Abstract
In this paper, X-ray diffraction, selective area electron diffraction, and transmission electron microscope (TEM) were used to study the twins at different positions and textures in different direction in CVDZnS. It was found that the CVDZnS twin showed streaks under TEM. The narrower the streaks, the higher the content of twins, and the content of twins in CVDZnS normal layer was higher than that in bright layer. There are textures in CVDZnS, and the main texture of P surface (perpendicular to the direction of growth) is different from S surface (parallel to the growth direction of surface). The main texture in P is {010} 〈001〉, and the S is {101} 〈\(\overline{1} \overline{3}\)1〉.
This is a preview of subscription content, log in via an institution to check access.
References
S. Musikant, Optical Materials—an Introduction to Selection and Application (Marcel Dekker, New York, 1985)
Y. Drezner, S. Berger, M. Hefetz et al., A correlation between microstructure, composition and optical transparency of CVD-ZnS. Mater. Sci. Eng., B 87, 59–65 (2001)
J. Mccloy, R.W. Tustison, Chemical Vapor Deposited Zinc Sulfide[M] (2013)
J.A. Savage, C.J.H. Wort, C.S.J. Pickles et al., Properties of free-standing CVD diamond optical components. Proc. SPIE Int. Soc. Opt. Eng. 3060, 144–15 (1997)
J. Mccloy, E. Fest, R. Korenstein, et al. Anisotropy in structural and optical properties of chemical vapor deposited ZnS, 2011 (2011)
D.C. Harris, Development of hot and chemical-vapor-deposited zinc sulfide and zinc selenide in United states for optical windows. SPIE, 654502:1-10
D.W. Blodgett, M.E. Thomas, D.V. Hahn et al., Longwave infrared absorption properties of ZnS and ZnSe. Proc. SPIE Int. Soc. Opt. Eng. 5078, 137–147 (2003)
P. Kiocek, J.T. Hoggins, Broad band IR transparent rain erosion protection coating for IR windows. Window Dome Technol. Mater. SPIE 1760, 210 (1992)
Taylor, et al. Process for Improved Laminates of ZnSe and ZnS. US5183689, 1993-02-02
F. Long, W.M. Wang, Z. Cui et al., An improved method for chemical bath deposition of ZnS thin films. J. Chem. Phys. Lett. 462(1), 84–87 (2008).
J. Mccloy, International development of chemical vapor deposited zinc sulfide, 2007. SPIE (2007)
T. Bansagi, E.A. Secco, O.K. Srivastava, R.R. Martin, Kinetics of hexagonal-cubic phase transformation of zinc sulfide in vacuo, in zinc vapor, and in sulfur vapor. Can. J. Chem. 46(18), 2881–2886 (1968)
S. Akeuchi, K. Suzuki, K. Maeda et al., Stacking-fault energy of II–VI compounds. Philos. Mag. A 50(2), 171–178 (1985)
J. McCloy, R. Korenstein, Variability in chemical vapor deposited zinc sulfide: assessment of legacy and international CVD ZnS materials. Proc. SPIE 7302, 73020M (2009)
H. Hartmann, L. Hildisch, E. Krause, Morphological stability and crystal structure of CVD-grown zinc selenide. J. Mater. Sci. 26, 4917–4923 (1991)
J.A. Savage, K.L. Lewis, A.M. Pitt, R.H.L. Whitehouse, The role of a CVD research reactor in studies of the growth and physical properties of ZnS infrared optical material. Proc. SPIE 0505, 47–51 (1984)
A.F. Shchurov et al., Structure and mechanical properties of polycrystalline zinc sulfide. Inorg. Mater. 40(2), 96–101 (2004)
T. Zscheckel, W. Wisniewski, C. Rüssel, Microstructure and texture of polycrystalline CVD-ZnS analyzed via EBSD. Adv. Funct. Mater. 22(23), 4969–4974 (2012)
M.T. Sebastian, P. Krishna, An X-ray diffraction study of faulting in single crystals of cubic ZnS grown from the vapour phase. Philos. Mag. A 49(6), 809–821 (1984)
M.B. Geilikman, Mechanisms of polytype stabilization during the wurtzite-sphalerite transition. Phys. Chem. Miner. 8(1), 2–7 (1982)
F.S. Daragona, P. Delavignette, S. Amelinckx, Direct evidence for the mechanism of the phase transition Wurtzite–Sphalerite. Phys. Status Solidi 14(2), K115–K118 (2010)
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
