Abstract
We report on spectroscopic measurements of acrolein and acrylonitrile at atmospheric pressure using a pulsed distributed feedback quantum-cascade laser in combination with intra- and inter-pulse techniques and compare the results. The measurements were done in the frequency region around 957 cm−1. In the inter-pulse technique, the laser is excited with short current pulses (5–10 ns), and the pulse amplitude is modulated with an external current ramp resulting in a ∼2.3 cm−1 frequency scan. In the intra-pulse technique, a linear frequency down-chirp during the pulse is used for sweeping across the absorption line. Long current pulses up to 500 ns were used for these measurements which resulted in a spectral window of ∼2.2 cm−1 during the down-chirp. These comparatively wide spectral windows facilitated the measurements of the relatively broad absorption lines (∼1 cm−1) of acrolein and acrylonitrile. The use of a room-temperature mercury-cadmium-telluride detector resulted in a completely cryogen-free spectrometer. We demonstrate ppb level detection limits within a data acquisition time of ∼10 s with these methodologies.
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This research was made possible by financial support from the Canada Foundation for Innovation (CFI) and the Natural Sciences and Engineering Research Council of Canada (NSERC). JM gratefully acknowledges an Alberta Ingenuity Postdoctoral Fellowship.
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Manne, J., Lim, A., Tulip, J. et al. Sensitive detection of acrolein and acrylonitrile with a pulsed quantum-cascade laser. Appl. Phys. B 107, 441–447 (2012). https://doi.org/10.1007/s00340-012-4941-9
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DOI: https://doi.org/10.1007/s00340-012-4941-9