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Synthesis of polyaspartate macromonomer having a vinyl end group and application to dispersion copolymerization of styrene

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Abstract

Sodium polyaspartate (PAspNa) macromonomer with an acryloyl end group was synthesized for dispersion polymerization. At first, a poly(succinimide) (PSI) derivative with a hydroxyphthalimide end group was synthesized by polycondensation of l-aspartic acid and 4-hydroxyphthalic acid. Then, the PSI derivative was end-capped with an acryloyl group by a reaction with acrlyloyl chloride. Finally, a PAspNa derivative with a vinyl end group was synthesized by a hydrolysis of succinimide units by sodium hydroxide. The synthesized macromonomer was applied as a polymerizable stabilizer in dispersion copolymerization of styrene in a mixture of ethanol and water. The PAspNa macromonomer acted as an effective stabilizer and gave sub-micron-sized polymeric particles in dispersion polymerization in polar medium.

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Authors and Affiliations

  1. Department of Material and Energy Science, Graduate School of Environmental Science, Okayama University, 3-1-1 Tsushima-Naka, Okayama, 700-8530, Japan

    Keisuke Tomita & Tsutomu Ono

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  1. Keisuke Tomita
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  2. Tsutomu Ono
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Correspondence to Tsutomu Ono.

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Tomita, K., Ono, T. Synthesis of polyaspartate macromonomer having a vinyl end group and application to dispersion copolymerization of styrene. Colloid Polym Sci 287, 109–113 (2009). https://doi.org/10.1007/s00396-008-1963-2

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  • DOI: https://doi.org/10.1007/s00396-008-1963-2

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