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Complexation behaviour of cellulose derivative/surfactant mixtures investigated by nonlinear enhanced Rayleigh scattering

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Abstract

Complexation behaviour of cellulose derivative/surfactant mixtures in aqueous solution was investigated by nonlinear enhanced Rayleigh scattering (NERS). The NERS spectra of polymer solutions, including second-order scattering, third-order scattering, frequency doubling scattering and triplet frequency scattering were created using by spectrofluorometer. The results indicated that NERS intensity of cellulose derivative/surfactant systems changes differently with continuing addition of surfactant due to the complexation between cellulose derivative and surfactant. The critical micelle concentration of cellulose derivatives/surfactants system is easy to obtain. The change of NERS intensity reveals the complexation behaviour of cellulose derivative/surfactant and the aggregation state of polymer chains in evidence. Therefore, NERS had been successfully developed to study complexation behaviour of cellulose derivative/surfactant mixtures in solution.

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Acknowledgment

The work was financially supported by the program of the Postdoctoral Foundation of Shanghai University and National Natural Science Foundation of China (grant no. 50673104).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Shanghai University, Shanghai, 200072, China

    Yunbo Li, Xiaoyan Zhang & Yubin Zhu

  2. School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, China

    Yunbo Li, Xudong Chen & Fangming Zhu

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  1. Yunbo Li
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  2. Xudong Chen
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  3. Xiaoyan Zhang
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  4. Fangming Zhu
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  5. Yubin Zhu
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Correspondence to Yunbo Li or Xudong Chen.

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Li, Y., Chen, X., Zhang, X. et al. Complexation behaviour of cellulose derivative/surfactant mixtures investigated by nonlinear enhanced Rayleigh scattering. Colloid Polym Sci 289, 767–774 (2011). https://doi.org/10.1007/s00396-011-2390-3

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  • DOI: https://doi.org/10.1007/s00396-011-2390-3

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