Colloid and Polymer Science

, Volume 291, Issue 1, pp 143–156 | Cite as

Design and analysis of the homogeneous and heterogeneous distribution of water confined within colloidal polymer particles

Original Contribution


Water is known to distribute within polymeric films in multiple states differentiable by the energy of association. Potentiometric swelling of carboxylated latex samples and subsequent differential scanning calorimetry (DSC) and thermogravimetric analysis verified this distribution of water, specifically confined within colloidal nanoparticle dimensions. DSC cooling curves can delineate between the freezable bound and freezable unbound water at low total water content but become difficult to distinguish the freezable bound contribution at high total water content. Of note is that the ratio of weakly bound water in the secondary layer to the water strongly hydrogen-bound to the polymer is approximately constant regardless of carboxylic acid type and, in fact, is greater for the case of the hydrophobic base polymer. Aside from its distribution within the particles, the total water content also appeared to be more related to the hydroplasticized glass point of the polymer colloid as opposed to the polarity of the polymer.


Polymer colloid Bound water Freezing point depression Latex Water cluster DSC TGA 


  1. 1.
    Andronikashvili EL, Mrevlishvili GM, Japaridze GS, Sokhadze VM, Kvadze KA (1976) Biopolymers 15:1991–2004CrossRefGoogle Scholar
  2. 2.
    Froix MF, Nelson R (1975) Macromolecules 8:726–730CrossRefGoogle Scholar
  3. 3.
    Nomura S, Hiltner A, Lando JB, Baer E (1977) Biopolymers 16(2):231–246Google Scholar
  4. 4.
    Preston JM, Tawde GP (1956) J Textile Inst 47:T154–T165Google Scholar
  5. 5.
    Magne FC, Portas HJ, Wakeham H (1947) J Amer Chem Soc 69:1896–1902CrossRefGoogle Scholar
  6. 6.
    Magne FC, Skau EL (1952) Text Res J 22:748–756CrossRefGoogle Scholar
  7. 7.
    Nakamura K, Hatakeyama T, Hatakeyama H (1981) Text Res J 51(9):607–613CrossRefGoogle Scholar
  8. 8.
    Hatakeyama T, Tanaka M, Kishi A, Hatakeyama H (2012) Thermochim Acta 532(20):159–163CrossRefGoogle Scholar
  9. 9.
    Lueng HK, Steinberg MP (1979) J Food Sci 44(4):1212–1216CrossRefGoogle Scholar
  10. 10.
    Pham QT (1987) J Food Sci 52(1):210–212CrossRefGoogle Scholar
  11. 11.
    Liu WG, Yao KD (2001) Polymer 42:3943–3947CrossRefGoogle Scholar
  12. 12.
    Barrie JA (1968) In: Crank J, Park GS (eds) “Diffusion in Polymers”, Academic Press, London and New York, Chapter 8Google Scholar
  13. 13.
    Barrie JA (1990) In: van Krevelen D (ed) “Properties of Polymers”, 3rd edn. Elsevier, Amsterdam, p 572Google Scholar
  14. 14.
    Tsavalas JG, Sundberg DC (2010) Langmuir 26(10):6960–6966CrossRefGoogle Scholar
  15. 15.
    Jiang B, Tsavalas JG, Sundberg DC (2010) Langmuir 26(12):9408–9415CrossRefGoogle Scholar
  16. 16.
    Ping ZH, Nguyen QT, Chen SM, Zhou JQ, Ding YD (2001) Polymer 42:8461–8467CrossRefGoogle Scholar
  17. 17.
    Zimm BH, Lundberg JL (1956) J Physical Chemistry 60:425–428CrossRefGoogle Scholar
  18. 18.
    Okubo M, Ito A, Okada M, Suzuki T (2002) Colloid Polym Sci 280:574–578CrossRefGoogle Scholar
  19. 19.
    Blair HE, Johnson GE, Merriweather R (1978) J Appl Phys 49:4976–4984CrossRefGoogle Scholar
  20. 20.
    Johnson GE, Blair HE, Matsuoka S, Anderson EW, Scott JE (1980) ACS Symp Ser 127:451–468CrossRefGoogle Scholar
  21. 21.
    Cho JK, Meng Z, Lyon A, Breedveld V (2008) AIP Conference Proceedings 1027(1):1156–1158CrossRefGoogle Scholar
  22. 22.
    Brown GL (1980) ACS Symp Ser 127:441–450CrossRefGoogle Scholar
  23. 23.
    Lee DI, Chen FB (2007) J Coat Technol Res 4(2):161–165CrossRefGoogle Scholar
  24. 24.
    Hatakeyama T, Nakamura K, Hatakeyama H (1988) Thermochim Acta 123:153–161CrossRefGoogle Scholar
  25. 25.
    Higuchi A, Iijima T (1985) Polymer 26, p 1207–1211 and p 1833–1837Google Scholar
  26. 26.
    Rodriguez O, Fornasiero F, Arce A, Radke CJ, Prausnitz JM (2003) Polymer 44:6323–6333CrossRefGoogle Scholar

Copyright information

© Springer-Verlag 2012

Authors and Affiliations

  • Yuxi Lei
    • 1
  • Jessica R. Child
    • 1
  • John G. Tsavalas
    • 1
  1. 1.Nanostructured Polymers Research Center, Materials Science ProgramUniversity of New HampshireDurhamUSA

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