Abstract
Ce-doped α-Fe2O3 nanoparticles were successfully synthesized by hydrothermal method at different pH. The relationship between the pH of the solution and the morphology, structure and electrochemical stability of the prepared Ce-doped α-Fe2O3 nanoparticles was investigated by X-ray diffraction, transmission electron microscopy, scanning electron microscope, Fourier transform infrared, X-ray photoelectron spectroscopy, electrochemical methods and saltwater immersion experiment. The results showed that the Ce-doped α-Fe2O3 nanoparticles prepared at pH = 4 and pH = 6 had surface defects structure, and the Ce-doped α-Fe2O3 nanoparticles prepared at pH = 8 had adhesion structures, which were CeO2 nanoparticles adhered to the α-Fe2O3 nanoparticles’ surface. The fact that Ce ions could be readily doped into the α-Fe2O3 lattice, causing lattice distortion and increasing the binding energy of Fe3+ in the lattice, thereby enhancing the stability of Fe–O bonds correspondingly. At the same time, the surface defect structure is produced, which has the effect of promoting the compactness of the coating. The surface defects structure of α-Fe2O3 has stronger electrochemical stability than the adhesion structure of α-Fe2O3 and Bayer α-Fe2O3. It was found that waterborne acrylic coatings prepared from of α-Fe2O3 with surface defects structure had a stronger hindering effect on the diffusion of charged ions.
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References
D.R. Baer, P.E. Burrows, A.A. El-Azab, Enhancing coating functionality using nanoscience and nanotechnology. Prog. Org. Coat. 47, 342–356 (2003). https://doi.org/10.1016/S0300-9440(03)00127-9
A. Mathiazhagan, R. J. I. J. o. C. E. Joseph and Applications, Nanotechnology-a New prospective in organic coating-review. Int. J. Chem. Eng. Appl. 2, 225 (2011)
P. Xu, G.M. Zeng, D.L. Huang, C.L. Feng, S. Hu, M.H. Zhao, C. Lai, Z. Wei, C. Huang, G.X.J.S.O.T.T.E. Xie, Use of iron oxide nanomaterials in wastewater treatment: a review. Sci. Total Environ. 424, 1–10 (2012). https://doi.org/10.1016/j.scitotenv.2012.02.023
L.S. Zhong, J.S. Hu, H.P. Liang, A.M. Cao, W.G. Song, L.J. Wan, Self-assembled 3D flowerlike iron oxide nanostructures and their application in water treatment. Adv. Mater. 18, 2426–2431 (2006). https://doi.org/10.1016/10.1002/adma.200600504
M. Ramaprakash, G. Sreedhar, S. Mohan, S. Panda, Corrosion protection studies of CeO2-TiO2 nanocomposite coatings on mild steel. Trans. IMF 94, 254–258 (2016). https://doi.org/10.1080/00202967.2016.1209892
M. Sorescu, L. Diamandescu, V. Teodorescu, Structure and characterization of cerium-doped hematite nanoparticles. Phys. B (Amsterdam, Neth.) 403, 3838–3845 (2008). https://doi.org/10.1016/j.physb.2008.07.027
G. Zhao, J. Li, X. Niu, K. Tang, S. Wang, W. Zhu, X. Ma, M. Ru, Y. Yang, Facile synthesis of Mn-doped Fe2O3 nanostructures: enhanced CO catalytic performance induced by manganese doping. New J. Chem. 40, 3491–3498 (2016). https://doi.org/10.1039/c5nj03694a
J. Lai, K.V. Shafi, K. Loos, A. Ulman, Y. Lee, T. Vogt, C. Estournès, Doping γ-Fe2O3 nanoparticles with Mn (III) suppresses the transition to the α-Fe2O3 structure. J. Am. Chem. Soc. 125, 11470–11471 (2003). https://doi.org/10.1021/ja035409d
J. Zhang, H. Kumagai, K. Yamamura, S. Ohara, S. Takami, A. Morikawa, H. Shinjoh, K. Kaneko, T. Adschiri, A. Suda, Extra-low-temperature oxygen storage capacity of CeO2 nanocrystals with cubic facets. Nano Lett. 11, 361–364 (2011). https://doi.org/10.1021/nl102738n
