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Effect of samarium (Sm3+) doping on structural, optical, dielectric and magnetic nature of La1.95Y0.05NiMnO6 double perovskite

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Abstract

Herein, we report La1.95Y0.05NiMnO6 and La1.9Sm0.05Y0.05NiMnO6 double perovskite multiferroic materials synthesized by solid-state reaction technique, which are XRD characterized for structural and phase formation studies. Rietveld refinement of XRD diffraction data infers that the samples are highly crystalline and have acquired the monoclinic structure (P 1 21/n 1). The analysis of Williamson-Hall’s plot revealed that both the samples have acquired higher crystallite size and higher tensile strain. The Raman modes at around 540–665 cm−1 presented anti-symmetric stretching and symmetric stretching modes, respectively confirming monoclinic phase. Isothermal dielectric constant study in the temperature range of 300–100 K with applied ac field varying from 100 Hz to 2 MHz infer that these samples exhibit good dielectric constant with lower loss values. Semiconducting nature of the double perovskites under observation, was verified by magnetic field dependent electrical (dc) resistivity exploiting four-probe technique. Low magnetic moment was observed with linear nature for field values in both positive and negative directions carried out at room temperature. The polarization (P–E loops) study of both the samples show their lossy nature.

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Acknowledgements

Authors acknowledge UGC DAE CSR Indore as an institute for extending characterization facilities. Dr. D. M. Phase, Center Director, Dr. Mukul Gupta, Dr. Rajeev Rawat, and Dr. V. R. Reddy are acknowledged with gratitude for all the characterizations here. Special thanks are extended to the concerned engineers and researcher scholars there for guidance and fruitful discussions.

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  1. School of Physics, Vigyan Bhavan, Devi Ahilya University, Khandwa Road Campus, Indore, 452001, India

    Niketa Bajpai, Mohd. Saleem & Ashutosh Mishra

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  1. Niketa Bajpai
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Correspondence to Mohd. Saleem.

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Bajpai, N., Saleem, M. & Mishra, A. Effect of samarium (Sm3+) doping on structural, optical, dielectric and magnetic nature of La1.95Y0.05NiMnO6 double perovskite. Appl. Phys. A 127, 723 (2021). https://doi.org/10.1007/s00339-021-04874-2

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