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Synthesis of novel polyarylate with elecrooptical chromophores as side chain as electro-optic host polymer

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Abstract

Two novel soluble polyarylates with different nonlinear optical chromophores as the side chains were prepared and characterized by UV–visible spectra, nuclear magnetic resonance, and infrared spectroscopy. The titled polymers show us good thermal stability; the thermal decomposition temperature values were 201 and 253 °C, respectively, for polymer sPAR-CTCF and sPAR-CTCP. The glass transition temperatures were 139 and 122 °C for sPAR-CTCF and sPAR-CTCP, respectively. Chromophore FTC-wl was doped in these polymers as a guest chromophore to form binary chromophore electro-optic (EO) system. And super large EO coefficients (124 pm/V) were found from FTC-wl-doped sPAR-CTCP binary chromophore system at high chromophore loading density.

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Acknowledgments

We are grateful to the Directional Program of the Chinese Academy of Sciences (KJCX2.YW.H02), Innovation Fund of Chinese Academy of Sciences (CXJJ-11-M035), and National Natural Science Foundation of China (nos. 11104284 and 61101054) for financial support.

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Authors and Affiliations

  1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, People’s Republic of China

    Jialei Liu, Liang Wang, Zhen Zhen & Xinhou Liu

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  1. Jialei Liu
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  2. Liang Wang
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  3. Zhen Zhen
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  4. Xinhou Liu
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Correspondence to Jialei Liu.

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Liu, J., Wang, L., Zhen, Z. et al. Synthesis of novel polyarylate with elecrooptical chromophores as side chain as electro-optic host polymer. Colloid Polym Sci 290, 1215–1220 (2012). https://doi.org/10.1007/s00396-012-2695-x

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  • DOI: https://doi.org/10.1007/s00396-012-2695-x

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