J. Ning, P. Shi, M. Jiang, C. Liu, Z. Jia, Synthesis and characterization of cerium oxide/iron oxide nanocomposite and its surface acid-base characteristics. J. Environ. Chem. Eng. 9, 105540 (2021). https://doi.org/10.1016/j.jece.2021.105540
N.A. Dharanipragada, M. Meledina, V.V. Galvita, H. Poelman, S. Turner, G. Van Tendeloo, C. Detavernier, G.B. Marin, Deactivation study of Fe2O3-CeO2 during redox cycles for CO production from CO2. Ind. Eng. Chem. Res. 55, 5911–5922 (2016). https://doi.org/10.1021/acs.iecr.6b00963
X. Mou, B. Zhang, Y. Li, L. Yao, X. Wei, D.S. Su, W. Shen, Rod-shaped Fe2O3 as an efficient catalyst for the selective reduction of nitrogen oxide by ammonia. Angew. Chem. Int. Ed. 51, 2989–2993 (2012). https://doi.org/10.1002/anie.201107113
A. Lassoued, M.S. Lassoued, B. Dkhil, A. Gadri, S. Ammar, Structural, optical and morphological characterization of Cu-doped α-Fe2O3 nanoparticles synthesized through co-precipitation technique. J. Mol. Struct. 1148, 276–281 (2017). https://doi.org/10.1016/j.molstruc.2017.07.051
L. Wang, T. Fei, Z. Lou, T. Zhang, Three-dimensional hierarchical flowerlike α-Fe2O3 nanostructures: synthesis and ethanol-sensing properties. ACS Appl. Mater. Interfaces. 3, 4689–4694 (2011). https://doi.org/10.1021/am201112z
A.H. Haviv, J.-M. Grenèche, J.-P. Lellouche, Aggregation control of hydrophilic maghemite (γ-Fe2O3) nanoparticles by surface doping using cerium atoms. J. Am. Chem. Soc. 132, 12519–12521 (2010). https://doi.org/10.1021/ja103283e
Y. Ni, X. Ge, Z. Zhang, Q. Ye, Fabrication and characterization of the plate-shaped γ-Fe2O3 nanocrystals. Chem. Mater. 14, 1048–1052 (2002). https://doi.org/10.1021/cm010446u
J. Qiu, C. Liu, Solid phase equilibrium relations in the CaO-SiO2-Nb2O5-La2O3 system at 1273 K. Metall. Mater. Trans. B. 49, 69–77 (2018). https://doi.org/10.1007/s11663-017-1144-0
B. Zhang, C. Liu, C. Li, M. Jiang, A novel approach for recovery of rare earths and niobium from bayan obo tailings. Miner. Eng. 65, 17–23 (2014). https://doi.org/10.1016/j.mineng.2014.04.011
B. Zhang, C. Liu, C. Li, M. Jiang, Separation and recovery of valuable metals from low-grade REE-Nb-Fe ore. Int. J. Miner. Process. 150, 16–23 (2016). https://doi.org/10.1016/j.minpro.2016.03.004
C. Liu, J. Qiu, Phase equilibrium relations in the specific region of CaO-SiO2-La2O3 system. J. Eur. Ceram. Soc. 38, 2090–2097 (2018). https://doi.org/10.1016/j.jeurceramsoc.2017.12.011
X. Yang, X. Lian, S. Liu, J. Tian, C. Jiang, G. Wang, J. Chen, R. Wang, Investigation of enhanced photoelectrochemical property of cerium doped hematite film prepared by sol-gel route. Int. J. Electrochem. Sci. 8, 3721–3730 (2013)
C. Yilmaz, U. Unal, Morphology and crystal structure control of α-Fe2O3 films by hydrothermal-electrochemical deposition in the presence of Ce3+ and/or acetate F- ions. RSC Adv. 6, 8517–8527 (2016). https://doi.org/10.1039/c5ra20105e
M. Ferreira, R. Duarte, M. Montemor, A. Simões, Silanes and rare earth salts as chromate replacers for pre-treatments on galvanised steel. Electrochim. Acta. 49, 2927–2935 (2004). https://doi.org/10.1016/j.electacta.2004.01.051
S. Li, Q. Wang, T. Chen, Z. Zhou, Y. Wang, J. Fu, Study on cerium-doped nano-TiO2 coatings for corrosion protection of 316 L stainless steel. Nanoscale Res. Lett. 7, 1–9 (2012). https://doi.org/10.1186/1556-276x-7-227
