Skip to main content
Log in

Effect of methyl orange dye molecule on the structural, optical and electrical properties of the KHOOD single crystals

  • Rapid communications
  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

In the present investigation, synthesis of pristine and methyl orange dye-doped potassium hydrogen oxalate oxalic acid dihydrate (KHOOD) single crystals are reported. In this study, the structural properties of the crystals were investigated using powder XRD and the effect of dye incorporation on the KHOOD crystal was explored in detail. The effect of dye molecule on the optical absorption of the crystal was studied and the optical band gap was calculated using Tauc relation and presented in detail. Further, the effect on emission and mechanical properties of the crystals were also explored after doping with the dye molecule. Furthermore, the crystals were also studied electrically by subjecting to varying electrical frequencies (A.C) and the properties of pristine and doped crystals were compared and explained in detail. The modulus properties of the crystals were studied and compared.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

References

  1. M. Shkir, V. Ganesh, S. AlFaify, A. Black, E. Dieguez, K.K. Maurya, Cryst. Growth Des. 18, 2046–2054 (2018)

    Google Scholar 

  2. S. Kumar, B. Kumar, Cryst Eng Comm 20, 624 (2018)

    Google Scholar 

  3. K. Mahendra, N.K. Udayashankar, J. Phys. Chem. Solids 138, 109263 (2019)

    Google Scholar 

  4. R. Punniyamoorthy, R. Suganthi, R. Manimekalai, G. Pasupathi, Asian J. Chem. 30, 2731 (2018)

    Google Scholar 

  5. M. Anis, M.D. Shirsat, G. Muley, S.S. Hussaini, Phys. B Condens. Matter 449, 61 (2014)

    ADS  Google Scholar 

  6. P. Kanchana, A. Elakkina Kumaran, Y. Hayakawa, C. Sekar, Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 103, 187 (2013)

