Skip to main content
Log in

Huge retardation of grating formation in holographic polymer-dispersed liquid crystals

  • Rapid communication
  • Published:
Applied Physics B Aims and scope Submit manuscript

Abstract

Phototriggered kinetics is investigated in the dark for holographic polymer-dispersed liquid crystal gratings. Subsequently to holographic recording, the diffraction efficiency first slightly increases, then decreases, and afterwards starts to grow again. The remarkable growth continues for several days until the diffraction efficiency stabilizes at values several times larger than the initial ones. The initial increase is attributed to a dark polymerization reaction as confirmed by electron paramagnetic resonance spectroscopy. The slow process is associated with the kinetics of a phase-separation mechanism. The non-monotonic behaviour of the diffraction efficiency is explained by superposition of refractive-index and extinction modulations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  1. For a recent review, see G.P. Crawford, Opt. Photon. News 14, 54 (2003)

    Google Scholar 

  2. R.L. Sutherland, V.P. Tondiglia, L.V. Natarajan, T.J. Bunning, W.W. Adams, Appl. Phys. Lett. 64, 1074 (1994)

    Article  ADS  Google Scholar 

  3. C.C. Bowley, G.P. Crawford, Appl. Phys. Lett. 76, 2235 (2000)

    Article  ADS  Google Scholar 

  4. T.J. Bunning, L.V. Natarjan, V.P. Tondiglia, R.L. Sutherland, Annu. Rev. Mater. Sci. 30, 83 (2000)

    Google Scholar 

  5. R. Caputo, L. De Sio, A. Veltri, C. Umeton, A.V. Sukhov, Opt. Lett. 29, 1261 (2004)

    Article  ADS  Google Scholar 

  6. R. Caputo, A. Veltri, C.P. Umeton, A.V. Sukhov, J. Opt. Soc. Am. B 21, 1939 (2004)

    ADS  Google Scholar 

  7. A. d’Alessandro, R. Asquini, C. Gizzi, R. Caputo, C. Umeton, A. Veltri, A.V. Sukhov, Opt. Lett. 29, 1405 (2004)

    Article  ADS  Google Scholar 

  8. T.J. Bunning, L.V. Natarajan, V. Tondiglia, R.L. Sutherland, D.L. Vezie, W.W. Adams, Polymer 36, 2699 (1995)

    Article  Google Scholar 

  9. A.Y.G. Fuh, M.S. Tsai, T.C. Liu, L.C. Chien, Japan. J. Appl. Phys. 36, 6839 (1997)

    Article  ADS  Google Scholar 

  10. T.J. Bunning, L.V. Natarajan, V.P. Tondiglia, G. Dougherty, R.L. Sutherland, J. Polym. Sci. B Polym. Phys. 35, 2825 (1997)

    Article  Google Scholar 

  11. C.C. Bowley, H.J. Yuan, G.P. Crawford, Mol. Cryst. Liq. Cryst. 331, 2069 (1999)

    Article  Google Scholar 

  12. R.T. Pogue, L.V. Natarajan, S.A. Siwecki, V.P. Tondiglia, R.L. Sutherland, T.J. Bunning, Polymer 41, 733 (2000)

    Article  Google Scholar 

  13. I. Drevenšek-Olenik, M. Jazbinšek, M.E. Sousa, A.K. Fontecchio, G.P. Crawford, M. Čopič, Phys. Rev. E 69, 051703 (2004)

    Article  ADS  Google Scholar 

  14. K.K. Vardanyan, J. Qi, J.N. Eakin, M. De Sarkar, G.P. Crawford, Appl. Phys. Lett. 81, 4736 (2002)

    Article  ADS  Google Scholar 

  15. M. De Sarkar, J. Qi, G.P. Crawford, Polymer 43, 7335 (2002)

    Article  Google Scholar 

  16. M. Escuti, J. Qi, G.P. Crawford, Appl. Phys. Lett. 83, 1331 (2003)

    Article  ADS  Google Scholar 

  17. M. De Sarkar, N.L. Gill, J.B. Whitehead, G.P. Crawford, Macromolecules 36, 630 (2003)

    Article  ADS  Google Scholar 

  18. R. Caputo, A.V. Sukhov, N.V. Tabirian, C. Umeton, R.F. Ushakov, Chem. Phys. 271, 323 (2001)

    Article  Google Scholar 

  19. T. Kyu, D. Nwabunma, H.W. Chiu, Phys. Rev. E 63, 061802 (2001)

    Article  ADS  Google Scholar 

  20. R.L. Sutherland, V.P. Tondiglia, L.V. Natarajan, T.J. Bunning, J. Appl. Phys. 96, 951 (2004)

    Article  ADS  Google Scholar 

  21. S. Meng, T. Kyu, L.V. Natarajan, V.P. Tondiglia, R.L. Sutherland, T.J. Bunning, Macromolecules 38, 4844 (2005)

    Article  ADS  Google Scholar 

  22. S. Meng, H. Duran, J. Hu, T. Kyu, L.V. Natarajan, V.P. Tondiglia, R.L. Sutherland, T.J. Bunning, Macromolecules 40, 3190 (2007)