T. Wang, G. Yang, J. Liu, B. Yang, S. Ding, Z. Yan, T. Xiao, Orthogonal synthesis, structural characteristics, and enhanced visible-light photocatalysis of mesoporous Fe2O3/TiO2 heterostructured microspheres. Appl. Surf. Sci. 311, 314–323 (2014). https://doi.org/10.1016/j.apsusc.2014.05.060
G. Yang, B. Yang, T. Xiao, Z. Yan, One-step solvothermal synthesis of hierarchically porous nanostructured CdS/TiO2 heterojunction with higher visible light photocatalytic activity. Appl. Surf. Sci. 283, 402–410 (2013). https://doi.org/10.1016/j.apsusc.2013.06.122
J. Ning, P. Shi, M. Jiang, C. Liu, X. Li, Effect of Ce doping on the structure and chemical stability of nano-α-Fe2O3. Nanomaterials 9, 1039 (2019). https://doi.org/10.3390/nano9071039
D. Wang, L. Jin, Y. Li, D. Yao, J. Wang, H. Hu, Upgrading of vacuum residue with chemical looping partial oxidation over Ce doped Fe2O3. Energy 162, 542–553 (2018). https://doi.org/10.1016/j.energy.2018.08.038
X. Wang, T. Wang, G. Si, Y. Li, S. Zhang, X. Deng, X. Xu, Oxygen vacancy defects engineering on Ce-doped α-Fe2O3 gas sensor for reducing gases. Sens. Actuators, B Chem. 302, 127165 (2020). https://doi.org/10.1016/j.snb.2019.127165
L. Guo, H. Arafune, N.J.L. Teramae, Synthesis of mesoporous metal oxide by the thermal decomposition of oxalate precursor. Langmuir 29, 4404–4412 (2013). https://doi.org/10.1021/la400323f
C. Yu, X. Dong, L. Guo, J. Li, F. Qin, L. Zhang, J. Shi, D. Yan, Template-free preparation of mesoporous Fe2O3 and its application as absorbents. J. Phys. Chem. C. 112, 13378–13382 (2008). https://doi.org/10.1021/jp8044466
F. Perez-Alonso, I. Melián-Cabrera, M.L. Granados, F. Kapteijn, J.G. Fierro, Synergy of FexCe1-xO2 mixed oxides for N2O decomposition. J. Catal. 239, 340–346 (2006). https://doi.org/10.1016/j.jcat.2006.02.008
J. Kurian, M. Naito, Growth of epitaxial CeO2 thin films on r-cut sapphire by molecular beam epitaxy. Phys. C (Amsterdam, Neth.) 402, 31–37 (2004). https://doi.org/10.1016/j.physc.2003.08.007
A. Ubale, M. Belkhedkar, Size dependent physical properties of nanostructured α-Fe2O3 thin films grown by successive ionic layer adsorption and reaction method for antibacterial application. J. Mater. Sci. Technol. (Sofia, Bulg.) 31, 1–9 (2015). https://doi.org/10.1016/j.jmst.2014.11.011
I. Lee, J.K. Cho, H.S. Kim, K.S. Kim, Ab initio studies on the correlation of force constant vs bond length in the transition state of methyl-transfer reactions. J. Phys. Chem. 94, 5190–5193 (1990)
R. Liu, X. Yang, C.L. Anfuso, Z. Huang, L. Han, Plasmonic α-Fe2O3 photoanodes for solar water splitting. Rev. Adv. Sci. Eng. 3, 331–339 (2014). https://doi.org/10.1166/rase.2014.1079
R. Reveendran, M.A. Khadar, Structural, optical and electrical properties of Cu doped α-Fe2O3 nanoparticles. Mater. Chem. Phys. 219, 142–154 (2018). https://doi.org/10.1016/j.matchemphys.2018.08.016
P. Shikha, B. Randhawa, T.S. Kang, Greener synthetic route for superparamagnetic and luminescent α-Fe2O3 nanoparticles in binary mixtures of ionic liquid and ethylene glycol. RSC Adv. 5, 51158–51168 (2015). https://doi.org/10.1039/c5ra07218b
F. Meng, L. Wang, J. Cui, Controllable synthesis and optical properties of nano-CeO2 via a facile hydrothermal route. J. Alloys Compd. 556, 102–108 (2013). https://doi.org/10.1016/j.jallcom.2012.12.096
L. Cui, J. Cui, H. Zheng, Y. Wang, Y. Qin, X. Shu, J. Liu, Y. Zhang, Y. Wu, Construction of NiO/MnO2/CeO2 hybrid nanoflake arrays as platform for electrochemical energy storage. J. Power Sources 361, 310–317 (2017). https://doi.org/10.1016/j.jpowsour.2017.07.013
