Abstract
Thin Pb films were grown by pulsed laser deposition on Si(111) at various laser fluences, pulse wavelengths, deposition time, and substrate temperatures. Scanning electron microscopy and ex situ atomic force microscopy were used to probe the surface morphology and structure. At room temperature, increasing the laser fluence and/or the pulse wavelength triggers the transformation from the “worm”-like interconnected islands to granular, separated islands. Increasing the substrate temperature to slightly below the Pb melting temperature results in the formation of large, nearly spherical non-wetting islands. Additionally, ultrathin Pb (111) films were grown at room temperature, which resulted in a small number of nearly 2D islands due to the emerging quantum size effect. Our results show that pulsed laser deposition can be used effectively for controlled growth of Pb thin films.
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V.A. Grazhulis, W.G. Schmidt, F. Bechstedt, G.P. Srivastava, Adsorption of group-V elements on III–V (1 1 0) surfaces. Surf. Sci. Rep. 25, 141 (1996)
Y.-F. Zhang, J.-F. Jia, Z. Tang, T.-Z. Han, X.-C. Ma, Q.-K. Xue, Growth, stability and morphology evolution of Pb films on Si(111) prepared at low temperature. Surf. Sci. 596(1), L331–L338 (2005)
M.M. Ozer, C.-Z. Wang, Z. Zhang, H.H. Weitering, Quantum size effects in the growth, coarsening, and properties of ultra-thin metal films and related nanostructures. J. Low Temp. Phys. 157, 221–251 (2009)
W.B. Su, C.S. Chang, T.T. Tsong, Quantum size effect on ultra-thin metallic films. J. Phys. D Appl. Phys. 43, 013001 (2010)
M. Li, J.W. Evans, C.Z. Wang, M. Hupalo, M.C. Tringides, T.L. Chan, K.M. Ho, Strongly-driven coarsening of height-selected Pb islands on Si(111). Surf. Sci. 601, L140–L144 (2007)
Y. Han, D.-J. Liu, Quantum size effects in metal nanofilms: comparison of an electron-gas model and density functional theory calculations. Phys. Rev. B 80, 155404 (2009)
J. Smedley, T. Rao, J. Sekutowicz, Lead photocathodes. Phys. Rev. Spec. Top. Accel. Beams 11(1), 013502 (2008)
D.H. Dowell, I. Bazarov, B. Dunham, K. Harkay, C.H. Garcia, R. Legg, H. Padmore, T. Rao, J. Smedley, W. Wan, Cathode R&D for future light sources. Nucl. Instrum. Methods Phys. Res. Sect. A Accel. Spectrom. Detect. Assoc. Equip. 622(3), 685–697 (2010)
F. Gontad, A. Lorusso, G. Gatti, M. Ferrario, L.G. Passione, L. Persano, N. Lovergine, A. Perrone, Characterization of photocatodes based on Pb thin film deposited by UV pulsed laser ablation. J. Mater. Sci. Technol. 30, 37 (2014)
A. Lorusso, F. Gontad, E. Broitman, E. Chiadroni, A. Perrone, Characterisation of Pb thin films prepared by the nanosecond pulsed laser deposition technique for photocathode application. Thin Solid Films 579, 50–56 (2015)
A. Lorusso, F. Gontad, L. Solombrino, E. Chiadroni, E. Broitman, A. Perrone, Tight comparison of Mg and Y thin film photocathodes obtained by the pulsed laser deposition technique. Nucl. Inst. Methods Phys. Res. Sect. A Accel. Spectrom. Detect. Assoc. Equip. 836, 57–60 (2016)
A. Lorusso, F. Gontad, A. Perrone, N. Stankova, Highlights on photocathodes based on thin films prepared by pulsed laser deposition. Phys. Rev. Spec. Top. Accel. Beams 14, 090401 (2011)
A. Lorusso, F. Gontad, A.P. Caricato, E. Chiadroni, E. Broitman, A. Perrone, Structural and morphological properties of metallic thin films grown by pulsed laser deposition for photocathode application. Appl. Phys. A 122, 162 (2016)
D. Velázquez, R. Seibert, H. Ganegoda, D. Olive, A. Rice, K. Logan, Z. Yusof, L. Spentzouris, J. Terry, Tailoring the emissive properties of photocathodes through materials engineering: ultra-thin multilayers. Appl. Surf. Sci. 360, 762 (2016)
A.H. Sommer, Photoemissive Materials (Wiley, New York, 1968), pp. 21–26
F. Gontad, A. Lorusso, A. Klini, A. Loufardaki, M. Panareo, C. Fotakis, A. Perrone, Picosecond and subpicosecond pulsed laser deposition of Pb thin films. Phys. Rev. Accel. Beams 16, 093401–093406 (2013)
