Abstract
This article discusses the optoelectronic performance of Cu-graphene (Cu-G) film prepared by the sputtering of the Cu layer on graphene oxide (GO) before the thermal reduction process. Surface diffusion of Cu intervenes with the reduction mechanism of GO in a good way if the Cu is sufficiently thick after 120 s sputtering. The best crystal quality of Cu-G is indicated by the Raman spectra lowest ΓG = 69 cm–1 and highest ID/IG = 1.63. Originally, the thickness of Cu after 120 s sputtering is 12 nm while the thickness of spin-coated GO is 5.52 nm. After the thermal reduction, Cu-G is 2.1 nm with an additional 0.3 nm residual layer underneath. The optical transmittance of Cu-G film at λ = 550 nm is 89.3% and it has two surface plasmon resonances at 4.58 eV and 5.28 eV. The peaks of absorption at high energy UV possibly allow Cu-G to boost its electrical conductivity without costing its transmittance in visible light. In a dark condition, the measured sheet resistance is 54.07 Ω sq–1, Hall mobility of holes majority carriers is 37.48 cm2 V–1 s–1, and dc conductivity is 7.88 × 104 S cm–1. They can be translated into a relatively high figure-of-merit of transparent conductor equivalent to 59.9. The stable processing of Cu-G film makes it promising to integrate this process into the fabrication of relevant optoelectronic devices.
Similar content being viewed by others
Data availability
The datasets generated during and/or analyzed in this study are available from the corresponding author upon reasonable request.
References
C. Tong, M. Kumar, J.H. Yun, J. Kim, S.J. Kim, High-quality ITO/Al-ZnO/n-Si heterostructures with junction engineering for improved photovoltaic performance. Appl. Sci. 10, 5285 (2020)
J.J. Lin, Z.Q. Li, Electronic conduction properties of indium tin oxide: single-particle and many-body transport. J. Phys. Condens. Matter 26, 343201 (2014)
S. Li, Y.L. Cao, W.H. Li, Z.S. Bo, A brief review of hole transporting materials commonly used in perovskite solar cells. Rare Met. 40, 2712–2729 (2021)
A. Tombak, M. Benhaliliba, Y.S. Ocak, T. Kilicoglu, The novel transparent sputtered p-type CuO thin films and Ag/p-CuO/n-Si Schottky diode applications. Results Phys. 5, 314–321 (2015)
K.H.L. Zhang, K. Xi, M.G. Blamire, R.G. Egdell, P-type transparent conducting oxides. J. Phys. Condens. Matter. 28, 383002 (2016)
N. Selvakumar, B. Vadivel, D.V.S. Rao, S.B. Krupanidhi, H.C. Barshilia, Controlled growth of high-quality graphene using hot-filament chemical vapor deposition. Appl. Phys. A 122, 943 (2016)
J. Zhang, L. Lin, K. Jia, L. Sun, H. Peng, Z. Liu, Controlled growth of single-crystal graphene films. Adv. Mater. 32, 1903266 (2019)
M. Saeed, Y. Alshammari, S.A. Majeed, E. Al-Nasrallah, Chemical vapour deposition of graphene–synthesis, characterisation, and applications: a review. Molecules 25, 3856 (2020)
J. Lim, K. Choi, J.R. Rani, J.S. Kim, C. Lee, J.H. Kim, S.C. Jun, Terahertz, optical, and Raman signatures of monolayer graphene behavior in thermally reduced graphene oxide films. J. Appl. Phys. 113, 183502 (2013)
I.K. Moon, J.I. Kim, H. Lee, K. Hur, W.C. Kim, H. Lee, 2D graphene oxide nanosheets as an adhesive over-coating layer for flexible transparent conductive electrodes. Sci. Rep. 3, 1112 (2013)
