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Interaction between sodium dodecyl sulfate (SDS) and polyvinylpyrrolidone (PVP) investigated with forward and reverse component addition protocols employing tensiometric, conductometric, microcalorimetric, electrokinetic, and DLS techniques

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Abstract

The interaction between polyvinylpyrrolidone (PVP) and sodium dodecyl sulfate (SDS) after the procedure of addition of the surfactant to polymer and the reverse procedure of addition of polymer to SDS micelles has been studied by tensiometric, conductometric, and microcalorimetric methods. The results have been analyzed and correlated with reference to SDS interfacial adsorption, association, and binding to PVP. Two aggregation states of SDS in presence of PVP have been found. The enthalpies of formation of SDS aggregates/micelles and their binding to the polymer have been evaluated. The interaction of PVP with SDS at concentrations below its critical micellar concentration (CMC) and above have evidenced distinctions. The forward addition protocol (FAP, SDS addition to PVP) and reverse addition protocol (RAP, PVP addition to SDS) have shown similarities and differences. Electrokinetic measurements have evidenced the interacted (SDS–PVP) colloidal products to possess negative zeta potential in the range of −39 to −65 mV. The hydrodynamic diameters of the PVP–SDS dispersion obtained from DLS measurements have ranged between 60 and 160 nm. Both zeta potential and hydrodynamic diameter have depended on [SDS] showing a maximum for the former at twice the critical micellar concentration of SDS.

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Acknowledgements

The work was done in a collaborative project by utilizing a research grant from the St. Francis Xavier University, Canada to the Centre for Surface Science, Jadavpur University with a fellowship to Madhumita Prasad. SPM thanks Indian National Science Academy for a Senior Scientist position. RP acknowledges the funding from NSERC of Canada in the form of an operating grant. Thanks are due to Dr. Ashis Acharya for the zeta potential measurements. We thank Mr. B. P. Ghosh and Dr. M. Ghosh of the Ceramic Membrane division (Central Glass and Ceramic Research Institute, Kolkata, India) for DLS measurements.

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Authors and Affiliations

  1. Centre for Surface Science, Department of Chemistry Jadavpur University, Kolkata, 700032, West Bengal, India

    M. Prasad & S. P. Moulik

  2. Department of Chemistry, St. Francis Xavier University, Nova Scotia, Canada

    R. Palepu

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  1. M. Prasad
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  2. R. Palepu
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  3. S. P. Moulik
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Correspondence to R. Palepu.

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Prasad, M., Palepu, R. & Moulik, S.P. Interaction between sodium dodecyl sulfate (SDS) and polyvinylpyrrolidone (PVP) investigated with forward and reverse component addition protocols employing tensiometric, conductometric, microcalorimetric, electrokinetic, and DLS techniques. Colloid Polym Sci 284, 871–878 (2006). https://doi.org/10.1007/s00396-005-1453-8

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  • DOI: https://doi.org/10.1007/s00396-005-1453-8

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