J.C. Miller, Laser Ablation: Principles and Applications (Springer, Berlin, 1994)
R. Eason, Pulsed Laser Deposition of Thin Film Applications (Wiley, Hoboken, 2007)
J. Schubert, M. Siegert, M. Fardmanesh, W. Zander, M. Prompers, C. Buchal, J. Lisoni, C.H. Lei, Superconducting and electro-optical thin films prepared by pulsed laser deposition technique. Appl. Surf. Sci. 168(1–4), 208–214 (2000)
F. Gontad, A. Lorusso, A. Klini, A. Loufardaki, M. Panareo, C. Fotakis, A. Perrone, Picosecond and subpicosecond pulsed laser deposition of Pb thin films. Phys. Rev. Spec. Top. Accel. Beams 16(9), 093401 (2013)
D.B. Chrisey, G.K. Hubler, Pulsed Laser Deposition of Thin Films (Wiley, New York, 1994)
D. Dijkkamp, T. Venkatesan, Preparation of Y-Ba-Cu oxide superconductor thin films using pulsed laser evaporation from high Tc bulk material. Appl. Phys. Lett. 51, 619 (1987)
P. Mele, K. Matsumoto, T. Horide, O. Miura, A. Ichinose, M. Mukaida, Y. Yoshida, S. Horii, Tuning of the critical current in YBa2Cu3O7−x thin films by controlling the size and density of Y2O3 nanoislands on annealed SrTiO3 substrates. Supercond. Sci. Technol. 19, 44–50 (2006)
P. Badica, K. Togano, S. Awaji, K. Watanabe, Growth of superconducting MgB2 films by pulsed-laser deposition using a Nd–YAG laser. Supercond. Sci. Technol. 19(2), 242 (2006)
A. Venimadhav, M.S. Hegde, R. Rawat, I. Das, M. El Marssi, Enhancement of magnetoresistance in La0.67Ca0.33MnO3/Pr0.7Ca0.3MnO3 epitaxial multilayers. J. Alloys Compd. 326(1-2), 270–274 (2001)
A.O. Er, W. Ren, H.E. Elsayed-Ali, Low temperature epitaxial growth of Ge quantum dot on Si(100)-(2 × 1) by femtosecond laser excitation. Appl. Phys. Lett. 98(1), 013108 (2011)
C.H. Hur, K.B. Han, K.A. Joen, S.Y. Lee, Enhancement of the dielectric properties of Pb(La, Ti)O3 thin films fabricated by pulsed laser deposition. Thin Solid Films 400(1–2), 169–171 (2001)
I.N. Mihailescu, V.S. Teodorescu, E. Gyorgy, A. Luches, A. Perron, M. Martino, About the nature of particulates covering the surface of thin films obtained by reactive pulsed laser deposition. J. Phys. D Appl. Phys. 31, 2236–2240 (1998)
W.-O. Siew, W.-K. Lee, H.-Y. Wong, T.-K. Yong, S.-S. Yap, T.-Y. Tou, Investigation of droplet formation in pulsed Nd:YAG laser deposition of metals and silicon. Appl. Phys. A 101, 627–632 (2010)
S.J. Barrington, T. Bhutta, D.P. Shepherd, R.W. Eason, The effect of particulate density on performance of Nd:Gd3Ga5O12 waveguide lasers grown by pulsed laser deposition. Opt. Commun. 185, 145–152 (2000)
S. Fähler, M. Störmer, H.U. Krebs, Origin and avoidance of droplets during laser ablation of metals. Appl. Surf. Sci. 109–110, 433–436 (1997)
D.L. Price, V. Henner, M. Khenner, Morphologies, metastability and coarsening of quantum nanoislands on the surfaces of the annealed Ag(110) and Pb(111) thin films. J. Appl. Phys. 124, 174302 (2018)
A. Liu, Z. Shi, R.G. Reddy, Electrodeposition of Pb from PbO in urea and 1-butyl-3methylimidazolium chloride deep eutectic solutions. Electrochim. Acta 251, 176–186 (2017)
J. Senavaitiene, J. Smirnova, A. Beganskiene, A. Kareiva, XRD and FTIR characterisation of lead oxide-based pigments and glazes. Acta Chim. Slov. 54, 185–193 (2007)
F. Gontad, A. Lorusso, M.D. Guilio, F. Eriksson, E. Broitman, A. Perrone, Growth of lead thin films on silicon and niobium substrates by sputtering technique. J. Vac. Sci. Technol. A 35, 031502 (2017)
Acknowledgements
Devon Loomis, Vladimir Dobrokhotov, and Mikhail Khenner were supported by Kentucky NSF EPSCoR (Grant No. 3200000271-18-069), and Ali Oguz Er was supported by Kentucky NSF EPSCoR (Grant No. 3200000271-16-039).
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Abdisatarov, B., Ilhom, S., Kholikov, K. et al. Morphology and structure of Pb thin films grown on Si(111) by pulsed laser deposition. Appl. Phys. A 126, 237 (2020). https://doi.org/10.1007/s00339-020-3414-y
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DOI: https://doi.org/10.1007/s00339-020-3414-y