Abstract
A new composition of MoTaxNbVTi (x = 0.25, 0.50, 0.75 and 1.00 at.%) high-entropy alloy was prepared by vacuum arc melting technique. The produced structures were thoroughly analyzed in terms of their microstructural features, followed by a complementary evaluation of their phase formation prediction models. The alloys’ crystal structure was also examined. Both hardness values and compression data were selected in order to postulate the related strengthening and fracture modes. Hardness values were within the range of 55–58 HRC, and the compression modulus varied between 49 and 62 GPa. Finally, the systems were evaluated concerning their tribological response, after the conduction of dry-sliding wear tests. The wear rates showed values between 0.19 ± 0.012 and 0.38 ± 0.038 g/N‧m‧10–6, and the friction coefficient was within the range of 0.571—0.773 following the same trend of the wear rate values. The wear mechanisms were highlighted in every case, based on the numerical data derived and the examination of the worn surfaces and debris.
Similar content being viewed by others
References
Y. Lu, Y. Dong, S. Guo, L. Jiang, H. Kang, T. Wang, B. Wen, Z. Wang, J. Jie, Z. Cao, H. Ruan, T. Li: Sci. Rep., 2014, vol 4, pp. 6200–1–6200–5.
D.B. Miracle, O. Senkov, Acta Mater. 122, 448–511 (2017)
D.B. Miracle, J.D. Miller, O.N. Senkov, C. Woodward, M.D. Uchic, J. Tiley, Entropy 16, 494–525 (2014)
J.W. Yeh, S.K. Chen, J.W. Gan, S.J. Lin, T.S. Chin, T.T. Shun, C.H. Tsau, S.Y. Chang, Metall. Mater. Trans. A 35, 2533–2536 (2004)
E.J. Pickering, N.G. Jones, Int. Mater. Rev. 61, 183–202 (2016)
M.H. Tsai, Entropy 15, 5338–5345 (2013)
D.B. Miracle, Nat. Commun. 10, 18051–18053 (2019)
Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, Z.P. Lu, Prog. Mat. Sci. 61, 1–93 (2014)
E.P. George, D. Raabe, R.O. Ritchie, Nat. Rev. Mater. 4, 515–534 (2019)
W. Zhang, P.K. Liaw, Y. Zhang, Sci. China Mater. 61, 2–22 (2018)
R. Feng, M.C. Gao, C. Lee, M. Mathes, T. Zuo, S. Chen, J.A. Hawk, Y. Zhang, P.K. Liaw, Entropy 18, 333–354 (2016)
J.Q. Yao, X.W. Liu, N. Gao, Q.H. Jiang, N. Lia, G. Liu, W.B. Zhang, Z.T. Fan, Intermetallics 98, 79–88 (2018)
L. Raman, K. Guruvidyathri, G. Kumari, S.V.S. Murty, R.S. Kottada, B.S. Murty, J. Mater. Res. 34, 756–766 (2019)
Y. Zhang, Y. Zhou, Mater. Sci. Forum 561, 1337–1339 (2007)
Z. Wang, Y. Huang, Y. Yang, J. Wang, C.T. Liu, Scripta Mater. 94, 28–31 (2015)
S. Guo, C.T. Liu, Prog. Nat. Sci. 21, 433–446 (2011)
M.C. Troparevsky, J.R. Morris, M. Daene, Y. Wang, A.R. Lupini, G.M. Stocks, JOM 67, 2350–2375 (2015)
D.J.M. King, S.C. Middleburgh, A.G. McGregor, M.B. Cortie, Acta Mater. 104, 172–179 (2016)
O. Senkov, D.B. Miracle, J. Alloys Compd. 658, 603–607 (2016)
F. Tian, Front. Mater. 4, 1–10 (2017)
S. Gorsse, J.P. Couzinié, D.B. Miracle, CR Phys. 19, 721–736 (2018)
A. Gali, E.P. George, Intermetallics 39, 74–78 (2013)
G. Qin, R. Chen, P.K. Liaw, Y. Gao, X. Li, H. Zheng, L. Wang, Y. Su, J. Guo, H. Fu, Scripta Mat. 172, 51–55 (2019)
S. Sinha, S.S. Nene, M. Frank, K. Liu, R.S. Mishra, B.A. McWilliams, K.C. Cho, Metal. Mater. Trans. A. 50, 179–190 (2019)
O.N. Senkov, D.B. Miracle, K.J. Chaput, J.P. Couzinie, J. Mater. Res. 33, 3092–3128 (2018)
H.W. Yao, J.W. Qiao, J.A. Hawk, H.F. Zhou, M.W. Chen, M.C. Gao, J. Alloys Compd. 696, 1139–1150 (2017)
A. Shabani, M.R. Toroghinejad, A. Shafyei, R.E. Logé, Mater. Chem. Phys. 221, 68–77 (2019)
B. Wang, A. Fu, X. Huang, B. Liu, Y. Liu, Z. Li, X. Zan, J. Mater. Eng. Perform. 25, 2985–2992 (2016)
R. Labusch, Acta Metall. 20, 917–927 (1972)
L.A. Gypen, A. Deruyttere, Scripta Metall. 15, 815–820 (1981)
O.N. Senkov, J.M. Scott, S.V. Senkova, D.B. Miracle, C.F. Woodward, J. Alloy. Comp. 509, 6043–6048 (2011)
H.W. Yao, J.W. Qiao, J.A. Hawk, H.F. Zhou, M.W. Chen, M.C. Gao, J. Alloy. Comp. 696, 1139–1150 (2016)
F.G. Coury, M. Kaufman, A.J. Clarke, Acta Mater. 175, 66–81 (2019)
W. Chen, Z. Fu, S. Fang, H. Xiao, D. Zhu, Mater. Des. 51, 854–860 (2013)
Z. Wang, X. Wang, H. Yue, G. Shi, S. Wang, Mater. Sci. Eng. A 627, 391–398 (2015)
Y. Yu, J. Wang, J. Li, H. Kou, H. Duan, J. Li, W. Liu, Tribol. Int. 92, 203–210 (2015)
L.M. Du, L.W. Lan, S. Zhu, H.J. Yang, X.H. Shi, P.K. Liaw, J.W. Qiao, J. Mater. Sci. Technol. 35, 917–925 (2019)
R. Zhou, G. Chen, B. Liu, J. Wang, L. Han, Y. Liu, Int. J. Refract. Met. H. 75, 56–62 (2018)
S. Alvi, F. Akhtar, Wear 426–427, 412–419 (2019)
C. Mathiou, A. Poulia, E. Georgatis, A.E. Karantzalis, Mater. Chem. Phys. 210, 126–135 (2018)
A. Poulia, E. Georgatis, A. Lekatou, A.E. Karantzalis, Adv. Eng. Mater. 19, 1600351–16003510 (2017)
A. Poulia, E. Georgatis, A.E. Karantzalis, Met. Mater. Int. 210, 1–12 (2019)
D.M. Herlach, Mater. Sci. Forum 539, 1977–1982 (2007)
A. Karma, Int. J. Non Equilibr. Process. 11, 201–233 (1998)
MTDATA—Phase Diagram Software from the National Physical Laboratory, https://resource.npl.co.uk/mtdata/phdiagrams/tav.htm.
