colloid Polym Sci 268:447
Bhowmik BB, Mukhopadhyay M (1998) Colloid Polym Sci 266:672
Perkins WS (2004) Beijing: China Textile Press.
Yi SX, Dong YC, Li B, Ding ZZ, Huang XB, Xue LX (2012) Color Technol 128:306–314
Zhu DM, Schelly ZA (1992) Langmuir 8:48
Zhu DM, Wu X, Schelly ZA (1992) J Phys Chem 96:7121
Kinugasa T, Kondo A, Nishimura S, Miyauchi Y, Nishii Y, Watanabe K, Takeuchi H (2002) Colloids and Surf A 204:193
Naoe K, Nishino M, Ohsa T, Kawagoe M, Imai M (1999) J Chem Technol Biotechnol 74:221
Naoe K, Ura O, Hattori M, Imai M (1998) Biochem Eng J 2:113
Yoshida T, Okabayashi H, Takahashi K, Ueda I (1984) Biochim Biophys Acta 772:102
Eicke HF, Borkovec M, Das-Gupta B (1989) J Phys Chem 93:314
Giustini M, Palazzo G, Colafemmina G, Monica MD, Giomini M, Ceglie A (1996) J Phys Chem 100:3190
Feldman Y, Kozlovich N, Nir I, Garti N, Archipov V. Idiyatullin Z. Zuev Y. Fedotov V (1996) J Phys Chem 100: 3745.
Maitra A, Mathew C, Varshney M (1990) J Phys Chem 94:5290
Hou MJ, Kim M, Shah DO (1988) J Colloid Interface Sci 123:398
Zhang Z, Liu C (2000) J Photochem Photobiol A 130(2):139
Pramanick D, Mukherjee D (1993) J Colloid Interface Sci 157:131
Sahoo D, Chakravorti S (2009) J Photochem Photobiol A 205:129
Sengupta B, Guharay J, Sengupta PK (2000) Spectrochim Acta Part A 56:1433
Zang L, Liu CY, Ren XM (1995) J Photochem Photobiol A 88:47
Acknowledgments
The authors thank the Tianjin Municipal Science and Technology Committee for a Science and Technology Support Key Project Plan (09ZCKFSH02000). This research was also supported by Zhejiang Province Science and Technology Program Foundation (2007C16033).
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Li, B., Dong, Y., Wang, P. et al. Visible and fluorescence spectroscopic studies on interaction of water-soluble anionic azo dyes with Triton X-100 in reverse micelle media. Colloid Polym Sci 293, 3033–3041 (2015). https://doi.org/10.1007/s00396-015-3696-3
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DOI: https://doi.org/10.1007/s00396-015-3696-3