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Terrestrial n-alkane signatures in the middle Okinawa Trough during the post-glacial transgression: control by sea level and paleovegetation confounded by offshore transport

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Abstract

We report records of land plant-derived long-chain n-alkanes since 37 ka b.p. from a sediment core in the middle Okinawa Trough, East China Sea. The data show the content and carbon preference index (CPI; degree of freshness) of n-alkanes generally decreasing as sea level rose, which could be explained by coastline retreat resulting in an increased transport route of n-alkanes toward the study site. The n-alkane CPI returned to higher values during the Holocene highstand, however, suggesting sea-level rise was not the only cause for the decline of freshness of n-alkanes. Paleovegetation changes in terms of C3 vs. C4 contributions inferred from n-alkane δ13C are overall consistent with published marine and terrestrial records during two distinct intervals: from 37.0 to 15.2 ka b.p., and from 7.6 ka b.p. to the present. However, n-alkane δ13C excursions from 15.2 to 7.6 ka b.p. are difficult to reconcile with terrestrial signatures. This disagreement, along with other possible causes for the decline of freshness of n-alkanes, and the higher-energy sedimentary environment inferred from increased mean grain sizes and silt/clay ratios during this time period, is consistent with existing knowledge of offshore transport of materials previously stored on the extensive continental shelf during the post-glacial transgression. We therefore suggest that n-alkane records from the Okinawa Trough should be used only cautiously to infer deglacial vegetation and sea-level changes.

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Correspondence to Guodong Jia.

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Zhang, J., Yu, H., Jia, G. et al. Terrestrial n-alkane signatures in the middle Okinawa Trough during the post-glacial transgression: control by sea level and paleovegetation confounded by offshore transport. Geo-Mar Lett 30, 143–150 (2010). https://doi.org/10.1007/s00367-009-0173-3

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