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Preparation of poly(methyl methacrylate) particles by dispersion polymerization with organic peroxide in the presence of trimethylsiloxy terminated poly(dimethylsiloxane) in supercritical carbon dioxide

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Abstract

Dispersion polymerizations of methyl methacrylate (MMA) were conducted with various types of organic peroxides as radical initiator in the presence of trimethylsiloxy terminated poly(dimethylsiloxane) in supercritical carbon dioxide. Micron-sized, relatively “monodisperse” poly(MMA) particles were prepared by using benzoyl peroxide.

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Authors and Affiliations

  1. Graduate School of Science and Technology, Kobe University, Kobe, 657-8501, Japan

    Syuji Fujii & Masayoshi Okubo

  2. Department of Chemical Science and Engineering, Faculty of Engineering, Kobe University, Kobe, 657-8501, Japan

    Hideto Minami & Masayoshi Okubo

Authors
  1. Syuji Fujii
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  2. Hideto Minami
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  3. Masayoshi Okubo
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Corresponding author

Correspondence to Masayoshi Okubo.

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Part CCLII of the series “Studies on Suspension and Emulsion”

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Fujii, S., Minami, H. & Okubo, M. Preparation of poly(methyl methacrylate) particles by dispersion polymerization with organic peroxide in the presence of trimethylsiloxy terminated poly(dimethylsiloxane) in supercritical carbon dioxide. Colloid Polym Sci 284, 327–333 (2005). https://doi.org/10.1007/s00396-005-1372-8

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  • DOI: https://doi.org/10.1007/s00396-005-1372-8

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