T. Zhang, J. Chen, Graphene/InP Schottky junction near-infrared photodetectors. Appl. Phys. A 126, 832 (2020)
H. Tian, A. Hu, Q. Liu, X. He, X. Guo, Interface-induced high responsivity in hybrid graphene/GaAs photodetector. Adv. Opt. Mater. 8, 1901741 (2020)
Y. Zhao, H. Chen, B. Yang, J. Chen, High response plasma-enhanced graphene/GaAs near-infrared photodetector. Mater. Sci. Semicond. Process. 157, 107331 (2023)
A.J. Wirth-Lima, P.P. Alves-Sousa, W. Bezerra-Fraga, Graphene/silicon and 2D-MoS2/silicon solar cells: a review. Appl. Phys. A 125, 241 (2019)
S. Jankauskas, R. Gudaitis, A. Vasiliauskas, A. Guobiene, S. Meskinis, The graphene structure’s effects on the current-voltage and photovoltaic characteristics of directly synthesized graphene/n-Si(100) diodes. Nanomaterials 12, 1640 (2022)
M. Kim, M.A. Rehman, K.M. Kang, Y. Wang, S. Park, H.S. Lee, S.B. Roy, S.H. Chun, C.A. Singh, S.C. Jun, H.H. Park, The role of oxygen defects engineering via passivation of the Al2O3 interfacial layer for the direct growth of a graphene-silicon Schottky junction solar cell. Appl. Mater. Today 26, 101267 (2022)
D.S. Murali, S. Kumar, R.J. Choudhary, A.D. Wadikar, M.K. Jain, A. Subrahmanyam, Synthesis of Cu2O from CuO thin films: optical and electrical properties. AIP Adv. 5, 047143 (2015)
A. Zivkovic, N.H. de Leeuw, Exploring the formation of intrinsic p-type and n-type defects in CuO. Phys. Rev. Mater. 4, 074606 (2020)
J.H. Lee, J. Kim, M. Jin, H.J. Na, H. Lee, C. Im, Y.S. Kim, Cu2O p-type thin-film transistors with enhanced switching characteristics for CMOS logic circuit by controlling deposition condition and annealing in the N2 atmosphere. ACS Appl. Electron. Mater. 5, 1123–1130 (2023)
M.F. Abdullah, N.J.N.B. Nazim, N. Soriadi, S.A.M. Badaruddin, M.R.M. Hussin, M.I. Syono, Thermal characterization of multi-layer graphene heat spreader by Pt/Cu/Ti micro-coil. Phys. Status Solidi A 218, 2100301 (2021)
C.V. Thompson, Solid-state dewetting of thin films. Annu. Rev. Mater. Res. 42, 399–434 (2012)
J.H. Cho, J.J. Gorman, S.R. Na, M. Cullinan, Growth of monolayer graphene on nanoscale copper-nickel alloy thin films. Carbon 115, 441–448 (2017)
M.F. Abdullah, Anti-dewetting of Cu thin film on nanostructured black Si template for continuous CVD growth of monolayer graphene. Mod. Phys. Lett. B 36, 2250108 (2022)
L. Klemeyer, H. Park, J. Huang, Geometry-dependent thermal reduction of graphene oxide solid. ACS Mater. Lett. 3, 511–515 (2021)
M.H. Ani, M.A. Kamarudin, A.H. Ramlan, E. Ismail, M.S. Sirat, M.A. Mohamed, M.A. Azam, A critical review on the contributions of chemical and physical factors toward the nucleation and growth of large-area graphene. J. Mater. Sci. 53, 7095–7111 (2018)
J.B. Wu, M.L. Lin, X. Cong, H.N. Liu, P.H. Tan, Raman spectroscopy of graphene-based materials and its applications in related devices. Chem. Soc. Rev. 47, 1822–1873 (2018)
M.F. Abdullah, S.F.A. Rahman, A.M. Hashim, Investigation on transition diode properties of rGO-GO/n-Si heterojunction. Phys. Status Solidi A 216, 1900064 (2019)
M. Gomaa, G.A. Fattah, Optical properties of graphene oxide thin film reduced by low-cost diode laser. Appl. Phys. A 126, 519 (2020)
A. Sinha, P. Ranjan, A.D. Thakur, Effect of characterization probes on the properties of graphene oxide and reduced graphene oxide. Appl. Phys. A 127, 585 (2021)
