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Preparation and properties of fluoroalkyl end-capped vinyltrimethoxysilane oligomeric nanoparticles—A new approach to facile creation of a completely superhydrophobic coating surface with these nanoparticles

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Abstract

Novel fluoroalkyl end-capped vinyltrimethoxysilane oligomeric nanoparticles were prepared by the hydrolysis of the corresponding oligomer under alkaline conditions. The size of fluorinated nanoparticles thus obtained is of submicrometer levels and is not sensitive to the refractive indices of a variety of solvents; however, the turbidity of the dispersed fluorinated nanoparticles is extremely sensitive to the refractive indices of these solvents. In particular, the solvents of which the refractive indices are from 1.378 to 1.408 were found to afford the transparent colorless dispersed particle solutions. More interestingly, the modified glass surface treated with fluorinated nanoparticles exhibited a completely superhydrophobic characteristic (a water contact angle: 180°) with a nonwetting property against water droplets.

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References

  1. Sawada H (1996) Chem Rev 96:1779

    Article  CAS  Google Scholar 

  2. Sawada H (2003) J Fluorine Chem 121:111

    Article  CAS  Google Scholar 

  3. Sawada H (2007) Prog Polym Sci 32:509

    Article  CAS  Google Scholar 

  4. Sawada H (2007) Polym J 39:637

    Article  CAS  Google Scholar 

  5. Gomez-Romero P, Sanchez C (2004) In: Functional hybrid materials. Wiley-VCH, Weinheim

    Google Scholar 

  6. Ajayan PM, Schadler LS, Braun PV (2003) Nanocomposite science and technology. Wiley-VCH, Weinheim

    Google Scholar 

  7. Matejka L, Plestil J (1997) Macromol Symp 121:191

    Google Scholar 

  8. Juangvanich N, Maurite KA (1998) J Appl Polym Sci 67:1799

    Article  CAS  Google Scholar 

  9. Judeinstein P, Sanchez C (1996) J Mater Chem 6:511

    Article  CAS  Google Scholar 

  10. Sawada H, Narumi T, Kajiwara A, Ueno K, Hamazaki K (2006) Colloid Polym Sci 284:551

    Article  CAS  Google Scholar 

  11. Sawada H, Narumi T, Kodama S, Kamijo M, Ebara R, Sugiya M, Iwasaki Y (2006) Colloid Polym Sci 285:977

    Article  Google Scholar 

  12. Sawada H, Kakehi H, Koizumi M, Katoh Y, Miura M (2007) J Mater Soc 42:7147

    Article  CAS  Google Scholar 

  13. Sawada H, Tashima T, Kodama S (2008) Polym Adv Technol 19:739

    Article  CAS  Google Scholar 

  14. Sawada H, Nakayama M (1991) J Chem Soc Chem Commun 677

  15. Xie Q, Fan G, Zhao N, Guo X, Xu J, Dong J, Zhang L, Zhang Y, Han CC (2004) Adv Mater 16:1830

    Article  CAS  Google Scholar 

  16. Jin M, Feng X, Xi J, Zhai J, Cho K, Feng L, Jiang L (2005) Macrmol Rapid Commun 26:1805

    Article  CAS  Google Scholar 

  17. Li H, Wang X, Song Y, Liu Y, Li Q, Jiang L, Zhu D (2001) Angew Chem Int Ed 40:1743

    Article  CAS  Google Scholar 

  18. Jiang L, Zhao Y, Zhai J (2004) Angew Chem Int Ed 43:4338

    Article  CAS  Google Scholar 

  19. Yao Y, Dong X, Hong S, Ge H, Han CC (2006) Macrmol Rapid Commun 27:1627

    Article  CAS  Google Scholar 

  20. Tsougeni K, Tserepi A, Boulousis G, Constantoudis V, Gogolides E (2007) Plasma Process Polym 4:398

    Article  CAS  Google Scholar 

  21. Xie Q, Xu J, Feng L, Jiang L, Tang W, Luo X, Han CC (2004) Adv Mater 16:302

    Article  CAS  Google Scholar 

  22. Feng L, Zhang Z, Mai Z, Ma Y, liu B, Jiang L, Zhu D (2004) Angew Chem Int Ed 43:2012

    Article  CAS  Google Scholar 

  23. Laguardia L, Ricci D, Vassallo E, Cremona A, Mesto E, Greezzi F, Dellera F (2007) Macrmol Symp 247:295

    Article  CAS  Google Scholar 

  24. McHale G, Shirtcliffe NJ, Newton MI, Pyatt FB (2007) Hydrol Process 21:2229

    Article  CAS  Google Scholar 

  25. Liu B, He Y, Fan Y, Wang X (2006) Macrmol Rapid Commun 27:1859

    Article  CAS  Google Scholar 

  26. Feng L, Li S, Li Y, Li H, Zhang L, Zhai J, Song Y, Liu B, Jiang L, Zhu D (2002) Adv Mater 14:1857

    Article  CAS  Google Scholar 

  27. Chang K-C, Chen H, Huang C-K, Huang S-I (2007) J Appl Polym Sci 104:1646

    Article  CAS  Google Scholar 

  28. Onda T, Shibuichi S, Saitoh N, Tsujii K (1996) Langmuir 12:2125

    Article  CAS  Google Scholar 

  29. Shibuichi S, Yamamoto T, Onda T, Tsujii K (1998) J Colloid Interface Sci 208:287

    Article  CAS  Google Scholar 

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Acknowledgement

Thanks are due to Keyence Corp. for measurements of AFM.

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Correspondence to Hideo Sawada.

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Sawada, H., Suzuki, T., Takashima, H. et al. Preparation and properties of fluoroalkyl end-capped vinyltrimethoxysilane oligomeric nanoparticles—A new approach to facile creation of a completely superhydrophobic coating surface with these nanoparticles. Colloid Polym Sci 286, 1569–1574 (2008). https://doi.org/10.1007/s00396-008-1926-7

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  • DOI: https://doi.org/10.1007/s00396-008-1926-7

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