Abstract
Densities and sound velocities of aqueous solutions of sodium octanoate were determined in a range of molalities between 0.0352 and 0.8105 mol kg−1 at 25, 30, 35, 40 and 45 °C. The isotherms of molality dependence of both density and sound velocity were used to determine the cmcs. Apparent molar volumes and compressibilities were determined from measurements of ultrasound velocity and density. The values of apparent molar volumes and compressibilities at infinite dilution and the apparent molar quantities in the micellar range were obtained and studied as a function of temperature. Values of the critical micelle concentration and the apparent molar quantities in the premicellar and postmicellar range are discussed and compared with the values of the corresponding fluorinated compound.
Similar content being viewed by others
References
Evans DF, Wennerström H (1994) The colloidal domain. Where physics, chemistry, biology and technology meet. VCH, New York
Moroi Y (1992) Micelles: theoretical and applied aspects. Plenum, New York
Desnoyers JE, De Lisi R, Perron G (1980) Pure Appl Chem 85:433
Garnsey R, Boe RJ, Mahoney R, Litovitz TA (1969) J Chem Phys 50:5222
Musbally GM, Perron G, Desnoyers JE (1974) J Colloid Interface Sci 48:631
Leduc PA, Fortier JL, Desnoyers JE (1974) J Phys Chem 78:1217
Desnoyers JE, Perron G, Roux AH (1987) In: Zana R (ed) Surfactant solutions: new methods of investigation. Surfactant science series, vol 22. Dekker, New York, pp 1–55
Millero FJ (1971) Chem Rev 71:147
Lepori L, Gianni P (2000) J Solution Chem 29:405
Shigehara K (1966) Bull Chem Soc Jpn 39:2332
Vikingstad E, Skauge A, Høiland H (1979) J Colloid Interface Sci 72:59
Bloor DM, Gormally J, Wyn-Jones E (1984) J Chem Soc Faraday Trans I 80:1915
Zielinski R, Ikeda S, Nomura H, Kato S (1988) J Chem Soc Faraday Trans I 84:151
Kudryashov E, Kapustina T, Morrissey S, Buckin V, Dawson K (1998) J Colloid Interface Sci 203:59
González-Pérez A, Ruso, JM, Prieto G, Sarmiento F J Surfactants Deterg (submitted)
Zielinski R, Ikeda S, Nomura H, Kato S (1987) J Colloid Interface Sci 119:398
Gonzalez-Pérez A, Prieto G, Ruso JM, Sarmiento F (2003) Mol Phys 101:3185
Ekwall P, Eikrem H, Mandell L (1963) Acta Chem Scand 17:111
Ekwall P, Holmberg P (1965) Acta Chem Scand 19:455
Ekwall P, Holmberg P (1965) Acta Chem Scand 19:573
Ekwall P, Lemstrom KE, Eikrem H, Holmberg P (1967) Acta Chem Scand 21:1401
Ekwall P, Eikrem H, Stenius P (1967) Acta Chem Scand 21:1639
Stenius P, Ekwall P (1967) Acta Chem Scand 21:1643
Ekwall P, Stenius P (1967) Acta Chem Scand 21:1767
D’Angelo M, Onori G, Santucci A (1994) Colloid Polym Sci 97:154
Franks F, Quickenden MJ, Ravenhill JR, Smith HT (1968) J Phys Chem 72:2668
Redlich O, Rosenfeld P (1931) Z Elektrochem 37:705
Redlich O, Rosenfeld P (1931) Z Phys Chem 155:65
Brun TS, Høiland H, Vikingstad E (1978) J Colloid Interface Sci 63:89
Musbally GM, Perron G, Desnoyers JE (1974) J Colloid Interface Sci 48:494
Sakurai M, Komatsu T, Nakagawa T (1975) Bull Chem Soc Jpn 48:3491
Leduc PA, Desnoyers JE (1973) Can J Chem 51:2993
Helper LG (1969) Can J Chem 47:4613
Shinoda K, Hutchinson E (1962) J Phys Chem 66:577
Del Castillo JL, Czapkiewic J, González-Pérez A, Rodríguez JR (2000) Colloids Surf A 166:161
Bradley DJ, Pitzer KS (1979) J Phys Chem 83:1599
Cabani S, Conti G, Matteoli E (1978) J Solution Chem 8:11
Tamaki K, Watanabe S, Daikyoji Y (1990) Bull Chem Soc Jpn 63:3681
Perron G, Desnoyers JE (1997) J Chem Eng Data 42:172
De Lisi R, Inglese A, Milioto S, Pellerito, A (1997) Langmuir 13:192
De Lisi R, Milioto S, De Giacomo A, Inglese A (1999) Langmuir 15:5014
Acknowledgements
This research was funded by the Spanish Ministry of Science and Technology, through the project MAT2002–00608 (European FEDER support included). A.G.-P. thanks the University of Santiago de Compostela for his postdoctoral grant.
Author information
Authors and Affiliations
Corresponding author
Additional information
An erratum to this article can be found at http://dx.doi.org/10.1007/s00396-004-1223-z
Rights and permissions
About this article
Cite this article
González-Pérez, A., Ruso, J.M., Prieto, G. et al. Apparent molar quantities of sodium octanoate in aqueous solutions. Colloid Polym Sci 282, 1133–1139 (2004). https://doi.org/10.1007/s00396-003-1047-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-003-1047-2