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Sonochemical-assisted synthesis of α-Fe2O3 nanoparticles and their photocatalytic activity toward methylene blue and methyl orange dyes

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Abstract

In this work, a facile and low-cost sonochemical-assisted route accompanied by calcination is used for the synthesis of α-Fe2O3 nanoparticles using Fe(NO3)3·9H2O as iron precursor, oxalic acid and polyvinyl pyrrolidone (PVP) as fuel and surfactant. The as-synthesized α-Fe2O3 nanoparticles were characterized using Fourier transform infrared (FT-IR) spectroscopy, X-ray powder diffraction (XRD), vibrating sample magnetometer (VSM) and transmission electron microscope (TEM) and the results confirmed the preparation of single phase of rhombohedral α-Fe2O3 nanoparticles with quasi-spherical shapes and ferromagnetic properties. The studies of photocatalytic degradation of rhombohedral α-Fe2O3 nanoparticles were performed using methylene blue (MB) and methyl orange (MO) dyes in aqueous solution under visible light irradiation. The effect of the important parameters such as pH solution, catalyst dose and contact time was investigated. Under optimum conditions, the efficiency of MB and MO degradation reaches to 93 and 88% for Fe-1 and 91 and 84% for Fe-2, respectively. In addition, the photodegradation of MB and MO dyes using the as-synthesized spherical α-Fe2O3 nanoparticles was evaluated using the pseudo-first-order kinetic model.

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References

  1. C.N.C. Hitam, A.A. Jalil, A reviwe on exploration of Fe2O3 photocatalyst towards degradation of dyes and organic contaminants. J. Environ. Manage. 258, 110050 (2020)

    Article  Google Scholar 

  2. M. Hakimi, M. Morvaridi, H.A. Hosseini, P. Alimard, Preparation, characterization, and photocatalytic activity of Bi2O3-Al2O3 nanocomposite. Polyhedron 170, 523–529 (2019)

    Article  Google Scholar 

  3. J. Wang, X. Shao, Q. Zhang, G. Tian, X. Ji, W. Bao, Preparation of mesoporous magnetic Fe2O3 nanoparticle and its application for organic dyes removal. J. Mol. Liq. 248, 13–18 (2017)

    Article  Google Scholar 

  4. K.G. Pavithara, S. Kumar, V. Jaikumar, Removal of colorants from wastewater: a review on sources and treatment strategies. J. Ind. Eng. Chem. 75, 1–19 (2019)

    Article  Google Scholar 

  5. M.A. Mohd Adnan, N. Muhd Julhapli, M.N.I. Amir, A. Maamor, Effect on different TiO2 photocatalyst supports on photodecolorization of synthetic dyes: A review. Int. J. Environ. Sci. Technol. 16, 547–566 (2019)

    Article  Google Scholar 

  6. M. Bilal, H.M.N. Iqbal, D. Barcelo, Persistence of pesticides-based contaminants in the environment and their effective degradation using laccase-assisted biocatalytic systems. Sci. Total Environ. 695, 133896 (2019)

    Article  ADS  Google Scholar 

  7. M. Punzi, F. Nilsson, A. Anbalagan, B.M. Svensson, K. Jonsson, B. Mattiasson, M. Jonstrup, Combined anaerobic-ozonation process for treatment of textile wastewater: removal of acute toxicity and mutagenicity. J. Hazard. Mater. 292, 52–60 (2015)

    Article  Google Scholar 

  8. K. Wang, A.A. Abdalla, M.A. Khaleel, N. Hilal, M.K. Kharisheh, mechanical properties of water desalination and wastewater treatment membranes. Desalination 401, 190–205 (2017)

    Article  Google Scholar 

  9. J.C. Cardoso, G.G. Bessegato, M.V.B. Zanoni, Efficiency comparision of ozonation, photolysis, photocatalysis and photoelectrocatalysis methods in real textile wastewater decolorization. Water Res. 98, 39–46 (2016)

    Article  Google Scholar 

  10. C. Byrne, G. Subramanian, S.C. Pillai, Recent advances in photocatalysis for environmental applications. J. Environ. Chem. Eng. 6, 3531–3555 (2018)

    Article  Google Scholar 

  11. G. Crini, E. Lichtfouse, Advantage and disadvantages of techniques used for wastewater treatmwnt. Environ. Chem. Lett. 17, 145–155 (2019)

