Facile preparation of α-Fe2O3/carbon and polyhydroxy iron cation/polyaniline hollow particles

Abstract

By virtue of a smartly designed strategy, we successfully prepared the α-Fe2O3/carbon and electromagnetic polyhydroxy iron cation/polyaniline (PIC/PANi) hollow particles. First, poly(styrene-butyl acrylate)/polyhydroxy iron cation (P(S-BA)/PIC) composite particles were prepared based on electrostatic attraction between the P(S-BA) and PIC. Second, the coating of P(S-BA)/PIC composite particles with PANi was achieved by the “Swelling–Diffusion–Interfacial-Polymerization Method”. Finally, α-Fe2O3/carbon and PIC/PANi hollow particles were obtained by calcination or solvent extraction of the P(S-BA)/PIC/PANi composite particles, respectively. The whole preparation process was monitored by transmission electron microscope, scanning electron microscope, Fourier transform infrared, and X-ray diffraction. The synthesized α-Fe2O3/carbon and PIC/PANi hollow particles possessed of a narrow size distribution and well-defined morphology.

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Acknowledgments

This work was supported by the Fundamental Research Funds for the Central Universities (JUSRP111A05) and National Natural Science Foundation of China (nos. 21204030, 51133002).

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Correspondence to Yunxing Li or Zhaoqun Wang.

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Li, Y., Zhao, Z., Wang, C. et al. Facile preparation of α-Fe2O3/carbon and polyhydroxy iron cation/polyaniline hollow particles. Colloid Polym Sci 291, 1287–1291 (2013). https://doi.org/10.1007/s00396-012-2857-x

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Keywords

  • Hollow particle
  • Polyaniline
  • α-Fe2O3
  • Polyhydroxy iron cation
  • Interfacial polymerization