Abstract
pH-induced transformation between a hemicylindrical aggregate and a laterally homogeneous layer at the graphite-solution interface was demonstrated in micellar aggregates of dodecyldimethylamine oxide (C12DMAO) using atomic force microscopy (AFM). Nonionic C12DMAO (pH~8) and fully-ionized cationic C12DMAO (pH~1.5) both formed hemicylindrical aggregates on graphite, similar to aggregates formed by many other ionic (or nonionic) surfactants on graphite. However, a laterally homogeneous layer was observed in the case of nearly half-ionized C12DMAO around pH~4 (a 1:1 mixture of the nonionic and the cationic species). These results indicated that the surface curvature of the C12DMAO aggregates on graphite was the smallest around the degree of ionization α=0.5, despite charging up the nonionic hemicylindrical aggregates. Using AFM images and the corresponding force curves, the transformation between the hemicylindrical aggregate and the laterally homogeneous layer was found to be reversible via a change in pH. The formation of the laterally homogeneous layer of nearly half-ionized C12DMAO is explained by hydrogen bond formation between the nonionic and the cationic headgroups.
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Gaudin AM, Fuerstenau DW (1955) T AIME 1
Gaudin AM, Fuerstenau DW (1955) T AIME 958
Manne S, Cleveland JP, Gaub HE, Stucky GD, Hansma PK (1994) Langmuir 10:4409
Manne S, Gaub HE (1995) Science 270:1480
Wanless EJ, Ducker WA (1996) J Phys Chem B 100:3207
Warr GG (2000) Curr Opin Colloid In 5:95
Tiberg F, Brinck J, Grant L (2000) Curr Opin Colloid In 4:411
Liu J-F, Ducker WA (1999) J Phys Chem B 103:8558
Wanless EJ, Ducker WA (1997) Langmuir 13:1463
FitzGerald PA, Warr GG (2001) Adv Mater 13:967
Lamont R, Ducker WA (1997) J Colloid Interf Sci 191:303
Grant LM, Tiberg F, Ducker WA (1998) J Phys Chem B 102:4288
Kiraly Z, Findenegg GH (1998) J Phys Chem B 102:1203
Grant LM, Edeth T, Tiberg F (2000) Langmuir 16:2285
Wolgemuth JL, Workman RK, Manne S (2000) Langmuir 16:3077
Bandyopadhyay S, Schelly JC, Tarek M, Moore PB, Klein ML (1998) J Phys Chem B 102:6318
Jonson RA, Nagarajan R (2000) Colloid Surface A 167:21
Herrmann KW (1962) J Phys Chem 66:295
Tokiwa F, Ohki K (1966) J Phys Chem 70:3437
Maeda H, Tsunoda M, Ikeda S (1974) J Phys Chem 78:1086
Ikeda S, Tsunoda M, Maeda H (1979) J Colloid Interf Sci 70:448
Warr GG, Grieser F, Evans DF (1986) J Chem Soc Farad T 1 82:1829
Rathman JF, Christian SD (1990) Langmuir 6:391
Maeda H (1996) Colloid Surface A 109:263
Maeda H, Kakehashi, R (2000) Adv Colloid Interfac 88:275
Kawasaki H, Fukuda T, Yamamoto A, Fukada K, Maeda H (2000) Colloid Surface A 169:117
Miyahara M, Kawasaki H, Fukuda T, Ozaki Y, Maeda H. (2001) Colloid Surface A 183–185:475
Kawasaki H, Maeda H (2001) Langmuir 17:2279
Kawasaki H, Ookuma K, Maeda H (2002) J Colloid Interf Sci 252:419
Kawasaki H, Souda M, Tanaka S, Nemoto N, Karlsson G, Almgren M, Maeda H (2002) J Phys Chem B 106:1524
Kawasaki H, Shutou M, Maeda H (2001) Langmuir 17:8210
Davey TW, Warr GG, Almgren M, Asakawa T (2001) Langmuir 17:5283
Maeda H, Kanakubo Y, Miyahara M, Kakehashi R, Garamus V, Pedersen JS (2000) J Phys Chem B 104:6174
Miyahara M, Kawasaki H, Garamus VM, Nemoto N, Kakehashi R, Tanaka S, Annaka M, Maeda H (2004) Colloid Surface B (submitted)
Ducker WA, Wanless EJ (1996) Langmuir 12:5915
Patrick HN, Warr GG, Manne S, Aksay IA (1999) Langmuir 15:1685
Xu SL, Wang C, Zeng, QD, Wu P, Wang ZG, Yan HK, Bai CL (2002) Langmuir 18:657
Israelachvili JN, Mitchel DJ, Ninham BW (1976) J Chem Soc Farad T 2 72:1525
Goddard ED, Kung HC (1973) J Colloid Interf Sci 43:511
Rathman JF, Scheuing DR (1990) ACS Sym Ser 447 7:123
Grant LM, Ducker WA (1997) J Phys Chem B 101:5337
Wanless EJ, Davey TW, Ducker WA (1997) Langmuir 13:4223
Holland NB, Ruegsegger M, Marchant RE (1998) Langmuir 14:2790
Acknowledgements
This work is supported, in part, by the Grant-in Aid for Scientific Research (No. 15750121) from The Monbukagaku-shou Japan, and in part by the Mitsubishi Chemical Corporation Fund. This study was partially supported by Industrial Technology Research Grant Program ‘03 from the New Energy and Industrial Technology Development Organization (NEDO) of Japan.
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Kawasaki, H., Shinoda, M., Miyahara, M. et al. Reversible pH-induced transformation of micellar aggregates between hemicylinders and laterally homogeneous layers at graphite-solution interfaces. Colloid Polym Sci 283, 359–366 (2005). https://doi.org/10.1007/s00396-004-1146-8
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DOI: https://doi.org/10.1007/s00396-004-1146-8