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Annealing-induced rheological and electric resistance variations in carbon black-filled polymer melts

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Abstract

Annealing-induced viscoelastic and electric conduction variations were traced by simultaneous measurement of resistance and dynamic modulus to carbon black (CB)-filled high-density polyethylene, polystyrene, and polypropylene at elevated temperatures. The resistance decay during annealing the melts is closely related to terminal relaxation of polymer chains and the temperature-mediated interfacial tension between CB and the matrix. On the other hand, a time–temperature–concentration superposition principle was disclosed to evolution of dynamic modulus for the filled melts at different temperatures and CB volume fractions. Annealing the filled melts causes a liquid-to-solid-like transition and the differences in kinetic constant for evolution of dynamic modulus among the three systems at the same condition are involved in interfacial tension.

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Acknowledgments

This research was funded by the National Natural Science Foundation of China (no. 51073136) and the Fundamental Research Funds for the Central Universities of China (no. 2011QNA4031).

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Authors and Affiliations

  1. MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, China

    Yihu Song, Qing Cao & Qiang Zheng

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  1. Yihu Song
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  2. Qing Cao
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  3. Qiang Zheng
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Correspondence to Yihu Song.

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Song, Y., Cao, Q. & Zheng, Q. Annealing-induced rheological and electric resistance variations in carbon black-filled polymer melts. Colloid Polym Sci 290, 1837–1842 (2012). https://doi.org/10.1007/s00396-012-2804-x

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  • DOI: https://doi.org/10.1007/s00396-012-2804-x

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