Skip to main content
SpringerLink
Log in

The synthesis of polyacrylamide nanoparticles in supercritical carbon dioxide

  • Short Communication
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Polyacrylamide nanoparticles, 50 to 200 nm, were created by inverse emulsion polymerization of acrylamide in supercritical carbon dioxide. The cross-linked polyacrylamide was produced by intermolecular imidization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

References

  1. Seymour KG, Harper BG (1965) Ger Pat 197:272

    Google Scholar 

  2. Gramain P, Myard PJ (1981) Colloids Interface Sci 84:114

    Article  CAS  Google Scholar 

  3. Mowry DT, Hendrick RM (1981) US Patent 2 625 472

  4. Bikales NM (ed) (1973) Water soluble polymers, vol 2. Plenum, New York

  5. Pye DJ (1963) US Patent 3 072 536

  6. Cyanamid (1969) Chemistry of acrylamide. American Cyanamid, New Jersey

    Google Scholar 

  7. Meltzer XL (1979) Water soluble polymers. Noyes Data, New Jersey

    Google Scholar 

  8. Schulz DN (1991) Water-soluble polymer synthesis: theory and practice in water soluble polymers. In: Shalaby SW, McCormick CL, Butler GB (eds) Water-soluble polymers. ACS, Washington, District of Columbia, pp 57–73

    Google Scholar 

  9. Beckman EJ, Smith RD (1989) Inverse emulsion polymerization of acrylamide in near-critical and supercritical continuous phases. In: Johnson KP, Penninger JML (eds) Supercritical fluid science and technology. ACS, Washington, District of Columbia, pp 184–206

    Google Scholar 

  10. Beckman EJ, Smith RD (1990) J Phys Chem 94:345

    Article  CAS  Google Scholar 

  11. Adamsky FA, Beckman EJ (1994) Macromolecules 27:312 (plus correction in Macromolecules 27:5238)

    Article  CAS  Google Scholar 

  12. Cooper AI, DeSimone JM (1996) Curr Opin Solid State Mater Sci 1:761

    Article  CAS  Google Scholar 

  13. Canelas DA, DeSimone JM (1997) Adv Polym Sci 133:103

    Article  CAS  Google Scholar 

  14. Young JL, DeSimone JM (2005) Macromolecules 38:4542

    Article  CAS  Google Scholar 

  15. Cooper AI, Hems WP, Holmes AB (1998) Macromol Rapid Commun 19:353

    Article  CAS  Google Scholar 

  16. Ni Y, Ge X (2001) Chem Lett 9:924

    Article  Google Scholar 

  17. Barton J (2002) Inverse microemulsion polymerization of oil-soluble monomers in the presence of hydrophilic polyacrylamide nanoparticles. In: Capek I (ed) Non-conventional polymer dispersion: 5th Bratislava Int. Conference on Polymers. Wiley, New York, pp 189–208

    Google Scholar 

  18. Honig DS (2005) Organic “microparticles”. In: Rodriguez JM (ed) Micro and nanoparticles in papermaking. TAPPI Publications, Atlanta, Georgia, pp 75–100

    Google Scholar 

  19. Bradford A, Reddy GR, McConville P, Hall DE, Chenevert TL, Kopelman RR, Philbert M, Weissleder R, Rehemtulla A, Ross BD (2003) Mol Imaging 2:324

    Article  Google Scholar 

  20. Xu Z, Wang CC, Yang WL, Deng YH, Fu SK (2004) J Magn Magn Mater 277:136

    Article  CAS  Google Scholar 

  21. Monson E, Brasuel M, Philbert MA, Kopelman R (2003) PEBBLE nanosensors for in vitro bioanalysis. In: Vo-Dinh T (ed) Biomedical photonics handbook. CRC Press, Boca Raton, Florida, pp 59–68

    Google Scholar 

  22. Brasuel M, Kopelman R, Philbert MA, Aylott JW, Clark HA, Kasman I, King M, Monson E, Sumner JP, Xu H, Hoover M, Miller TJ, Tjalkens R (2002) PEBBLE nanosensors in real time intercellular chemical imaging. In: Ligler R, Rowe-Tait C (eds) Optical biosensors: present and future. Elsevier, Amsterdam, pp 407–536

    Google Scholar 

  23. Clark HA, Barker SLR, Brasuel M, Miller MT, Monson E, Parus S, Shi Z-Y, Song A, Thorsrud B, Kopelman R, Ade A, Meixner W, Athey B, Hoyer M, Hill D, Lightle RM, Philbert MA (1998) Sens Actuators B Chem 51:12

    Article  Google Scholar 

  24. Clark HA, Hoyer M, Philbert MA, Kopelman R (1999) Anal Chem 71:4831

    Article  CAS  Google Scholar 

  25. Clark HA, Hoyer M, Parus S, Philbert M, Kopelman R (1999) Mikrochim Acta 131:121

    CAS  Google Scholar 

  26. Moreno MJ, Monson ER, Reddy RG, Rehemtulla A, Ross BD, Philbert M, Schneider RJ, Kopelman R (2003) Sens Actuators B Chem 90:82

    Article  CAS  Google Scholar 

  27. Tang W, Xu H, Kopelman R, Philbert M (2005) Photochem Photobiol 81(2):242

    Article  CAS  Google Scholar 

  28. Williams EF, Woodberry NT, Dixon JK (1957) Journal of Colloid Science 12:451

    Article  Google Scholar 

  29. Riggs JP, Rodriguez F (1967) J Polym Sci A1 5:3151

    Article  CAS  Google Scholar 

  30. Pohl K, Rodriguez F (1980) J Appl Polym Sci 26:611

    Article  Google Scholar 

  31. Ohde H, Rodriguez JM, Ye X-R, Wai CM (2000) Chem Commun, p 2353

  32. Smith RD, Watson DW, Fulton JL, Peterson RC (1987) Ind Eng Chem Res 26:2298

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Idaho, Moscow, ID, 83844, USA

    Hiroyuki Ohde & C. M. Wai

  2. Mississippi State Chemical Laboratory, Petroleum Prod. Div., Mississippi State University, P.O. Box CR, Mississippi, MS, 39762, USA

    Jose M. Rodriguez

Authors
  1. Hiroyuki Ohde
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. M. Wai
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jose M. Rodriguez
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jose M. Rodriguez.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ohde, H., Wai, C.M. & Rodriguez, J.M. The synthesis of polyacrylamide nanoparticles in supercritical carbon dioxide. Colloid Polym Sci 285, 475–478 (2007). https://doi.org/10.1007/s00396-006-1582-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-006-1582-8

Keywords

Search

Navigation