    Article  Google Scholar 

  12. N.C. Cinperi, E. Ozturk, N.O. Yigit, M. Kitis, Treatment of woolen textile wastewater using membrane bioreactor, nanofiltration and reverse osmosis for reuse in production processes. J. Clean. Prod. 223, 837–848 (2019)

    Article  Google Scholar 

  13. M. Madkour, O.G. Allam, A.A. Nazeer, M.O. Amin, E. Al-Hetlani, CeO2-based nanoheterostructures with p-n and n-n heterojunction arrangements for enhancing the solar-driven photodegradation of rhodamine 6G dye. J. Mater. Sci: Mater. Electron. 30, 10857–10866 (2019)

    Google Scholar 

  14. A. Lassoued, M.S. Lassoued, B. Dkhill, S. Ammar, A. Gadri, Photocatalytic degradation of methyl orange dye by NiFe2O4 nanoparticles under visible irradiation: effect of varying the synthesis temperature. J. Mater. Sci: Mater. Electron. 29, 7057–7067 (2018)

    Google Scholar 

  15. S.S. Kumar, K. Lellala, M. Ashok, A. Priyadharsan, C. Sanjeeviraja, A. Rajendran, Green synthesis of CeO2-TiO2 compound using Cleome chelidonii leaf extract for excellent photocatalytic activity. J. Mater. Sci: Mater. Electron. 29, 14022–14030 (2018)

    Google Scholar 

  16. M. Vatanparast, L. Saedi, Sonochemical-assisted synthesis and characterization of CeO2 nanoparticles and its photocatalytic properties. J. Mater. Sci: Mater. Electron. 29, 7107–7113 (2018)

    Google Scholar 

  17. A. Lassoued, M.S. Lassoued, B. Dkhill, S. Ammar, A. Gadri, Nanocrystalline NixCo(0.5-x)Zn0.5Fe2O4 ferrites: fabrication through co-precipitation route with enhanced structural, magnetic and photocatalytic activity. J. Mater. Sci: Mater. Electron. 29, 7333–7344 (2018)

    Google Scholar 

  18. Y. Bian, G. Zheng, W. Ding, L. Hu, Z. Sheng, Magnetic field effect on the photocatalytic degradation of methyl orange by commercial TiO2 powder. RSC Adv. 11, 6284–6291 (2021)

    Article  ADS  Google Scholar 

  19. A. Kusior, K. Michalec, P. Jelen, M. Radecka, Shaped Fe2O3 nanoparticles-Synthesis and anhanced photocatalytic degradation towards RhB. App. Surf. Sci. 476, 342–352 (2019)

    Article  ADS  Google Scholar 

  20. R. Khurram, Z. Wang, M.F. Ehsan, α-Fe2O3-based nanocomposites: synthesis, characterization, and photocatalytic response towards wastewater treatment. Environ. Sci. Pollut. Res. 28, 17697–17711 (2021)

    Article  Google Scholar 

  21. C. Ye, K. Hu, Z. Niu, Y. Lu, L. Zhang, K. Yan, Controllable synthesis of rhombohedral α-Fe2O3 efficient for photocatalytic degradation of bisphenol A. J. Water Process Eng. 27, 205–210 (2019)

    Article  Google Scholar 

  22. R. Kumar, G. Kumar, M.S. Akhtar, A. Umar, Sonophotocatalytic degradation of methyl orange using ZnO nano-aggregates. J. All. Compd. 629, 167–172 (2015)

    Article  Google Scholar 

  23. N.B. Bokhale, S.D. Bomble, R.R. Dalbhanjan, D.D. Mahale, S.P. Hinge, B.S. Banerjee, A.V. Mohod, P.R. Gogate, Sonocatalytic and sonophotocatalytic degradation of rhodamine 6G containing wastewaters. Ultrason. Sonochem. 21, 1797–1804 (2014)

    Article  Google Scholar 

  24. A.M. Mazrouaa, M.G. Mohamed, M. Fekry, Physical and magnetic properties of iron oxide nanoparticles with a different molar ratio of ferrous and ferric, Egypt. J. Petrol. 28, 165–171 (2019)

    Google Scholar 

  25. M. Jamzad, M. Kamari Bidkorpeh, Green synthesis of iron oxide nanoparticles by the aqueous extract of Laurus nobilis L. Leaves and evalution of the antimicrobial activity. J. Nanostruct. Chem. 10, 193–201 (2020)