X. Lin, Y.Q. Cao, Z.T. Wang, J. Cao, L.L. Wang, W.D. Huang, Acta Mater. 126, 210–220 (2017)
A. Leo, C. Hansch, D. Elkins, Chem. Rev. 71, 525–616 (1971)
O.N. Senkov, G.B. Wilks, D.B. Miracle, C.P. Chuang, P.K. Liaw, Intermetallics 18, 1758–1765 (2010)
O.N. Senkov, J.M. Scott, S.V. Senkova, D.B. Miracle, C.F. Woodward, J. Alloy Compd. 509, 6043–6048 (2011)
X. Yang, Y. Zhang, P.K. Liaw, Proc. Eng. 36, 292–298 (2011)
K.B. Zhang, Z.Y. Fu, J.Y. Zhang, W.M. Wang, H. Wang, Y.C. Wang, Q.J. Zhang, J. Shi, Mat Sci Eng A. 508, 214–219 (2009)
O.N. Senkov, G.B. Wilks, J.M. Scott, D.B. Miracle, Intermetallics 19, 698–706 (2011)
U. Roy, H. Roy, H. Daoud, U. Glatzel, K.K. Ray, Mater. Lett. 132, 186–189 (2014)
Y. Zhang, Y. Liu, Y. Li, X. Chen, H. Zhang, Mater. Lett. 174, 82–85 (2016)
L. Ma, C. Li, Y. Jiang, J. Zhou, L. Wang, F. Wang, T. Cao, Y. Xue, J. Alloys Compd. 694, 61–67 (2017)
S.P. Wang, J. Xu, Mater. Sci. Eng. C 73, 80–89 (2017)
N. Larianovsky, A. Kovalevsky, A. Katz-Demyanetz, M. Regev, Materials 10, 1–12 (2017)
Y. Chen, Y. Li, X. Cheng, C. Wu, B. Cheng, Z. Xu, Materials 11, 208–219 (2018)
Z.D. Han, H.W. Luan, S.F. Zhao, N. Chen, R.X. Peng, Y. Shao, K.F. Yao, Chin. Phys. Lett. 35, 0361021–0361025 (2018)
T.T. Shun, W.J. Hung, Adv. Mater. Sci. Eng. 6, 1–7 (2018)
M. Zhang, X. Zhou, W. Zhu, J. Li, Met. Mater. Trans. A 49, 1313–1327 (2018)
J. Joseph, N. Stanford, P. Hodgson, D.M. Fabijanic, Scripta Mater. 129, 30–34 (2017)
D. Hull, J. Mater. Sci. Lett. 15, 651–653 (1996)
Y. Ivanisenko, L. Kurmanaeva, J. Weissmueller, K. Yang, J. Markmann, H. Rösner, T. Scherer, H.J. Fecht, Acta Mater. 57, 3391–3401 (2009)
E. Sommer, Eng. Fract. Mech. 1, 539–546 (1969)
D. Hull, Int. J. Fract. 70, 59–79 (1995)
B. Gludovatz, A. Hohenwarter, K.V.S. Thurston, H. Bei, Z. Wu, E.P. George, R.O. Ritchie, Nat. Commun. 7, 106021–106028 (2016)
L. Lu, X. Chen, X. Huang, K. Lu, Science 323, 607–610 (2009)
M.J. Tobar, J.M. Amado, C. Álvarez, A. García, A. Varela, A. Yáñez, Surf. Coat. Tech. 202, 2297–2301 (2008)
D.H. Buckley, Surface Effects in Adhesion, Friction, Wear, and Lubrication (Elsevier Scientific Pub. Co., Amsterdam, 1981)
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Petroglou, D., Poulia, A., Mathiou, C. et al. A further examination of MoTaxNbVTi (x = 0.25, 0.50, 0.75 and 1.00 at.%) high-entropy alloy system: microstructure, mechanical behavior and surface degradation phenomena. Appl. Phys. A 126, 364 (2020). https://doi.org/10.1007/s00339-020-03566-7
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-020-03566-7