Skip to main content
SpringerLink
Log in

Melting behavior of lamellae of isotactic polypropylene studied using hot-stage atomic force microscopy

  • Original Contribution
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

The α- and β-form lamellae of isotactic polypropylene were developed at different temperatures. The melting behaviors of the lamellae were observed in real time at elevated temperatures using a hot-stage atomic force microscopy. The melting behavior of the α-form lamellae was determined by the lamellar defects. For the α-form lamellae developed at different undercoolings, the larger the undercoolings, the relatively higher amount of defect in the lamellae was observed. The lamellae with defects were melted into lamellar segments, and recrystallization took place during the heating process. The β-form lamellae had lower thermal stability, and they melted firstly and separately from that of α-form.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Keith HD, Padden FJ, Walter NM, Wyckoff HW (1959) J Appl Phys 30:1485

    Article  CAS  Google Scholar 

  2. Al-Raheil IA, Qudah AM, Al-Share M (1998) J Appl Polym Sci 67:1267

    Article  CAS  Google Scholar 

  3. Mezghani K, Campbell RA, Phillips PJ (1994) Macromolecules 27:997

    Article  CAS  Google Scholar 

  4. Yadav YS, Jain PC (1986) Polymer 27:721

    Article  CAS  Google Scholar 

  5. Janimak JJ, Cheng SZD, Zhang AQ (1992) Polymer 33:728

    Article  CAS  Google Scholar 

  6. Samules RJ (1975) J Appl Polym Sci 13:1417

    Google Scholar 

  7. Zhang FJ, Gong YM, He TB (2003) Eur Polym J 39:2315

    Article  CAS  Google Scholar 

  8. Weng J, Olley RH, Bassett DC, Jääskeläinen P (2002) J Macromol Sci Phys 41:891

    Article  Google Scholar 

  9. Weng J, Olley RH, Bassett DC, Jääskeläinen P (2003) J Polym Sci Polym Phys 41:2342

    Article  CAS  Google Scholar 

  10. Petraccone V, Guerra G, De Rosa C, Tuzi A (1985) Macromolecules 18:813

    Article  CAS  Google Scholar 

  11. Paukkeri R, Lehtinen A (1993) Polymer 34:4083

    Article  CAS  Google Scholar 

  12. De Rosa C, Guerra G, Napolitano R, Petraccone V, Pirozzi B (1984) Eur Polym J 20:937

    Article  Google Scholar 

  13. Guerra G, Petraccone V, Corradini P, De Rosa C, Napolitano R, Pirozzi B (1984) J Polym Sci Polym Phys 22:1029

    Article  CAS  Google Scholar 

  14. Corradi P, Napolitano R, Oliva L, Petraccone V (1982) Makromol Chem Rapid Commun 3:753

    Article  Google Scholar 

  15. Naiki M, Kikkawa T, Endo Y, Nozaki K, Yamamoto T, Hara T (2000) Polymer 42:5471

    Article  Google Scholar 

  16. Passingham C, Hendra PJ, Cudby MEA, Zichy V, Weller M (1990) Eur Polym J 26:631

    Article  CAS  Google Scholar 

  17. Norton DR, Keller A (1985) Polymer 26:704

    Article  CAS  Google Scholar 

  18. Dragaun H, Hubeny H, Muschik H (1977) J Polym Sci Polym Phys Ed 15:1779

    Article  CAS  Google Scholar 

  19. Lovinger AJ, Chua JD, Gryte LC (1977) J Polym Sci Polym Phys Ed 15:641

    Article  CAS  Google Scholar 

  20. Turner-Jones A, Cobbold AJ (1968) J Polym Sci 6:539

    Article  CAS  Google Scholar 

  21. Varga J (1992) J Mater Sci 27:2557

    Article  CAS  Google Scholar 

  22. Matheu C, Thierry JC, Wittmann JC, Lotz B (2002) J Polym Sci Polym Phys 40:2504

    Article  Google Scholar 

  23. Varga J (1986) J Therm Anal 31:165

    Article  CAS  Google Scholar 

  24. Varga J (1992) J Mater Sci 27:2557

    Article  CAS  Google Scholar 

  25. Godovsky YK, Magonov SN (2000) Langmuir 16:3549

    Article  CAS  Google Scholar 

  26. Winkel AK, Hobbs JK, Miles MJ (2000) Polymer 41:8791

    Article  CAS  Google Scholar 

  27. Zhou W, Cheng SZD, Putthanarat S, Eby RK, Reneker DH, Lotz B, Magonov S, Hsieh ET, Geerts RG, Palackal SJ, Hawley GR, Welch M (2000) Macromolecules 33:6861

    Article  CAS  Google Scholar 

  28. Jiang Y, Jin XG, Han CC, Li L, Wang Y, Chan CM (2003) Langmuir 19:8010

    Article  CAS  Google Scholar 

  29. Zhou JJ, Liu JG, Yan SK, Dong JY, Li L, Chan CM, Schultz JM (2005) Polymer 46:4077

    CAS  Google Scholar 

  30. Zhou JJ, Li L, Lu J (2006) Polymer 47:261–264

    Article  CAS  Google Scholar 

  31. Keller A, Cheng SZD (1998) Polymer 39:4461

    Article  Google Scholar 

  32. Cheng SZD, Keller A (1998) Annu Rev Mater Sci 28:533

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work is supported by the Outstanding Youth Fund and the National Science Foundation of China (grant nos. 20325414, 20574083, and 50521302). We also thank Professor Jerold M. Schultz for his constructive comments.

Author information

Author notes

  1. Xi Wang & Weimin Hou

    Present address: Graduate School of the Chinese Academy of Sciences, Beijing, China

Authors and Affiliations

  1. Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100080, China

    Xi Wang, Weimin Hou, Jianjun Zhou & Lin Li

  2. Department of Polymer Science and Materials, The School of Chemical Engineering, Dalian University of Technology, Dalian, 116012, China

    Yang Li

  3. Department of Chemical Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong, China

    Chi-Ming Chan

Authors
  1. Xi Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Weimin Hou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jianjun Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Lin Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yang Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Chi-Ming Chan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jianjun Zhou.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, X., Hou, W., Zhou, J. et al. Melting behavior of lamellae of isotactic polypropylene studied using hot-stage atomic force microscopy. Colloid Polym Sci 285, 449–455 (2007). https://doi.org/10.1007/s00396-006-1586-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-006-1586-4

Keywords

Search

Navigation