M.C. Prado, D. Jariwala, T.J. Marks, M.C. Hersam, Optimization of graphene dry etching conditions via combined microscopic and spectroscopic analysis. Appl. Phys. Lett. 102, 193111 (2013)
M.F. Abdullah, N.J.N.B. Nazim, N.A. Aziz, M.R.M. Hussin, Conversion of vertical-to-planar graphene by morphing of copper nanostructure during a moderate temperature plasma process. Vacuum 206, 111539 (2022)
D. Lopez-Diaz, M. Lopez Holgado, J.L. Garcia-Fierro, M.M. Velazquez, Evolution of the Raman spectrum with the chemical composition of graphene oxide. J. Phys. Chem. C. 121, 20489–20497 (2017)
A.Y. Lee, K. Yang, N.D. Anh, C. Park, S.M. Lee, T.G. Lee, M.S. Jeong, Raman study of D* band in graphene oxide and its correlation with reduction. Appl. Surf. Sci. 536, 147990 (2021)
M.W. Iqbal, M.Z. Iqbal, M.F. Khan, X. Jin, C. Hwang, J. Eom, Modification of the structural and electrical properties of graphene layers by Pt adsorbates. Sci. Technol. Adv. Mater. 15, 055002 (2014)
A. Piazza, F. Giannazzo, G. Buscarino, G. Fisichella, A. La Magna, F. Roccaforte, M. Cannas, F.M. Gelardi, S. Agnello, Graphene p-type doping and stability by thermal treatments in molecular oxygen controlled atmosphere. J. Phys. Chem. C 119, 22718–22723 (2015)
M.M. Haidari, H. Kim, J.H. Kim, M. Park, H. Lee, J.S. Choi, Doping effect in graphene-graphene oxide interlayer. Sci. Rep. 10, 8258 (2020)
J.E. Lee, G. Ahn, J. Shim, Y.S. Lee, S. Ryu, Optical separation of mechanical strain from charge doping in graphene. Nat. Commun. 3, 1024 (2012)
S. Gupta, P. Joshi, J. Narayan, Electron mobility modulation in graphene oxide by controlling carbon melt lifetime. Carbon 170, 327–337 (2020)
P. Gangwar, S. Singh, N. Khare, Study of optical properties of graphene oxide and its derivatives using spectroscopic ellipsometry. Appl. Phys. A 124, 620 (2018)
J. Hu, P. Liu, L. Chen, Comparison of surface plasmon resonance responses to dry/wet air for Ag, Cu, and Au∕SiO2. Appl. Opt. 51, 1357–1360 (2012)
M.F. Abdullah, Defect repair of thermally reduced graphene oxide by gold nanoparticles as a p-type transparent conductor. J. Electron. Mater. 50, 6795–6803 (2021)
R. Negishi, M. Akabori, T. Ito, Y. Watanabe, Y. Kobayashi, Band-like transport in highly crystalline graphene films from defective graphene oxides. Sci. Rep. 6, 28936 (2016)
M. Karyaoui, D. Ben Jemia, M. Daoudi, A. Bardaoui, A. Boukhachem, M. Amlouk, R. Chtourou, Physical properties of graphene oxide GO-doped ZnO thin films for optoelectronic application. Appl. Phys. A 127, 134 (2021)
A. Kocanali, E. Apaydin Varol, An experimental study on the electrical and thermal performance of reduced graphene oxide coated cotton fabric. Int. J. Energy Res. 45, 12915–12927 (2021)
F. Werner, Hall measurements on low-mobility thin films. J. Appl. Phys. 122, 135306 (2017)
R. Cao, H.X. Deng, J.W. Luo, Design principles of p-type transparent conductive materials. ACS Appl. Mater. Interfaces 11, 24837–24849 (2019)
H. Yin, J. Chen, Y. Wang, J. Wang, H. Guo, Composition dependent band offsets of ZnO and its ternary alloys. Sci. Rep. 7, 41567 (2017)
R. Nandee, M.A. Chowdhury, A. Shahid, N. Hossain, M. Rana, Band gap formation of 2D material in graphene: Future prospect and challenges. Results Eng. 15, 100474 (2022)
