Skip to main content
SpringerLink
Log in

Formation of polymer–colloid complexes of aluminoxane particles with poly(acrylic acid) and its copolymers with acrylamide

  • Original Contribution
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Formation of polymer–colloid complexes formed by positively charged aluminoxane particles with a size of ~4.6 nm, which constitute the main part of the dispersed phase in aluminum polyhydroxychloride sols with poly(acrylic acid) and acrylic acid copolymers with acrylamide, is studied. Conditions of preparing water-soluble polymer–colloid complexes are determined. It is shown that water-soluble polycomplexes are obtained through the interaction of aluminoxane particles with acrylic acid–acrylamide copolymers containing no more than 0.8 mol% acrylic acid units. In the polymer–colloid complex, aluminoxane particles are uniformly distributed over polyelectrolyte macromolecules and the optimum composition is attained at the molar ratio of components Z equal to 1:1. In semidilute solutions, the addition of aluminoxane particles to the copolymer brings about formation of the gel featuring viscoelastic properties. For all copolymers, the maximally elastic properties of the gels are attained at Z ≈ 1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Laine RM, Sanchez C, Brinker CJ, Giannelis E (eds) (2000) Organic/inorganic hybrid materials, vol 628. Materials Research Society, Warrendale

  2. Shilov OL, Shilov VV (2003) Nanosystems, nanomaterials. Nanotechnologies 1:9

    Google Scholar 

  3. Ozerin SA, Zav’yalov SA, Chvalun SN (2001) Vysokomol Soedin Ser A 43:1993

    CAS  Google Scholar 

  4. Ivanchev SS, Mesh AM, Reikhel’t H, Khaikin S Ya, Nesse A, Myakin SV (2002) Vysokomol Soedin Ser A 44:996

    CAS  Google Scholar 

  5. Volkov AV, Moskvina MA, Zezin SB, Volynsky AL, Bakeev NF (2003) Vysokomol Soedin Ser A 45:283

    CAS  Google Scholar 

  6. Yu YY, Chen WCh (2003) Mater Chem Phys 82:388

    Article  CAS  Google Scholar 

  7. Alves de Rezende C, Lee L-T, Galembeck F (2008) Langmuir 24:7346

    Article  CAS  Google Scholar 

  8. Kontos AJ, Likodimos V, Stergiopoulos T, Tsouhleris DS, Falaras P (2009) Chem Mater 21:662

    Article  CAS  Google Scholar 

  9. Oren R, Liang Z, Board S, Warren SC, Wiener U, Huck WT (2009) J Am Chem Soc 131:1670

    Article  CAS  Google Scholar 

  10. Smith G, Bedrov D (2009) Langmuir 25:11239

    Article  CAS  Google Scholar 

  11. Karpushkin EA, Zezin SB, Zezin AV (2009) Vysokomol Soedin Ser A 51:329

    Google Scholar 

  12. Roman-Leshkov Y, Moliner M, Davis ME (2010) Chem Mater 22:2646

    Article  CAS  Google Scholar 

  13. Unger EL, Ripaud E, Lerichc Ph, Cravino A, Roncali J, Johansson E, Hagfeldt A, Boshloo GJ (2010) Phys Chem C 114:11659

