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Preparation of ZrO2/γ-Al2O3 albumen type catalyst and its catalytic performance for carbonyl sulfide hydrolysis

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Abstract

In order to realize the efficient removal of COS from blast furnace gas, a ZrO2/γ-Al2O3 albumen type catalyst with low energy consumption and high hydrolysis efficiency using γ-Al2O3 as the carrier and zirconium nitrate as the active component was prepared in this study. The results showed that when the loading of zirconium nitrate was 6% and the calcination temperature was 550 °C, the prepared ZrO2/γ-Al2O3 albumen hydrolysis catalyst had the best hydrolysis catalytic effect on COS. The removal rate of COS could reach up to 96.95%, and the overflow rate of H2S was maintained at 72.0% after 80 min of reaction. Compared with the single carrier γ-Al2O3, the loading of active component ZrO2 can avoid the adsorption of H2S on the catalyst to block the pore structure of the catalyst, and it can improve the hydrolysis conversion of COS and the overflow rate of H2S, so that the catalyst maintains high catalytic activity.

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Data availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Acknowledgements

This research was funded by Technology Innovation Leading Program of Shaanxi [No. 2022QFY06-04]; Key Research and development Plan of Ningxia Hui Autonomous Region [No. 2023BEG02058]; Natural Science Basic Research Program of Shaanxi [No. 2019JL-01]. “Two-chain” fusion key program of Shaanxi Province [No. 2023-LL-QY-05].

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Authors and Affiliations

  1. School of Geology and Environment, Xi’an University of Science and Technology, Xi’an, 710054, China

    Lei Zhang, Ya Chen, Ruikang Song, Qi Wang, Chunjiang Liu & Yidan Mu

  2. Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Ministry of Natural Resources, Xi’an, 710021, China

    Lei Zhang

  3. China National Heavy Machinery Research Institute Co, Ltd, Xi’an, 710032, China

    Lei Zhang

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Contributions

Conceptualization, LZ (F) and LZ (M); Methodology, RS; Software, QW; Validation, CL; Investigation, LZ (F); Data Curation, YM; Writing-Original Draft Preparation, YC; Writing-Review & Editing, YC.

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Correspondence to Lei Zhang.

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Zhang, L., Chen, Y., Zhang, L. et al. Preparation of ZrO2/γ-Al2O3 albumen type catalyst and its catalytic performance for carbonyl sulfide hydrolysis. Appl. Phys. A 130, 170 (2024). https://doi.org/10.1007/s00339-024-07303-2

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