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Development of a versatile atmospheric N2O sensor based on quantum cascade laser technology at 4.5 μm

Abstract

We report the development of a field-deployable infrared laser spectrometer using new quantum cascade laser technology at 4.5 μm. The instrument is designed to measure in situ N2O concentrations at ground level even in bad weather conditions. We provide details of the instrument design and data processing. The long-term stability of the instrument was evaluated using the Allan variance technique. A preliminary evaluation of the instrument performance was realized by in situ measurements of N2O concentration outside the laboratory.

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References

  1. 1.

    T. Mitsui, M. Miyamura, A. Matsunami, K. Kitagawa, N. Arai, Clin. Chem. 43, 1993 (1997)

    Google Scholar 

  2. 2.

    R. Knowles, Microbiol. Rev. 46, 43 (1982)

    Google Scholar 

  3. 3.

    J.I. Prosser, Nitrification (IRL Press, Oxford, 1986)

    Google Scholar 

  4. 4.

    J.M. Duxbury, D.R. Bouldin, R.E. Terry, R.L. Tate III, Nature 298, 462 (1982)

    ADS  Article  Google Scholar 

  5. 5.

    H. Flessa, R. Ruser, R. Schilling, N. Loftfield, J.C. Munch, E.A. Kaiser, F. Beese, Geoderma 105, 307 (2002)

    Article  Google Scholar 

  6. 6.

    A.F. Bouwman, Nutr. Cycl. Agroecosyst. 46, 53 (1996)

    Article  Google Scholar 

  7. 7.

    M.S. Zahniser, D.D. Nelson, J.B. McManus, P.L. Kebabian, Philos. Trans. R. Soc. Lond., Ser. A 351, 371 (1995)

    ADS  Article  Google Scholar 

  8. 8.

    M. Carras, M. Garcia, X. Marcadet, O. Parillaud, A. De Rossi, S. Bansropun, Appl. Phys. Lett. 93, 011109 (2008)

    ADS  Article  Google Scholar 

  9. 9.

    M. Carras, G. Maisons, B. Simozrag, M. Garcia, O. Parillaud, J. Massies, X. Marcadet, Appl. Phys. Lett. 96, 161105 (2010)

    ADS  Article  Google Scholar 

  10. 10.

    A. Grossel, V. Zéninari, B. Parvitte, L. Joly, D. Courtois, Appl. Phys. B 88, 483 (2007)

    ADS  Article  Google Scholar 

  11. 11.

    L. Joly, C. Robert, B. Parvitte, V. Catoire, G. Durry, G. Richard, B. Nicoullaud, V. Zéninari, Appl. Opt. 47, 1206 (2008)

    ADS  Article  Google Scholar 

  12. 12.

    L.S. Rothman, I.E. Gordon, A. Barbe, D. ChrisBenner, P.F. Bernath, M. Birk, V. Boudon, L.R. Brown et al., J. Quant. Spectrosc. Radiat. Transf. 110, 533 (2009)

    ADS  Article  Google Scholar 

  13. 13.

    www.3-5lab.fr

  14. 14.

    V. Zéninari, B. Parvitte, L. Joly, T. Le Barbu, N. Amarouche, G. Durry, Appl. Phys. B 85, 265 (2006)

    ADS  Article  Google Scholar 

  15. 15.

    M. Mulier, V. Zéninari, L. Joly, T. Decarpenterie, B. Parvitte, P. Jeandet, G. Liger-Belair, Appl. Phys. B 94, 725 (2009)

    ADS  Article  Google Scholar 

  16. 16.

    J. Moncrieff, R. Valentini, S. Greco, G. Seufert, P. Ciccioli, J. Exp. Bot. 48, 1133 (1997)

    Article  Google Scholar 

  17. 17.

    D.W. Allan, IEEE Trans. Ultrason. Ferroelectr. Freq. Control 34, 647 (1987)

    ADS  Article  Google Scholar 

  18. 18.

    D.W. Allan, Proc. IEEE 54, 221 (1966)

    Article  Google Scholar 

  19. 19.

    E.S. Ferre-Pikal, J.R. Vig, J.C. Camparo, L.S. Cutler, L. Maleki, W.J. Riley, S.R. Stein, C. Thomas, F.L. Walls, J.D. White, in Proc. IEEE Int. Freq. Control Symp. (1997), p. 338

    Chapter  Google Scholar 

  20. 20.

    D.R. Keeney, I.R. Fillery, G.P. Marx, Soil Sci. Soc. Am. J. 43, 1124 (1979)

    Article  Google Scholar 

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Correspondence to V. Zéninari.

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Joly, L., Decarpenterie, T., Dumelié, N. et al. Development of a versatile atmospheric N2O sensor based on quantum cascade laser technology at 4.5 μm. Appl. Phys. B 103, 717–723 (2011). https://doi.org/10.1007/s00340-011-4522-3

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Keywords

  • Quantum Cascade Laser
  • Allan Variance
  • Tunable Diode Laser Absorption Spectroscopy
  • Absorption Path Length
  • ZnSe Lens