    ADS  Google Scholar 

  7. B.M. Boaz, S.M. Navis Priya, J.M. Linet, P.M. Deva Prasath, S.J. Das, Opt. Mater. 29, 827 (2007)

    ADS  Google Scholar 

  8. R. Rajasekaran, P.M. Ushasree, R. Jayavel, P. Ramasamy, J. Cryst. Growth 229, 563 (2001)

    ADS  Google Scholar 

  9. L. Ruby Nirmala, J. Thomas Joseph Prakash, Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 110, 249 (2013)

    ADS  Google Scholar 

  10. N.P.R.V. Kannan, J. Cryst. Growth 269, 565 (2004)

    ADS  Google Scholar 

  11. K. Mahendra, N.K. Udayashankar, Int. J. Mod. Phys. B 34, 2050002 (2019)

    ADS  Google Scholar 

  12. G.H. Nancollas, G.L. Gardner, J. Cryst. Growth 21, 267 (1974)

    ADS  Google Scholar 

  13. C. Ramki, R. Ezhil Vizhi, Mater. Chem. Phys. 197, 70 (2017)

    Google Scholar 

  14. D.J. Hodgson, J.A. Ibers, Acta Crystallogr. B 25, 469 (1969)

    Google Scholar 

  15. A. Eriksson, O.F. Nielsen, J. Mol. Struct. 48, 343 (1978)

    ADS  Google Scholar 

  16. K.V. Bangera, P.M. Rao, Bull. Mater. Sci. 15, 339 (1992)

    Google Scholar 

  17. C. Bridle, T.R. Lomer, Acta Crystallogr. 19, 483 (1965)

    Google Scholar 

  18. P.V. Dalal, K.B. Saraf, Bull. Mater. Sci. 29, 421 (2006)

    Google Scholar 

  19. K.S. Raju, K.N. Krishna, J. Issac, M.A. Ittyachen, Bull. Mater. Sci. 17, 1447 (1994)

    Google Scholar 

  20. B.F. Pedersen, Acta Crystallogr. B 28, 746 (1972)

    Google Scholar 

  21. C. Joseph, M.A. Ittyachen, K.S. Raju, Bull. Mater. Sci. 20, 37 (1997)

    Google Scholar 

  22. K. Mahendra, K.S. Bhat, H.S. Nagaraja, N.K. Udayashankar, J. Mater. Sci. Mater. Electron. 30, 12566 (2019)

    Google Scholar 

  23. M.A. Ahlam, M.N. Ravishankar, N. Vijayan, G. Govindaraj, V. Upadhyaya, A.P.G. Prakash, J. Opt. 41, 158 (2012)

    Google Scholar 

  24. K. Mahendra, K.K. Nayak, B.J. Fernandes, N.K. Udayashankar, J. Mater. Sci. Mater. Electron. 29, 18905 (2018)

    Google Scholar 

  25. N. Jagannatha, P. Mohan Rao, Bull. Mater. Sci. 16, 365 (1993)

    Google Scholar 

  26. E. Takasaki, Y. Naito, Nihon Hinyokika Gakkai Zasshi Jpn. J. Urol. 59, 1117 (1968)

    Google Scholar 

  27. R.D. Stewart, Clin. Chem. Lab. Med. 49, 1405 (2011)

    Google Scholar 

  28. M. Lalia-Kantouri, G.E. Manoussakis, J. Therm. Anal. 29, 1151 (1984)

    Google Scholar 

  29. R. Cammi, M. Lanfranchi, L. Marchiò, C. Mora, C. Paiola, M.A. Pellinghelli, Inorg. Chem. 42, 1769 (2003)

    Google Scholar 

  30. A.M. Goforth, M.D. Smith, L. Peterson, H.-C. Zur Loye, Inorg. Chem. 43, 7042 (2004)

    Google Scholar 

  31. L. Balazs, H.J. Breunig, E. Lork, A. Soran, C. Silvestru, Inorg. Chem. 45, 2341 (2006)

    Google Scholar 

  32. D.F. Swinehart, J. Chem. Educ. 39, 333 (1962)

    Google Scholar 

  33. B.D. Viezbicke, S. Patel, B.E. Davis, D.P. Birnie, Phys. Status Solidi B 252, 1700 (2015)

    ADS  Google Scholar 

  34. X.-T. Yin, J. Li, D. Dastan, W.-D. Zhou, H. Garmestani, F.M. Alamgir, Sens. Actuators B Chem. 319, 128330 (2020)

    Google Scholar 

  35. X.-T. Yin, W.-D. Zhou, J. Li, P. Lv, Q. Wang, D. Wang, F. Wu, D. Dastan, H. Garmestani, Z. Shi, Ş. Ţălu, J. Mater. Sci. Mater. Electron. 30, 14687 (2019)

    Google Scholar 

  36. W.-D. Zhou, D. Dastan, J. Li, X.-T. Yin, Q. Wang, Nanomaterials 10, 785 (2020)

    Google Scholar 

  37. D. Dastan, Appl. Phys. A 123, 699 (2017)

    ADS  Google Scholar 

  38. M. Shkir, S. AlFaify, Sci. Rep. 7, 16091 (2017)

    ADS  Google Scholar 

  39. M. Shkir, V. Ganesh, I.S. Yahia, H.S.M. Abd-Rabboh, S. Alfaify, J. Phys. Chem. Solids 123, 336–343 (2018)

    ADS  Google Scholar 

  40. S. Gahlawat, J. Singh, A. Kumar Yadav, P.P. Ingole, Phys. Chem. Chem. Phys. 21, 20463 (2019)

    Google Scholar 

  41. R. Shakoury, A. Arman, Ş. Ţălu, D. Dastan, C. Luna, S. Rezaee, Opt. Quantum Electron. 52, 1 (2020)

    Google Scholar 

  42. A. Jafari, K. Tahani, D. Dastan, S. Asgary, Z. Shi, X.-T. Yin, W.-D. Zhou, H. Garmestani, Ş. Ţălu, Surf. Interfaces 18, 100463 (2020)

    Google Scholar 

  43. M. Anis, S.S. Hussaini, A. Hakeem, M.D. Shirsat, G.G. Muley, Optik 127, 2137 (2016)

    ADS  Google Scholar 

  44. S. Sasi, R. Robert, S. Arumugam, C. Inmozhi, Optik 127, 2366 (2016)

    ADS  Google Scholar 

  45. J. Dalal, B. Kumar, Opt. Mater. 51, 139 (2016)

    ADS  Google Scholar 

  46. J.R. Lakowicz, Principles of Fluorescence Spectroscopy, 3rd edn. (Springer, US, 2006)

    Google Scholar 

  47. S. Gopinath, S. Barathan, R. Rajasekaran, Adv. Mater. Res. 584, 112–115 (2012)

    Google Scholar 

  48. O. Sahin, O. Uzun, U. Kolemen, N. Ucar, Mater. Charact. 58, 197 (2007)

    Google Scholar 

  49. K. Mahendra, J.M. Fernandes, N.K. Udayashankar, J. Therm. Anal. Calorim. (2020). https://doi.org/10.1007/s10973-020-09965-5