    Article  CAS  Google Scholar 

  14. Gann JP, Yan M (2008) Langmuir 24:5319

    Article  CAS  Google Scholar 

  15. Poselt E, Fischer S, Foerster S, Weller H (2009) Langmuir 25:13906

    Article  CAS  Google Scholar 

  16. Chakraborty S, Bishnoi SW, Perez-Luna VHJ (2010) Phys Chem C 114:5947

    Article  CAS  Google Scholar 

  17. Hockel JC, Kisley LM, Mannion JM, Chumanov G (2009) Langmuir 17:9671

    Article  Google Scholar 

  18. Zafiropoulou J, Paragelis K, Boukos N, Siokou A, Niarchos D, Tzizios VJ (2010) Phys Chem C 114:7582

    Article  CAS  Google Scholar 

  19. Yuan J, Schacher F, Drechsier M, Hanich A, Lu Y, Ballauff M, Muller AM (2010) Chem Mater 22:2626

    Article  CAS  Google Scholar 

  20. Hong J, Stavis SW, DePaoli Lacerda SH, Locascio LE, Raghavan SR, Gaitan M (2010) Langmuir 26:11581

    Article  CAS  Google Scholar 

  21. Len GM (1995) Supramolecular chemistry. Concepts and perspectives. Weincheim, New York

    Book  Google Scholar 

  22. Sotiropolou M, Oberdisse J, Staikos G (2006) Macromolecules 39:3065

    Article  Google Scholar 

  23. Jayaraman A, Schweizer KS (2009) Macromolecules 42:8423

    Article  CAS  Google Scholar 

  24. Sedlak M, Konak C (2009) Macromolecules 42:7430

    Article  CAS  Google Scholar 

  25. Aulin C, Johansson E, Wagberg L, Lindstrom T (2010) Macromolecules 11:872

    CAS  Google Scholar 

  26. Novakov IA, Radchenko Ph S, Papisov IM (2003) Vysokomol Soedin Ser A 45:1340

    CAS  Google Scholar 

  27. Novakov IA, Radchenko Ph S, Pastukhov AS, Papisov IM (2005) Vysokomol Soedin Ser A 47:73

    CAS  Google Scholar 

  28. Novakov IA, Radchenko Ph S, Papisov IM (2007) Vysokomol Soedin Ser B 49:912

    CAS  Google Scholar 

  29. Papisov IM, Litmanovich AA (1999) Colloids Surf A 151:399

    Article  CAS  Google Scholar 

  30. Buchhammer H-M, Petzold G, Lunkwitz K (1999) Langmuir 15:4306

    Article  CAS  Google Scholar 

  31. Papisov IM, Bolyachevskaya KI, Litmanovich AA, Matveenko VN, Volochkova LL (1999) Eur Polym J 35:2087

    Article  CAS  Google Scholar 

  32. Radhakrichnan B, Ranjan R, Brittain WJ (2006) Soft Matter 2:386

    Article  Google Scholar 

  33. Baglioni P, Giorgi R (2006) Soft Matter 2:293

    Article  CAS  Google Scholar 

  34. Papisov IM, Bolyachevskaya KL, Litmanovich AA, Maveenko VN, Volchkova IL (1999) Eur Polym J 35:2087

    Article  CAS  Google Scholar 

  35. Gao J, Fu J, Lin C, Hang Y, Yu X, Pan C (2004) Longmuir 20:2775

    Google Scholar 

  36. Milanesi F, Cappelletti G, Annunziata R, Bionchi CL, Meroni D, Ardizzone SJ (2010) Phys Chem 114:8287

    CAS  Google Scholar 

  37. Mori H, Muller HE, Klee JE (2003) J Am Chem Soc 125:3712

    Article  CAS  Google Scholar 

  38. Ermakova LN, Frolov, Yu G, Kasaikin VA, Zezin AB, Kabanov VA (1981) Vysokomol Soedin Ser 23:2341

    Google Scholar 

  39. Ermakova LN, Nuss PV, Kasaikin VA, Zezin AB, Kabanov VA (1983) Vysokomol Soedin Ser A 25:1391

    CAS  Google Scholar 

  40. Bucur C, Sui Z, Schlenoff J (2006) J Am Chem Soc 128:13690

    Article  CAS  Google Scholar 

  41. Frolov YuG, Shabanova NA, Leskin VV, Pavlov AN (1976) Kolloid Zh 38:1205

    CAS  Google Scholar 

  42. Kasaikin VA, Pavlova NV, Ermakova LN, Zezin AB, Kabanov VA (1986) Kolloid Zh 48:452

    CAS  Google Scholar 

  43. Kalyuzhnaya RI, Khul’chaev KhKh, Kasaikin VA, Zezin AB, Kabanov VA (1994) Vysokomol Soedin 36:257

    CAS  Google Scholar 

  44. Averchenko IA, Papisov IM, Matveenko VN (1993) Vysokomol Soedin Ser A 35:1986

    Google Scholar 

  45. Mason MR, Smith JM, Bott SG, Barron ARJ (1993) Am Chem Soc 145:4971

    Article  Google Scholar 

  46. Harlan CJ, Mason MR, Barron AR (1994) Organometallics 13:2957

