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Infrared multiphoton dissociation of 1,2-dichloroethyltrifluorosilane

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Abstract

Infrared multiphoton absorption and dissociation of 1,2-dichloroethyltrifluorosilane molecules under the action of pulsed TEA CO2 laser were experimentally studied. The composition of dissociation products was analyzed. The only products of dissociation have been found to be stable molecules: chloroethylene and trifluorochlorosilane. Dissociation proceeds via chlorine atom transfer from carbon to silicon. The silicon isotope-selective infrared multiphoton dissociation was performed at different wavelengths of the CO2-laser radiation. High degrees of silicon isotope separation have been achieved.

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion SB RAS, Institutskaya, 3, Novosibirsk, 630090, Russia

    P. V. Koshlyakov, P. S. Dementyev, E. N. Chesnokov & A. K. Petrov

  2. Novosibirsk State University, Pirogova, 2, Novosibirsk, 630090, Russia

    P. S. Dementyev & E. N. Chesnokov

  3. Institute of Material of Research and Engineering, 3, Research Link, Singapore, 117602, Singapore

    S. R. Gorelik

Authors
  1. P. V. Koshlyakov
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  2. P. S. Dementyev
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  3. S. R. Gorelik
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  4. E. N. Chesnokov
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  5. A. K. Petrov
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Correspondence to P. V. Koshlyakov.

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Koshlyakov, P.V., Dementyev, P.S., Gorelik, S.R. et al. Infrared multiphoton dissociation of 1,2-dichloroethyltrifluorosilane. Appl. Phys. B 97, 625–633 (2009). https://doi.org/10.1007/s00340-009-3596-7

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  • DOI: https://doi.org/10.1007/s00340-009-3596-7

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