Abstract
Microcapsules are nowadays applied in a wide range of products including food, pharmaceuticals, and cosmetic formulations. Because of their pronounced viscoelastic properties, polymer microcapsules are able to undergo mechanical deformations when they are stimulated by external signals. The elongation of capsule membranes, up to bursting processes, is important for the controlled release of active ingredients under well-defined conditions. Their application as quick and reliable control release systems affords a detailed knowledge of their rheological and mechanical properties. The aims of our work were to prepare new types of magnetic switchable microcapsules and to investigate their deformation behavior in externally imposed magnetic fields. The magnetic sensitivity was achieved by encapsulating magnetic magnetite (Fe3O4) particles within a polyorganosiloxane capsule. We investigated the dynamic response of those capsule suspensions and single capsules to external magnetic forces where aggregation processes, rotational movements, and field-induced deformations in static or rotating fields were observed.
Similar content being viewed by others
References
Arshady R (1999) Microspheres and liposomes. Citus, London
Arshady R, Kono K (2006) Smart nanoparticles in nanomedicine. Kentus, London
Benton BF, Gardner DL (1983) Microcapsules: innovative, versatile product delivery, Columbus. Battelle Memorial Institute, Ohio
Chang TMS (1964) Science 149(364):524
Kugelmass IN, Charles CT (eds) (1972) Artificial cells, Springfield Ill: American Lecture Science
Franjione J, Vasishtha (1996) The art and science of microencapsulation, Technology Today
Kondo A, Van Valkenburg JW (1979) Microcapsule processing and technology. Marcel Dekker, New York
Kono K, Arshady R (2006) Smart nano and microparticles. Kentus, London
Madan PL (1978) Drug Cosmet Ind 122(6):47
Sliwka W (1975) Angew Chem Int Ed 14(8):539
Yao SJ, Cho MG (1998) Chin J Chem Eng 6(2):116
Pieper G, Rehage H, Barthès-Biesel D (1998) J Colloid Interface Sci 202:293
Dähne L, Peyratout CS (2004) Angew Chem 116:3850
Walter A, Rehage H, Leonhard H (2001) Colloids Surf, A Physicochem Eng Asp 183–185:123
Rehage H, Husmann M, Walter A (2002) Rheol Acta 41:292
Hirzinger G (1996) IEEE/ASME Trans Mechatron 1(2):149
Noritsugu T, Tanaka T (1997) IEEE/ASME Trans Mechatron 2(4):259
Barthès-Biesel D, Sgaier H (1985) J Fluid Mech 160:119
Walter A, Rehage H, Leonhard H (2000) Colloid Polym Sci 278:169
Mathiowitz E, Cohen MD (1989) J Membr Sci 40:27
Janssen LJJM, Nijenhuis K (1993) J Membr Sci 79:11
Husmann M, Rehage H, Dhenin E, Barthès-Biesel D (2005) J Colloid Interface Sci 282:109
Fowler CE, Khushalani D, Mann S (2001) J Mater Chem 11:1969
Wang H, Chen P, Zheng X (2004) J Mater Chem 14:1648
Fujiwara M, Shiokawa K, Tanaka Y, Nakahara Y (2004) Chem Mater 16:5420
Blandino A, Macias M, Cantero D (1999) J Biosci Bioeng 88(6):686
Shen F, Li AAH, Cornelius RM, Cirone P, Childs RF, Brash JL, Chang PL (2005) J Biomed Mater Res Part B Appl Biomater 75B(2):425
Dai C, Wang B, Zhao H (2005) Colloids Surf B: Biointerfaces 41:117
Sukhorukov GB, Fery A, Brumen M, Möhwald H (2004) Phys Chem Chem Phys 6:4078
Schneider G, Decher G (2004) Nano Lett 4(10):1833
Caruso F, Caruso RA, Möhwald H (1998) Science 282:1111
Decher G (1997) Science 277:1232
Dähne L (2003) In: Decher G, Schlenhoff JB (eds) Thin multilayer films. 1st edn. Wiley-VCH, Weinheim
Husmann M, Achenbach B, Rehage H (1999) In: Stokke BT, Elgsaeter A (eds) The Wiley polymer network review series. Wiley Chichester, Weinheim
Ulman A (1990) Adv Mater 2:573
Rehage H, Achenbach B, Klaerner FG (2002) Langmuir 18:7115
Lindén M, Slotte JP, Rosenholm JB (1996) Langmuir 12:4449
Bergeron V, Langevin D (1996) Macromolecules 29:306
Mark JE (2004) Acc Chem Res 37:946
Odenbach S (2005) Nachr Chem Tech Lab 53:297
Rosensweig RE (1997) Ferrohydrodynamics. Cambridge University Press, Cambridge
Jones TB (1995) Electromechanics of particles. Cambridge University Press, Cambridge
Rwei SP, Lee HY, Yoo SD, Wang LY, Lin JG (2005) Colloid Polym Sci 283:1253
Odenbach S (2001) Phys Unserer Zeit 32(3):122
Hähndel T, Nethe A, Stahlmann HD (2000) Forum der Forschung 10, BTU Cottbus, Eigenverlag: 53
Husmann M (2001) Dissertation. University of Essen, Germany
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the image is a link to a high resolution version.
Fig. S1
(GIF 113 kb)
Rights and permissions
About this article
Cite this article
Degen, P., Peschel, S. & Rehage, H. Stimulated aggregation, rotation, and deformation of magnetite-filled microcapsules in external magnetic fields. Colloid Polym Sci 286, 865–871 (2008). https://doi.org/10.1007/s00396-008-1841-y
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-008-1841-y