Skip to main content
SpringerLink
Log in

Dilational viscoelasticity of anionic polyelectrolyte/surfactant adsorption films at the water–octane interface

  • Original Contribution
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

In this article, the interfacial tension and interfacial dilational viscoelasticity of polystyrene sulfonate/surfactant adsorption films at the water–octane interface have been studied by spinning drop method and oscillating barriers method respectively. The experimental results show that different interfacial behaviors can be observed in different type of polyelectrolyte/surfactant systems. Polystyrene sulfonate sodium (PSS)/cationic surfactant hexadecanetrimethyl–ammonium bromide systems show the classical behavior of oppositely charged polyelectrolyte/surfactant systems and can be explained well by electrostatic interaction. In the case of PSS/anionic surfactant sodium dodecyl sulfate (SDS) systems, the coadsorption of PSS at interface through hydrophobic interaction with alkyl chain of SDS leads to the increase of interfacial tension and the decrease of dilational elasticity. For PSS/nonionic surfactant TX100 systems, PSS may form a sub-layer contiguous to the aqueous phase with partly hydrophobic polyoxyethylene chain of TX100, which has little effect on the TX100 adsorption film and interfacial tension.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Holmberg K, Jonsson B, Kronberg B, Lindman B (2003) Surfactants and polymers in aqueous solutions, 2nd edn. Wiley, Chichester