    Article  Google Scholar 

  26. E. Rostamizadeh, A. Iranbakhsh, A. Majd, S. Arbabian, I. Mehregan, Green synthesis of Fe2O3 nanoparticles using fruit extract of Cornus mas L. And its growth-promoting roles in Barley. J. Nanostruct. Chem. 10, 125–130 (2020)

    Article  Google Scholar 

  27. P.N.V. Kumar Pallela, S. Ummey, L.K. Ruddaraju, S. Gadi, C.S. Cherukuri, S. Barla, S.V.N. Pammi, Antibacterial efficiency of green synthesized α-Fe2O3 nanoparticles using Sida cordifolia plant extract. Heliyon 5, e02765 (2019)

    Article  Google Scholar 

  28. A.D. Khalaji, P. Machek, M. Jarosova, α-Fe2O3 nanoparticles: synthesis, characterization, magnetic properties and photocatalytic degradation of methyl orange. Adv. J. Chem. A 4, 317–326 (2021)

    Google Scholar 

  29. A.D. Khalaji, S.M. Mousavi, M. Jarosova, P. Machek, The effect of calcination temperature on the morphology, size and the crystalline phase of the as-synthesized products by direct calcination of FeSO4 at the presence of benzoic acid. J. Surf. Invest: X-ray Synch. Neutron Techniq. 14, 1191–1194 (2020)

    Article  Google Scholar 

  30. A.D. Khalaji, M. Ghorbani, Thermal studies of iron (II) Schiff base complexes: new precursors for preparation of α-Fe2O3 nanoparticles via solid-state thermal decomposition. Chem. Method. 4, 532–542 (2020)

    Article  Google Scholar 

  31. A. Lassoued, M.S. Lassoued, B. Dkhil, S. Ammar, Synthesis, photoluminescence and magnetic properties of iron oxide (α-Fe2O3) nanoparticle through precipitation of hydrothermal methods. Phys. E. 101, 212–219 (2018)

    Article  Google Scholar 

  32. R.N. Araujo, E.P. Nascimento, H.C.T. Firmino, D.A. Macedo, G.A. Neves, M.A. Morales, R.R. Menezes, α-Fe2O3 fibers: An efficient photocatalyst for dye degradation under visible light. J. All. Compd. 882, 160683 (2021)

    Article  Google Scholar 

  33. A.D. Khalaji, Spherical α-Fe2O3 nanoparticle: Synthesis and characterization and its photocatalytic degradation of methyl orange and methylene blue. Phys. Chem. Res. 10, 473–483 (2022)

    Google Scholar 

  34. N.K. Gupta, Y. Ghaffari, J. Bae, K.S. Kim, Synthesis of coral-like α-Fe2O3 nanoparticle for dye degradation at neutral pH. J. Mol. Liq. 301, 112473 (2020)

    Article  Google Scholar 

  35. G.K. Weldegebrieal, A.K. Sibhatu, Photocatalytic activity of biosynthesized α-Fe2O3 nanoparticle for the degradation of methylene blue and methyl orange dyes. Optik 241, 167226 (2021)

    Article  ADS  Google Scholar 

Download references

Acknowledgements

The work is supported by Operational Programme Research, Development and Education financed by European Structural and Investment Funds and the Czech Ministry of Education, Youth and Sports (Project No. SOLID21 CZ.02.1.01/0.0/0.0/16_019/0000760).

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Authors and Affiliations

  1. Department of Chemistry, Dr. A.P.J. Abdul Kalam University, Indore, India

    Reena Solanki

  2. Institute of Physics of the Czech Academy of Sciences, V.V.I., Na Slovance 2, 182 21, Prague 8, Czech Republic

    Marketa Jarosova & Pavel Machek

  3. Department of Medical Instruments Engineering Techniques, Al-Farahidi University, Baghdad, Iraq

    Waleed Khalid Al-Azzawi

  4. Medical Physics Department, Al-Mustaqbal University College, 51001, Hillah, Babil, Iraq

    Forat H. Alsultany

  5. Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran

    Aliakbar Dehno Khalaji

  6. Al-Nisour University College, Baghdad, Iraq

    Zuhair I. Al Mashhadani

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  1. Reena Solanki
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Solanki, R., Jarosova, M., Al-Azzawi, W.K. et al. Sonochemical-assisted synthesis of α-Fe2O3 nanoparticles and their photocatalytic activity toward methylene blue and methyl orange dyes. Appl. Phys. A 128, 741 (2022). https://doi.org/10.1007/s00339-022-05826-0

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