Colloid and Polymer Science

, Volume 284, Issue 7, pp 780–787 | Cite as

Synthesis of polymer particles and nanocapsules stabilized with PEO/PPO containing polymerizable surfactants in miniemulsion

  • D. Crespy
  • A. Musyanovych
  • K. LandfesterEmail author
Original Contribution


We describe the miniemulsion polymerization of vinyl monomers stabilized in the presence of the polymerizable anionic surfactant Tego XP-1008 and the polymerizable nonionic surfactant Tego XP-1007. Different amounts of polymerizable surfactants and various types of initiators were used to investigate the size and the stability of the final latex particles by transmission electron microscopy and dynamic light-scattering measurements. The grafting of the polymerizable surfactants onto the surface of the latex particles was checked by NMR and XPS measurements and was found to be efficient. Finally, polymerizations of appropriate formulations containing divinylbenzene with the polymerizable surfactant Tego XP-1008 in the presence of a larger amount of hydrophobic agent produced nanocapsules.


Miniemulsion Polymerizable surfactant Surfmer Polymer nanoparticles Nanocapsules 



We especially thank the Degussa Goldschmidt GmbH for the surfactants. We gratefully thank Dr. Cai Jun for performing the XPS investigations and Mike Wendel for the GPC measurements. We also thank Dr. Ulrich Ziener for helpful discussions.


  1. 1.
    Guyot A, Tauer K (1994) Adv Polym Sci 111:43CrossRefGoogle Scholar
  2. 2.
    Guyot A (1996) Curr Opin Colloid Interface Sci 1:580CrossRefGoogle Scholar
  3. 3.
    Asua JM, Schoonbrood HAS (1998) Acta Polym 49:671CrossRefGoogle Scholar
  4. 4.
    Ottewill RH, Satgurunathan R (1995) Colloid Polym Sci 273:379CrossRefGoogle Scholar
  5. 5.
    Cochin D, Laschewsky A, Nallet F (1997) Macromolecules 30:2278CrossRefGoogle Scholar
  6. 6.
    Dufour MG, Guyot A (2003) Colloid Polym Sci 281:105CrossRefGoogle Scholar
  7. 7.
    Schoonbrood HAS, Asua JM (1997) Macromolecules 30:6034CrossRefGoogle Scholar
  8. 8.
    Boisson F, Uzulina I, Guyot A (2001) Macromol Rapid Commun 22:1135CrossRefGoogle Scholar
  9. 9.
    Guyot A, Graillat C, Favero C (2003) CR Chim 6:1319CrossRefGoogle Scholar
  10. 10.
    Pich A, Datta S, Musyanovych A, Adler HJP, Engelbrecht L (2005) Polymer 46:1323CrossRefGoogle Scholar
  11. 11.
    Landfester K (2003) Top Curr Chem 227:75Google Scholar
  12. 12.
    Tiarks F, Landfester K, Antonietti M (2001) Langmuir 17:908CrossRefGoogle Scholar
  13. 13.
    Luo Y, Zhou X (2004) J Polym Sci [A1] 42:2145Google Scholar

Copyright information

© Springer-Verlag 2006

Authors and Affiliations

  1. 1.Department of Macromolecular Chemistry and Organic MaterialsUniversity of UlmUlmGermany

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