    Google Scholar 

  2. Goddard ED, Ananthapadmanabhan KP (1993) Interaction of surfactants with polymers and proteins. CRC, Boca Raton

    Google Scholar 

  3. Bhattacharyya A, Monroy F, Langevin D, Argillier JF (2000) Langmuir 16:8727

    Article  CAS  Google Scholar 

  4. Kwak JCT (1998) Polymer-surfactant systems (surfactant science series vol. 77). Marcel Dekker, New York

    Google Scholar 

  5. Morishima Y, Mizusaki M, Yoshida K, Dubin PL (1999) Colloids Surf A 147:149

    Article  CAS  Google Scholar 

  6. Goddard ED (1986) Colloids Surf 19:301

    Article  CAS  Google Scholar 

  7. Cabane B, Duplessix R (1985) Colloids Surf 13:19

    Article  CAS  Google Scholar 

  8. Takisawa N, Brown P, Bloor D, Hall DG, Wyn-Jones EJ (1989) Chem Soc Faraday Trans 85:2099

    Article  CAS  Google Scholar 

  9. Triener C, Nguyen D (1990) J Phys Chem 94:2021

    Article  Google Scholar 

  10. Goddard ED, Hannan RB (1976) J Colloid Interface Sci 55:73

    Article  CAS  Google Scholar 

  11. Piculell L, Lindman B (1992) Adv Colloid Interface Sci 41:149

    Article  CAS  Google Scholar 

  12. Bergeron V, Langevin D, Asnacios A (1996) Langmuir 12:1550

    Article  CAS  Google Scholar 

  13. Monteux C, Williams CE, Meunier J, Anthony O, Bergeron V (2004) Langmuir 20:57

    Article  CAS  Google Scholar 

  14. Dubin PL, Rigsbee DR, Gan LM, Fallon MA (1988) Macromolecules 21:2555

    Article  CAS  Google Scholar 

  15. Almgren M, Hansson P, Mukhtar E, van Stam J (1992) Langmuir 8:2405

    Article  CAS  Google Scholar 

  16. Thalberg K, van Stam J, Lindbald C, Almgren M, Lindman B (1991) J Phys Chem 95:8975

    Article  CAS  Google Scholar 

  17. Abuin EB, Scaiano JC (1984) J Am Chem Soc 106:6274

    Article  CAS  Google Scholar 

  18. Asnacios A, Langevin D, Argillier JF (1996) Macromolecules 29:7412

    Article  CAS  Google Scholar 

  19. Gorelov AV, Kudryashov ED, Jacquier JC, McLoughlin DM, Dawson KA (1998) Physica A 249:216

    Article  CAS  Google Scholar 

  20. Svensson A, Piculell L, Cabane B, Ilekti P (2002) J Phys Chem B 106:1013

    Article  CAS  Google Scholar 

  21. Hayakawa K, Kwak JCT (1982) J Phys Chem 86:3866

    Article  CAS  Google Scholar 

  22. Hayakawa K, Kwak JCT (1983) J Phys Chem 87:506

    Article  CAS  Google Scholar 

  23. Hayakawa K, Santerre KJCT (1983) Macromolecules 16:1642

    Article  CAS  Google Scholar 

  24. Hayakawa K, Kwak JCT (1984) J Phys Chem 88:1930

    Article  Google Scholar 

  25. Babak VG, Skotnikova EA, Lukina IG, Pelletier S, Hubert P, Dellacherie E (2000) J Colloid Interface Sci 225:505

    Article  CAS  Google Scholar 

  26. Stubenrauch C, Albouy PA, Rv K, Langevin D (2000) Langmuir 16:3206

    Article  CAS  Google Scholar 

  27. Avranas A, Iliou P (2003) J Colloid Interface Sci 258:102

    Article  CAS  Google Scholar 

  28. Penfold J, Taylor DJF, Thomas RK, Tucker I, Thompason LJ (2003) Langmiur 19:7740

    Article  CAS  Google Scholar 

  29. Noskov BA (1995) Colloid Polym Sci 273:263

    Article  CAS  Google Scholar 

  30. Wu D, Feng YJ, Xu GY, Chen YJ, Cao XL, Li YM (2007) Colloids Surf A 299:117

    Article  CAS  Google Scholar 

  31. Wu D, Xu GY, Feng YJ, Li YM (2007) Int J Biol Macromol 40:345

    Article  CAS  Google Scholar 

  32. Babak VG, Desbrieres J, Tikhonov VE (2005) Colloids Surf A 255:119

    Article  CAS  Google Scholar 

  33. Delgado C, Merchán MD, Velázquez MM (2008) J Phys Chem B 112:687

    Article  CAS  Google Scholar 

  34. Noskov BA, Loglio G, Miller R (2005) Mendeleev Commun 15:63

    Article  CAS  Google Scholar 

  35. Loglio G, Pandolfini P, Miller R, Makievski AV, Kragel J, Ravera F, Noskov BA (2005) Colloids Surf A 261:57

    Article  CAS  Google Scholar 

  36. Klebanau A, Kliabanova N, Ortega F, Monroy F, Rubio RG, Starov V (2005) J Phys Chem B 109:18316

    Article  CAS  Google Scholar 

  37. Noskov BA, Loglio G, Miller R (2004) J Phys Chem B 108:18615

    Article  CAS  Google Scholar 

  38. Monteux C, Fuller GG, Bergeron V (2004) J Phys Chem B 108:16473

    Article  CAS  Google Scholar 

  39. Lucassen J, Giles DJ (1975) Chem Soc Faraday Trans 71:217

    Article  CAS  Google Scholar 

  40. Lucassen J, Tempel MVD (1972) J Colloid Interface Sci 41:491

    Article  CAS  Google Scholar 

  41. SunTL ZhangL, Wang YY, Zhao S, Peng B, Li MY, Yu JY (2002) J Colloid Interface Sci 255:241

    Article  CAS  Google Scholar 

  42. Wang YY, Zhang L, Sun TL, Zhao S, Yu JY (2003) J Colloid Interface Sci 270:163

    Article  CAS  Google Scholar 

  43. Monteaux C, Williams CE, Bergeron V (2004) Langmuir 20:5367

    Article  CAS  Google Scholar 

  44. Babak VG, Desbrieres J (2006) Colloid and Polym Sci 284:745

    Article  CAS  Google Scholar 

  45. Babak VG, Baros F, Boury F, Desbrieres J (2008) Colloids Surf B 65:43

    Article  CAS  Google Scholar 

  46. Noskov BA, Akentiev AV, Bilibin AY, Zorin IM, Miller R (2003) Adv Colloid Interface Sci 104:245

    Article  CAS  Google Scholar 

  47. Wang YY, Dai YH, Zhang L, Luo L, Chu YP, Zhao S, Li MZ, Wang EJ, Yu JY (2004) Macromolecules 37:2930

    Article  CAS  Google Scholar 

Download references

Acknowledgment

The work was financially supported by the National Science & Technology Major Project (2008ZX05011) of China.

Author information

Authors and Affiliations

  1. Shengli Engineering and Consulting CO., LTD, Shengli Oilfield Company of SINOPEC, Dongying, 257000, Shandong, China

    Hong-Bo Fang

Authors
  1. Hong-Bo Fang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hong-Bo Fang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fang, HB. Dilational viscoelasticity of anionic polyelectrolyte/surfactant adsorption films at the water–octane interface. Colloid Polym Sci 287, 1131–1137 (2009). https://doi.org/10.1007/s00396-009-2070-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-009-2070-8

Keywords

Search

Navigation