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Nanoscale studies of magnetoelectric coupling in multiferroic BTO–CFO composite

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Abstract

We report on the existence of interacting ferromagnetic and ferroelectric nanodomains in multiferroic 0.65BaTiO3–0.35CoFe2O4 (BTO–CFO) composite synthesized using a conventional solid-state route. X-ray diffraction study shows the coexistence of individual phases (BTO and CFO) of the composite material. Nanometric studies on the sample pellet of BTO–CFO composite are carried out using Scanning Probe Microscopy (SPM) to probe local ferroelectric and magnetic ordering. Importantly, the interactive nanodomains of individual phases are distinctly seen in the Atomic Force Acoustic Microscopy (AFAM) and Piezo-Force Microscopy (PFM) studies, which are done to investigate the magnetoelectric coupling in the BTO–CFO composite. Elasticity maps and piezoresponse images show local inhomogeneities with respect to the distribution of magnetoelectric coupling in the composite.

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References

  1. D.N. Astrov, The magnetoelectric effect in antiferromagnetics. Sov. Phys. JETP. 11, 708–709 (1960)

    Google Scholar 

  2. D.N. Astrov, Magnetoelectric effect in chromium oxide. Sov. Phys. JETP. 13, 729–733 (1961)

    Google Scholar 

  3. W. Eerenstein, N.D. Mathur, J.F. Scott, Multiferroic and magnetoelectric materials. Nature. 442, 759–765 (2006)

    Article  ADS  Google Scholar 

  4. M. Fiebig, Revival of the magnetoelectric effect. J. Phys. D. Appl. Phys. 38, R123 (2005)

    Article  ADS  Google Scholar 

  5. V.C. Flores, D.B. Baques, D.C. Flores, J.A.M. Aquino, Enhanced magnetoelectric effect in core-shell particulate composites. J. Appl. Phys. 99, 08J503 (2006)

    Article  Google Scholar 

  6. R.A. Islam, Y. Ni, A.G. Khachaturyan, S. Priya, Giant magnetoelectric effect in sintered multilayered composite structures. J. Appl. Phys. 104, 044103 (2008)

    Article  ADS  Google Scholar 

  7. K.P. Jayachandran, J.M. Guedes, H.C. Rodrigues, Solutions for maximum coupling in multiferroic magnetoelectric composites by material design. Sci. Rep. 8, 4866 (2018)

    Article  ADS  Google Scholar 

  8. R.V. Krishnaiah, A. Srinivas, S.V. Kamat, T. Karthik, S. Asthana, Effect of CoFe2O4 mole percentage on multiferroic and magnetoelectric properties of Na0.5Bi0.5TiO3/CoFe2O4 particulate composites. Ceram. Int. 40, 7799–7804 (2014)

    Article  Google Scholar 

  9. M. Liu, X. Li, J. Lou, S. Zheng, K. Dui, N.X. Sun, A modified sol-gel process for multiferroic nanocomposite films. J. Appl. Phys. 102, 083911 (2007)

    Article  ADS  Google Scholar 

  10. L.W. Martin, A.M. Rappe, Thin-film ferroelectric materials and their applications. Nat. Rev. Mater. 2, 16087 (2016)

    Article  ADS  Google Scholar 

  11. V.R. Mudinepalli, S.H. Song, B.S. Murty, Enhanced magnetoelectric properties in lead-free Ni0.83Co0.15Cu0.02Fe1.9O4 − δ-Na0.5Bi0.5TiO3 composites by spark plasma sintering. Scr. Mater. 82, 9–12 (2014)

    Article  Google Scholar 

  12. C.W. Nan, M.I. Bichurin, S. Dong, D. Viehland, G. Srinivasan, Multiferroic magnetoelectric composites: historical perspective, status, and future directions. J. Appl. Phys. 103, 031101 (2008)

    Article  ADS  Google Scholar 

  13. M. Naveed-Ul-Haq, V.V. Shvartsman, S. Salamon, H. Wende, H. Trivedi, A. Mumtaz, D.C. Lupascu, A new (Ba,Ca)(Ti,Zr)O3 based multiferroic composite with large magnetoelectric effect. Sci. Rep. 6, 32164 (2016)

    Article  ADS  Google Scholar 

  14. V.M. Petrov, G. Srinivasan, T.A. Galkina, Microwave magnetoelectric effects in bilayers of single crystal ferrite and functional graded piezoelectric. J. Appl. Phys. 104, 113910 (2008)

    Article  ADS  Google Scholar 

  15. E.V. Ramana, F. Figueiras, M.P.F. Graca, M.A. Valente, Observation of magnetoelectric coupling and local piezoresponse in modified (Na0.5Bi0.5)TiO3-BaTiO3-CoFe2O4 lead-free composites. Dalton. Trans. 43, 9934–9943 (2014)

    Article  Google Scholar 

  16. J. Ryu, A.V. Carazo, K. Uchino, H.E. Kim, Piezoelectric and magnetoelectric properties of lead zirconate titanate/Ni-ferrite particulate composites. J. Electroceram. 7, 17–24 (2001)

    Article  Google Scholar 

  17. J. Van den Boomgaard, D.R. Terrell, R.A.J. Born, et al. An in situ grown eutectic magnetoelectric composite material. J. Mater. Sci. 9, 1705–1709 (1974)

    Article  ADS  Google Scholar 

  18. J. Van den Boomgaard, A.M.J.G. van Run, J. van Suchtelen, Piezoelectric-piezomagnetic composite with magnetoelectric effect. Ferroelectrics. 14, 727–728 (1976)

    Article  Google Scholar 

  19. J. Vanden Boomgaard, R.A.J. Born, A sintered magnetoelectric composite material BaTiO3-Ni(Co,Mn)Fe2O4. J. Mater. Sci. 13, 1538–1548 (1978)

    Article  ADS  Google Scholar 

  20. J. Van Suchtelen, Product properties: a new application of composite materials. Philips. Res. Rep. 27, 28–37 (1972)

    Google Scholar 

  21. J. Zhai, Z. Xing, S. Dong, J. Li, D. Viehland, Magnetoelectric laminate composites: an overview. J. Am. Ceram. Soc. 91, 351–358 (2008)

    Article  Google Scholar 

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Acknowledgements

Authors like to thank Dr. Amarendra, IGCAR, India, for his constant help and useful discussions. Authors acknowledge support from Homi Bhabha National Institute (HBNI). Author MSRR acknowledges the Department of Science and Technology, India (Project no. SR/CMP-23/2005).

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Correspondence to Mangamma Geramilla or Ramachandran Balakrishnan.

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Geramilla, M., Balakrishnan, R., Natarajan, S.T. et al. Nanoscale studies of magnetoelectric coupling in multiferroic BTO–CFO composite. Appl. Phys. A 125, 39 (2019). https://doi.org/10.1007/s00339-018-2333-7

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  • DOI: https://doi.org/10.1007/s00339-018-2333-7

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