Interaction of atmospheric chemistry and climate and its impact on stratospheric ozone

Abstract.

The interactively coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM is employed in sensitivity calculations to investigate feedback mechanisms of dynamic, chemical, and radiative processes. Two multi-year model simulations are carried out, which represent recent atmospheric conditions. It is shown that the model is able to reproduce observed features and trends with respect to dynamics and chemistry of the troposphere and lower stratosphere. In polar regions it is demonstrated that an increased persistence of the winter vortices is mainly due to enhanced greenhouse gas mixing ratios and to reduced ozone concentration in the lower stratosphere. An additional sensitivity simulation is investigated, concerning a possible future development of the chemical composition of the atmosphere and climate. The model results in the Southern Hemisphere indicate that the adopted further increase of greenhouse gas mixing ratios leads to an intensified radiative cooling in the lower stratosphere. Therefore, Antarctic ozone depletion slightly increases due to a larger PSC activity, although stratospheric chlorine is reduced. Interestingly, the behavior in the Northern Hemisphere is different. During winter, an enhanced activity of planetary waves yields a more disturbed stratospheric vortex. This "dynamical heating" compensates the additional radiative cooling due to enhanced greenhouse gas concentrations in the polar region. In connection with reduced stratospheric chlorine loading, the ozone layer clearly recovers.