A. Anand, M.M. Islam, R. Meitzner, U.S. Schubert, H. Hoppe, Introduction of a novel figure of merit for the assessment of transparent conductive electrodes in photovoltaics: exact and approximate form. Adv. Energy Mater. 11, 2100875 (2021)
S. De, J.N. Coleman, Are there fundamental limitations on the sheet resistance and transmittance of thin graphene films? ACS Nano 4, 2713–2720 (2010)
H. Kim, J.S. Horwitz, G. Kushto, A. Pique, Z.H. Kafafi, C.M. Gilmore, D.B. Chrisey, Effect of film thickness on the properties of indium tin oxide thin films. J. Appl. Phys. 88, 6021 (2000)
L. Yang, X. Yu, W. Hu, X. Wu, Y. Zhao, D. Yang, An 8.68% efficiency chemically-doped-free graphene−silicon solar cell using silver nanowires network buried contacts. ACS Appl. Mater. Interfaces 7, 4135–4141 (2015)
Y.T. Lin, D.W. Huang, P.F. Huang, L.C. Chang, Y.T. Lai, N.H. Tai, A green approach for high oxidation resistance, flexible transparent conductive films based on reduced graphene oxide and copper nanowires. Nanoscale Res. Lett. 17, 79 (2022)
L. Dou, F. Cui, Y. Yu, G. Khanarian, S.W. Eaton, Q. Yang, J. Resasco, C. Schildknecht, K. Schierle-Arndt, P. Yang, Solution-processed copper/reduced-graphene-oxide core/shell nanowire transparent conductors. ACS Nano 10, 2600–2606 (2016)
J.H. Kang, S. Choi, Y.J. Park, J.S. Park, N.S. Cho, S. Cho, B. Walker, D.S. Choi, J.W. Shin, J.H. Seo, Cu/graphene hybrid transparent conducting electrodes for organic photovoltaic devices. Carbon 171, 341–349 (2021)
R. Zhang, Y. Liao, Y. Zhou, J. Qian, A facile and economical process for high-performance and flexible transparent conductive film based on reduced graphene oxides and silver nanowires. J. Nanopart. Res. 22, 39 (2020)
L. He, S.C. Tjong, Silver-decorated reduced graphene oxides as novel building blocks for transparent conductive films. RSC Adv. 7, 2058–2065 (2017)
J. Ning, L. Hao, M. Jin, X. Qiu, Y. Shen, J. Liang, X. Zhang, B. Wang, X. Li, L. Zhi, A facile reduction method for roll-to-roll production of high performance graphene-based transparent conductive films. Adv. Mater. 29, 1605028 (2017)
M. Savchak, N. Borodinov, R. Burtovyy, M. Anayee, K. Hu, R. Ma, A. Grant, H. Li, D.B. Cutshall, Y. Wen, G. Koley, W.R. Harrell, G. Chumanov, V. Tsukruk, I. Luzinov, Highly conductive and transparent reduced graphene oxide nanoscale films via thermal conversion of polymer-encapsulated graphene oxide sheets. ACS Appl. Mater. Interfaces 10, 3975–3985 (2018)
K. Sa, P. Mahanandia, Conducting reduced graphene oxide film as transparent electrode. Thin Solid Films 692, 137594 (2019)
Funding
This project is internally funded by MIMOS Semiconductor (M) Sdn. Bhd.
Author information
Authors and Affiliations
Contributions
MFA conceptualization, methodology, investigation, formal analysis, visualization, writing- original draft preparation, writing—reviewing and editing.
Corresponding author
Ethics declarations
Conflict of interest
The author declares no known competing financial interests or personal relationships that could have appeared to influence the present work.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Abdullah, M.F. Appealing optoelectronic properties of p-type Cu-G transparent conductor prepared by Cu sputtering and thermal reduction of graphene oxide. Appl. Phys. A 129, 694 (2023). https://doi.org/10.1007/s00339-023-06986-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-023-06986-3