Skip to main content
SpringerLink
Log in

Two-dimensional gel permeation chromatography (2D GPC) correlation studies of the aggregate-aggregate interactions in acid-catalyzed triethoxysilyl-terminated polystyrene systems. The effect of specific catalysts on growth process

  • Original Contribution
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

A set of time resolved gel-permeation chromatography (GPC) profiles, for the reaction mixture of a well-defined polymeric silane coupling agent, triethoxysilyl-terminated polystyrene with molecular weight equal to 8000 (TESi-PS (8000)), catalyzed by HCl (0.1 mol/kg) in tetrahydrofuran (THF), was measured over a long time scale (1–768 h). The GPC profiles were then converted to two-dimensional (2D) correlation spectra. The 2D GPC correlation spectra were compared with those for the CH3SO3H (0.1 mol/kg)-catalyzed TESi-PS (8000)-THF system. It has been demonstrated that predominant production of less-reactive oligomers in the HCl-catalyzed system hinders further growth of the oligomer, while formation of reactive oligomers leads to further growth of polymeric precursors in the CH3SO3H-catalyzed system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1A,B
Fig. 2.A
Fig. 3.A

Similar content being viewed by others

References

  1. Suzuki K, Esaki M, Misawa A, Takaki M (1994) Kobunshi Ronbunshu 51:11

    CAS  Google Scholar 

  2. Suzuki K, Oku J, Okabayashi H, O’Connor CJ (2003) Langmuir 19:7611

    Article  CAS  Google Scholar 

  3. Munir A, Goethals EJ (1981) Makromol Chem Rapid Commun 2:693

    Article  CAS  Google Scholar 

  4. Lee KW, MacCarthy TJ (1988) Macromolecules 21:3353

    CAS  Google Scholar 

  5. Chujo Y, Ihara E, Ihara H, Saegusa T (1989) Macromolecules 22:2040

    CAS  Google Scholar 

  6. Ogasawara T, Izawa K, Hattori N, Okabayashi H, O’Connor CJ (2000) Colloid Polym Sci 278:293

    Article  CAS  Google Scholar 

  7. Izawa K, Ogasawara T, Masuda H, Okabayashi H, Monkenbnsch M, O’Connor CJ (2002) Colloid Polym Sci 280:725

    Article  CAS  Google Scholar 

  8. Izawa K, Ogasawara T, Masuda H, Okabayashi H, Noda I (2002) Macromolecules 35:92

    Article  CAS  Google Scholar 

  9. Izawa K, Ogasawara T, Masuda H, Okabayashi H, O’Connor CJ, Noda I (2002) J Phys Chem B 106:2867

    Article  CAS  Google Scholar 

  10. Izawa K, Ogasawara T, Masuda H, Okabayashi H, O’Connor CJ, Noda I (2002) Phys Chem Chem Phys 4:1053

    Article  CAS  Google Scholar 

  11. Suzuki K, Oku J, Izawa K, Okabayashi H, Noda I, O’Connor CJ (2004) Colloid Polym Sci (in press)

  12. Noda I (1993) Appl Spectrosc 47:1329

    CAS  Google Scholar 

  13. Suzuki K, Oku J, Okabayashi H, O’Connor CJ (2003) Polym J 35:938

    Article  CAS  Google Scholar 

  14. Suzuki K, Katsumura G, Kondo Y, Oku J, Takaki M (1992) Kobunshi Ronbunshu 49:825

    CAS  Google Scholar 

  15. Takaki M, Suzuki K, Kondo Y, Oku J (1991) Polym J 23:917

    CAS  Google Scholar 

  16. Iler RK (1979) The chemistry of silica—solubility, polymerization, colloid and surface properties and biochemistry. Wiley, New York, p 175

  17. Izawa K, Ogasawara T, Masuda H, Okabayashi H, O’Connor CJ (2002) Colloid Polym Sci 280:380

    Article  CAS  Google Scholar 

  18. Witten TA, Cates ME (1986) Science 232:1607

    CAS  Google Scholar 

  19. Sander LM (1987) Sci Am 256:94

    Google Scholar 

  20. Schaefer DW (1989) Science 243:94

    Google Scholar 

  21. Daoud M, Martin JE (1989) In: Avenir D (ed) The fractal approach to heterogeneous chemistry. Wiley, New York, p 109

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, 466-8555, Showa-ku, Nagoya, Aichi, Japan

    Keita Suzuki, Jun-ichi Oku & Hiro-Fumi Okabayashi

  2. Chromato Dept., Fuji Silysia Chemical Ltd., 1846 Kozoji2, 487-0013, Kasugai, Aichi, Japan

    Kenichi Izawa

  3. The Procter and Gamble Company, 8611 Beckett Road, West Chester, OH, 45069, USA

    Isao Noda

  4. Department of Chemistry, The University of Auckland, Private Bag 92019, Auckland, New Zealand

    Charmian J. O’Connor

Authors
  1. Keita Suzuki
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jun-ichi Oku
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kenichi Izawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hiro-Fumi Okabayashi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Isao Noda
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Charmian J. O’Connor
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hiro-Fumi Okabayashi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Suzuki, K., Oku, Ji., Izawa, K. et al. Two-dimensional gel permeation chromatography (2D GPC) correlation studies of the aggregate-aggregate interactions in acid-catalyzed triethoxysilyl-terminated polystyrene systems. The effect of specific catalysts on growth process. Colloid Polym Sci 283, 551–558 (2005). https://doi.org/10.1007/s00396-004-1185-1

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-004-1185-1

Keywords

Search

Navigation