    Article  CAS  Google Scholar 

  47. JPC B32 B5813 (2001) US Patent 6,322,890

  48. Wynne KY (1985) Inorg Chem 24:1339

    Article  CAS  Google Scholar 

  49. Gurian P, Cheatham LK, Ziller IW, Barron AR (1991) J Chem Soc Dalton Trans 1449

  50. Landry CC, Davis IA, Apblett AW, Barron ARJ (1993) Mater Chem 3:597

    Article  CAS  Google Scholar 

  51. Matievic E, Tezar BJ (1968) Phys Chem 79:91

    Google Scholar 

  52. Levitsky EA, Maksimov VN, Marchenko IYu (1961) Dokl Akad Nauk SSSR 41:865

    Google Scholar 

  53. Mesmeer RE, Baes M, Tehoubar D, Cases M, Fripiat JJ, Friesinger FJ (1987) Colloid Interface Sci 117:47

    Article  Google Scholar 

  54. Bottero JY, Axelos M, Tchoubar D, Cases IM, Fripiat JJ, Fiessinger FJ (1987) Colloid Interface Sci 117:47

    Article  CAS  Google Scholar 

  55. Wang D, Sun W, Xu Y, Tang H, Gregory I (2004) Colloids Surf. A 243:1

    CAS  Google Scholar 

  56. Chen Zh, Fan B, Peng X, Zhang Zh, Fan J, Luan Zh (2006) Chemosphere 64:912

    Article  CAS  Google Scholar 

  57. Novakov IA, Radchenko SS, Radchenko PhS (2004) Zh Prikl Khim (St Petersburg) 77:169

    Google Scholar 

  58. Novakov IA, Radchenko SS, Pastuchov AS, Radchenko PhS (2006) S Zh Prikl Khim (St Petersburg) 79:472

    Google Scholar 

  59. JPC C02F 1/58 (2006) RF Patent 228,182

  60. JPC C02F 1/58 (2007) RF Patent 2292309

  61. Novakov IA, Radchenko SS, Radchenko PhS, Ozerin AS, Karaulov AV (2008) Zh Prikl Khim (St Petersburg) 81:1389

    Google Scholar 

  62. JPC E21B 33/136 (2009) RF Patent 2,348,792

  63. Novakov IA, Radchenko FS, Ozerin AS, Rybakova EV (2009) Izv Volg Gos Tekh Univ, Ser Khim Khim Tekhnol 6:97, Volgograd

    Google Scholar 

  64. JPC C02F 1/58 (1997) RF Patent 2,083,495

  65. Kabanov VA et al (eds) (1977) Encyclopedia of polymers, vol 3. Sovetskaya Entsiklopediya, Moscow

  66. Brosset G, Biedewun G, Sillen LG (1954) Acta Chem Scand 8:19170

    Article  Google Scholar 

  67. Fripiat JJ, Van Canwelaert F, Basmans HJ (1965) Phys Chem 69:2458

    CAS  Google Scholar 

  68. Mesmer RE, Baes CF (1971) Inorg Chem 10:2290

    Article  CAS  Google Scholar 

  69. Furrer G, Ludwig Che, Schinder PWJ (1992) Colloid Interface Sci 149:56

    Article  CAS  Google Scholar 

  70. Zakharchenko SO, Litmanovich EA, Radchenko FS, Pastukhov AS, Zezin AB, Novakov IA, Kabanov VA (2006) Kolloidn Zh 68:467

    Google Scholar 

  71. Ozerin AS, Radchenko FS, Timofeeva GI, Novakov IA (2009) Ross Nanotekhnol 4:145

    Google Scholar 

  72. Svergun DI (1999) Biophys 76:2879

    Article  CAS  Google Scholar 

  73. Kabanov VA et al (eds) (1972) Encyclopedia of polymers, vol 1. Sovetskaya Entsiklopediya, Moscow

Download references

Author information

Authors and Affiliations

  1. Volgograd State Technical University, pr. Lenina 28, Volgograd, 400131, Russia

    Ivan A. Novakov, Philipp S. Radchenko, Aleksandr S. Ozerin, Elena V. Rybakova & Stanislav S. Radchenko

Authors
  1. Ivan A. Novakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Philipp S. Radchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Aleksandr S. Ozerin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Elena V. Rybakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Stanislav S. Radchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Stanislav S. Radchenko.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Novakov, I.A., Radchenko, P.S., Ozerin, A.S. et al. Formation of polymer–colloid complexes of aluminoxane particles with poly(acrylic acid) and its copolymers with acrylamide. Colloid Polym Sci 289, 1197–1203 (2011). https://doi.org/10.1007/s00396-011-2446-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-011-2446-4

Keywords

Search

Navigation