    Article  Google Scholar 

  50. M. Lawrence, J.J.P. Thomas, Spectrochim. Acta. A. Mol. Biomol Spectrosc. 91, 30 (2012)

    ADS  Google Scholar 

  51. L. Liu, Y. Sheng, M. Liu, M. Dienwiebel, Z. Zhang, D. Dastan, Tribol. Int. 140, 105727 (2019)

    Google Scholar 

  52. B.M. Boaz, S.M. Navis Priya, J.M. Linet, P.M. Deva Prasath, S.J. Das, Opt. Mater. 29, 827 (2007)

    ADS  Google Scholar 

  53. S.M. Attia, M.S. Abdelfatah, M.M. Mossad, J. Phys. Conf. Ser. 869, 012035 (2017)

    Google Scholar 

  54. S. Panchapakesan, K. Subramani, B. Srinivasan, Optik 157, 774 (2018)

    ADS  Google Scholar 

  55. C.K. Madhusudhan, K. Mahendra, B.S. Madhukar, T.E. Somesh, M. Faisal, Synth. Met. 267, 116450 (2020)

    Google Scholar 

  56. J. Yang, X. Zhu, H. Wang, X. Wang, C. Hao, R. Fan, D. Dastan, Z. Shi, Compos. Part Appl. Sci. Manuf. 131, 105814 (2020)

    Google Scholar 

  57. L. Sun, Z. Shi, H. Wang, K. Zhang, D. Dastan, K. Sun, R. Fan, J. Mater. Chem. A 8, 5750 (2020)

    Google Scholar 

  58. K. Mahendra, H.K.T. Kumar, N.K. Udayashankar, Appl. Phys. A 125, 228 (2019)

    ADS  Google Scholar 

  59. K. Mahendra, N.K. Udayashankar, Phys. Lett. A 384, 126475 (2020)

    Google Scholar 

  60. S. Raju, S. Kanagathara, D.R. Babu, R. Muralidharan, H. Krishnan, Mater. Res. Innov. 20, 439 (2016)

    Google Scholar 

  61. K. Shan, Z.-Z. Yi, X.-T. Yin, D. Dastan, H. Garmestani, Dalton Trans. 49, 6682 (2020)

    Google Scholar 

  62. K. Shan, Z.-Z. Yi, X.-T. Yin, D. Dastan, H. Garmestani, Dalton Trans. 49, 8549 (2020)

    Google Scholar 

  63. S.F. Mansour, M.A. Abdo, J. Magn. Magn. Mater. 428, 300 (2017)

    ADS  Google Scholar 

  64. H.M.T. Farid, I. Ahmad, I. Ali, S.M. Ramay, A. Mahmood, G. Murtaza, J. Magn. Magn. Mater. 434, 143 (2017)

    ADS  Google Scholar 

  65. R. Vaish, K.B.R. Varma, J. Appl. Phys. 106, 064106 (2009)

    ADS  Google Scholar 

  66. H. Chouaib, N. Elfaleh, S. Karoui, S. Kamoun, M.P.F. Graça, Synth. Met. 217, 129 (2016)

    Google Scholar 

  67. F. Borsa, D.R. Torgeson, S.W. Martin, H.K. Patel, Phys. Rev. B 46, 795 (1992)

    ADS  Google Scholar 

  68. A.K. Behera, N.K. Mohanty, S.K. Satpathy, B. Behera, P. Nayak, Open Phys. (2014). https://doi.org/10.2478/s11534-014-0523-2

    Article  Google Scholar 

  69. R.J. Sengwa, S. Sankhla, S. Choudhary, Ionics 16, 697 (2010)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to K. Mahendra.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mahendra, K., Pujar, S. & Udayashankar, N.K. Effect of methyl orange dye molecule on the structural, optical and electrical properties of the KHOOD single crystals. Appl. Phys. A 126, 728 (2020). https://doi.org/10.1007/s00339-020-03859-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00339-020-03859-x

Keywords

Navigation