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Superconductivity at 45 K in La2CuO4+δ oxidized by NaClO

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Abstract

An efficient and convenient oxidizing agent, sodium hypochlorite solution, has been used to chemically prepare the superconductor La2CuO4+δ at room temperature. The crystallographic data show an enhanced orthorhombic distortion and an increase of the unit-cell volume. The magnetic susceptibility properties reveal a sharp transition beginning at 45 K and the oxidized sample is a homogeneous and single-phase bulk superconductor. The iodometric titration measurements indicate that the oxidized sample has a higher excess-oxygen content of 0.11. Scanning electron microscope observations showed that no grain size difference was observed for the sample before and after oxidation.

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Received: 15 September 2000 / Accepted: 19 January 2001 / Published online: 3 April 2001

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Tu, Q., Chen, X., Ma, B. et al. Superconductivity at 45 K in La2CuO4+δ oxidized by NaClO. Appl Phys A 74, 79–82 (2002). https://doi.org/10.1007/s003390100839

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  • DOI: https://doi.org/10.1007/s003390100839

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