    Article  ADS  Google Scholar 

  23. C.F. van Nostrum, R.J.M. Nolte, D.J. Broer, Chem. Mater. 10, 135 (1998)

    Article  Google Scholar 

  24. R. Caputo, A.V. Sukhov, N.V. Tabiryan, C. Umeton, Chem. Phys. 245, 463 (1999)

    Article  Google Scholar 

  25. J. Qi, M. De Sarkar, G.T. Warren, G.P. Crawford, J. Appl. Phys. 91, 4795 (2002)

    Article  ADS  Google Scholar 

  26. C. Neipp, S. Gallego, M. Ortuno, A. Marquez, A. Belendez, I. Pascual, Opt. Commun. 224, 27 (2003)

    Article  ADS  Google Scholar 

  27. J. Qi, M.E. Sousa, A.K. Fontecchio, G.P. Crawford, Appl. Phys. Lett. 82, 1652 (2003)

    Article  ADS  Google Scholar 

  28. A. Veltri, R. Caputo, C. Umeton, A.V. Sukhov, Appl. Phys. Lett. 84, 3492 (2004)

    Article  ADS  Google Scholar 

  29. J. Qi, G.P. Crawford, Displays 25, 177 (2004)

    Article  Google Scholar 

  30. S. Massenot, J.L. Kaiser, M.C. Perez, R. Chevallier, J.L.B. de la Tocnaye, Appl. Opt. 25, 5273 (2005)

    Article  ADS  Google Scholar 

  31. A. Veltri, R. Caputo, L. De Sio, C. Umeton, A.V. Sukhov, Mol. Cryst. Liq. Cryst. 465, 187 (2007)

    Article  Google Scholar 

  32. J.T. Sheridan, J.R. Lawrence, J. Opt. Soc. Am. A 17, 1108 (2000)

    Article  ADS  Google Scholar 

  33. S. Massenot, J.L. Kaiser, R. Chevallier, Y. Renotte, Appl. Opt. 43, 5489 (2004)

    Article  ADS  Google Scholar 

  34. J. Qi, L. Li, M. De Sarkar, G.P. Crawford, J. Appl. Phys. 96, 2443 (2004)

    Article  ADS  Google Scholar 

  35. J.V. Kelly, F.T. O’Neill, J.T. Sheridan, C. Neipp, S. Gallego, M. Ortuno, J. Opt. Soc. Am. B 22, 407 (2005)

    Article  ADS  Google Scholar 

  36. J.V. Kelly, M.R. Gleeson, C.E. Close, F.T. O’Neill, J.T. Sheridan, J. Appl. Phys. 99, 113105 (2006)

    Article  ADS  Google Scholar 

  37. J.G. Kloosterboer, Adv. Polym. Sci. 84, 1 (1988)

    Article  Google Scholar 

  38. I. Drevenšek-Olenik, M. Fally, M.A. Ellabban, Phys. Rev. E 74, 021707 (2006)

    Article  ADS  Google Scholar 

  39. E. Selli, C. Oliva, Macromol. Chem. Phys. 197, 497 (1996)

    Article  Google Scholar 

  40. R.L. Sutherland, L.V. Natarajan, V.P. Tondiglia, T.J. Bunning, Chem. Mater. 5, 1533 (1993)

    Article  Google Scholar 

  41. Z. Lin, H. Zhang, Y. Yang, Macromol. Chem. Phys. 200, 943 (1999)

    Article  Google Scholar 

  42. F. Roussel, J.M. Buisine, U. Maschke, X. Coqueret, F. Benmouna, Phys. Rev. E 62, 2310 (2000)

    Article  ADS  Google Scholar 

  43. M.A. Ellabban, M. Bichler, M. Fally, I. Drevenšek-Olenik, Proc. SPIE 6587, 65871J-1 (2007)

  44. H. Kogelnik, Bell Syst. Tech. J. 48, 2909 (1969)

    Google Scholar 

  45. K. Sutter, P. Günter, J. Opt. Soc. Am. B 7, 2274 (1990)

    ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to I. Drevenšek-Olenik.

Additional information

PACS

42.40.Ht; 61.30.Pq; 42.70.Df; 64.70.Md

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ellabban, M., Drevenšek-Olenik, I. & Rupp, R. Huge retardation of grating formation in holographic polymer-dispersed liquid crystals. Appl. Phys. B 91, 11–15 (2008). https://doi.org/10.1007/s00340-008-2964-z

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00340-008-2964-z

Keywords

Navigation