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Effect of ionic and non-ionic surfactants on the reduction of water soluble colloidal MnO2 by glycolic acid

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Abstract

Kinetics of the redox reaction between colloidal MnO2 and glycolic acid have been studied spectrophotometrically by monitoring the decay in the absorbance of colloidal MnO2 in absence and presence of surfactants. Anionic sodium dodecyl sulfate has no effect, non-ionic Triton X-100 catalyzed the reaction and experiments were not possible in presence of cationic cetyltrimethylammonium bromide due to the precipitation of MnO2.The reaction followed the same type of kinetic behavior, i.e., fractional-, first- and fractional-order dependencies, respectively, in [glycolic acid], [MnO2] and [H+ ] in both the media. Effects of gum arabic and manganese(II) have also been studied and discussed. Mechanisms in accordance with the experimental data are proposed for the reaction.

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References

  1. Ladbury JW, Cullis CF (1958) Chem Rev 58: 403

    Article  CAS  Google Scholar 

  2. Pratt EF, Suskind SP (1963) J Org Chem 28: 638

    Article  CAS  Google Scholar 

  3. Jaky M, Zrinyi M (1993) Polyhedron 12:1271

    Article  CAS  Google Scholar 

  4. Freeman F, Kappos JC (1989) J Org Chem 54:2730

    Article  CAS  Google Scholar 

  5. Perez-Benito JF, Mata- Perez F, Brillas E (1987) Can J Chem 65:2329

    CAS  Google Scholar 

  6. Perez-Benito JF, Rodriguez RM, Andres J, Brillas E, Garzolo JA (1989) Int J Chem Kinet 21:71

    Article  CAS  Google Scholar 

  7. Perez-Benito JF, Arias C, Brillas E (1990) Int J Chem Kinet 22:261

    Article  CAS  Google Scholar 

  8. Perez-Benito JF, Arias C (1991) Int J Chem Kinet 23:717

    Article  CAS  Google Scholar 

  9. Flynn CM, Stucky GD (1969) Inorg Chem 8:332

    Article  CAS  Google Scholar 

  10. Dzzhaliev TS, Shafirovich VY, Shilov AE (1976) React Kinet Catal Lett 4:11

    Article  Google Scholar 

  11. Magers KD, Smith CG, Sawyer DT (1978) Inorg Chem 17:515

    Article  CAS  Google Scholar 

  12. Nagy L, Gajdr T, Pali T, Burger K (1988) Acta Chim Acad Sci Hung 125:403

    CAS  Google Scholar 

  13. Henglein, A (1985) In: Eicke H-F, (ed) Modern trends of colloid science in chemistry and biology. Birhauser-Verlag, Basel

  14. Perez-Benito JF, Brillas E, Pouplana R (1989) Inorg Chem 28:390

    Article  CAS  Google Scholar 

  15. Perez-Benito JF, Arias C (1992) J Colloid Interface Sci 149:92

    Article  CAS  Google Scholar 

  16. Perez-Benito JF, Arias C, Amat E (1996) J Colloid Interface Sci 177:288

    Article  CAS  Google Scholar 

  17. Khan Z, Raju, Akram M, Kabir-ud-Din (2004) Int J Chem Kinet 36:359

    Article  CAS  Google Scholar 

  18. Tuncay M, Yuce N, Arlkan B, Gokturk S (1999) Colloids Surf A Physicochem Eng Aspects 149:279

    Article  CAS  Google Scholar 

  19. Kabir-ud-Din, Fatima W, Khan Z (2004) Colloids Surf A Physicochem Eng Aspects 234:159

    Article  CAS  Google Scholar 

  20. Kabir-ud-Din, Iqubal SMS, Khan Z (2005) Inorg React Mech 5:151

    CAS  Google Scholar 

  21. Kabir-ud-Din, Iqubal SMS, Khan Z (2005) Colloid Polym Sci 283:504

    Article  CAS  Google Scholar 

  22. Kabir-ud-Din, Morshed AMA, Khan Z (2000) Inorg React Mech 3:255

    Google Scholar 

  23. Kabir-ud-Din, Morshed AMA, Khan Z (2003) Int J Chem Kinet 35:543

    Article  CAS  Google Scholar 

  24. Kabir-ud-Din, Morshed AMA, Khan Z (2004) Indian J Chem 43B:2178

    Google Scholar 

  25. Kabir-ud-Din, Hartani K, Khan Z (2002) Transition Met Chem 27:617

    Article  CAS  Google Scholar 

  26. Kabir-ud-Din, Harani K, Khan Z (2001) Colloids Surf A Physicochem Eng Aspects 193:1

    Article  Google Scholar 

  27. Kabir-ud-Din, Hartani K, Khan Z (2002) Indian J Chem 41B:2614

    Google Scholar 

  28. Fendler JH, Fendler EJ (1975) Catalysis in micellar and macromolecular systems. Academic, New York

    Google Scholar 

  29. Kabir-ud-Din, Morshed AMA, Khan Z (2002) Carbohydr Res 337:1573

    Article  PubMed  CAS  Google Scholar 

  30. Kabir-ud-Din, Morshed AMA, Khan Z (2002) Oxid Commun 26:59

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Aligarh Muslim University, Aligarh, 202002, India

    Kabir-ud-Din & S. M. Shakeel Iqubal

  2. Department of Chemistry, Jamia Millia Islamia, Jamia Nagar, New Delhi, 110025, India

    Zaheer Khan

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  1. Kabir-ud-Din
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  2. S. M. Shakeel Iqubal
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  3. Zaheer Khan
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Correspondence to Kabir-ud-Din.

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Kabir-ud-Din, Iqubal, S.M.S. & Khan, Z. Effect of ionic and non-ionic surfactants on the reduction of water soluble colloidal MnO2 by glycolic acid. Colloid Polym Sci 284, 276–283 (2005). https://doi.org/10.1007/s00396-005-1373-7

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  • DOI: https://doi.org/10.1007/s00396-005-1373-7

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