L. Wang, F. Meng, K. Li, F. Lu, Characterization and optical properties of pole-like nano-CeO2 synthesized by a facile hydrothermal method. Appl. Surf. Sci. 286, 269–274 (2013). https://doi.org/10.1016/j.apsusc.2013.09.067
A. Cabral, L. Cavalcante, R. Deus, E. Longo, A. Simões, F. Moura, Photoluminescence properties of praseodymium doped cerium oxide nanocrystals. Ceram. Int. 40, 4445–4453 (2014). https://doi.org/10.1016/j.ceramint.2013.08.117
F. Meng, J. Gong, Z. Fan, H. Li, J. Yuan, Hydrothermal synthesis and mechanism of triangular prism-like monocrystalline CeO2 nanotubes via a facile template-free hydrothermal route. Ceram. Int. 42, 4700–4708 (2016). https://doi.org/10.1016/j.ceramint.2015.11.123
R. Si, M. Flytzani-Stephanopoulos, Shape and crystal-plane effects of nanoscale ceria on the activity of Au-CeO2 catalysts for the water–gas shift reaction. Angew. Chem. 120, 2926–2929 (2008). https://doi.org/10.1002/anie.200705828
M. Konsolakis, Z. Ioakimidis, T. Kraia, G.E. Marnellos, Hydrogen production by ethanol steam reforming (ESR) over CeO2 supported transition metal (Fe Co, Ni, Cu) catalysts: insight into the structure-activity relationship. Catalysts 6, 39 (2016). https://doi.org/10.3390/catal6030039
K. Zhou, X. Wang, X. Sun, Q. Peng, Y. Li, Enhanced catalytic activity of ceria nanorods from well-defined reactive crystal planes. J. Catal. 229, 206–212 (2005). https://doi.org/10.1016/j.jcat.2004.11.004
H.-X. Mai, L.-D. Sun, Y.-W. Zhang, R. Si, W. Feng, H.-P. Zhang, H.-C. Liu, C.-H. Yan, Shape-selective synthesis and oxygen storage behavior of ceria nanopolyhedra, nanorods, and nanocubes. J. Phys. Chem. B. 109, 24380–24385 (2005). https://doi.org/10.1021/jp055584b
X.-S. Huang, H. Sun, L.-C. Wang, Y.-M. Liu, K.-N. Fan, Y. Cao, Morphology effects of nanoscale ceria on the activity of Au/CeO2 catalysts for low-temperature CO oxidation. Appl. Catal., B 90, 224–232 (2009). https://doi.org/10.1016/j.apcatb.2009.03.015
S. Pourhashem, F. Saba, J. Duan, A. Rashidi, F. Guan, E.G. Nezhad, B. Hou, Polymer/Inorganic nanocomposite coatings with superior corrosion protection performance: a review. J. Ind. Eng. Chem. (2020). https://doi.org/10.1016/j.jiec.2020.04.029
X. Shi, T.A. Nguyen, Z. Suo, Y. Liu, R. Avci, Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating. Surf. Coat. Technol. 204, 237–245 (2009). https://doi.org/10.1016/j.surfcoat.2009.06.048
V. Sumi, S. Arunima, M. Deepa, M.A. Sha, A. Riyas, M. Meera, V.S. Saji, S. Shibli, PANI-Fe2O3 composite for enhancement of active life of alkyd resin coating for corrosion protection of steel. Mater. Chem. Phys. 247, 122881 (2020). https://doi.org/10.1016/j.matchemphys.2020.122881
Acknowledgements
This work was supported by the National Natural Science Foundation of China [51874082], National Key R&D Program of China [2017YFC0805100] and Open project supported by the key laboratory for ecological metallurgy of multimetallic ores (Ministry of Education) [NEMM2019002]. Thanks are due to Yingying Yue and Jiyu Qiu for providing language help and writing assistance.
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Ning, J., Shi, P., Jiang, M. et al. Ce-doped α-Fe2O3 nanoparticles prepared by hydrothermal method used in corrosion-resistant field: effects of pH on the structure, morphology and chemical stability. Appl. Phys. A 127, 604 (2021). https://doi.org/10.1007/s00339-021-04766-5
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DOI: https://doi.org/10.1007/s00339-021-04766-5