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Infrared multiphoton dissociation of difluorosilane

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Abstract

Infrared (IR) multiphoton absorption and dissociation of difluorosilane molecules under the action of a pulsed transversely excited atmospheric CO2 laser were experimentally studied. It has been found that the multiphoton absorption is strongly saturated due to the rotational bottleneck effect. Isotope-selective IR multiphoton dissociation of difluorosilane was performed at 977.2 cm-1. The dissociation rate for 28SiH2F2 isotopomer has been found to be about twice as high as for the other isotopomers at this wavelength.

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion of SB RAS, Institutskaya, 3, 630090, Novosibirsk , Russia

    S.R. Gorelik, E.N. Chesnokov, A.V. Kuibida, R.R. Akberdin & A.K. Petrov

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  1. S.R. Gorelik
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  2. E.N. Chesnokov
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  3. A.V. Kuibida
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  4. R.R. Akberdin
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  5. A.K. Petrov
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Correspondence to S.R. Gorelik.

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PACS

82.50.Bc; 82.30.Lp

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Gorelik, S., Chesnokov, E., Kuibida, A. et al. Infrared multiphoton dissociation of difluorosilane. Appl Phys B 78, 119–125 (2004). https://doi.org/10.1007/s00340-003-1317-1

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  • DOI: https://doi.org/10.1007/s00340-003-1317-1

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