Abstract
We report on the existence of interacting ferromagnetic and ferroelectric nanodomains in multiferroic 0.65BaTiO3–0.35CoFe2O4 (BTO–CFO) composite synthesized using a conventional solid-state route. X-ray diffraction study shows the coexistence of individual phases (BTO and CFO) of the composite material. Nanometric studies on the sample pellet of BTO–CFO composite are carried out using Scanning Probe Microscopy (SPM) to probe local ferroelectric and magnetic ordering. Importantly, the interactive nanodomains of individual phases are distinctly seen in the Atomic Force Acoustic Microscopy (AFAM) and Piezo-Force Microscopy (PFM) studies, which are done to investigate the magnetoelectric coupling in the BTO–CFO composite. Elasticity maps and piezoresponse images show local inhomogeneities with respect to the distribution of magnetoelectric coupling in the composite.
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References
D.N. Astrov, The magnetoelectric effect in antiferromagnetics. Sov. Phys. JETP. 11, 708–709 (1960)
D.N. Astrov, Magnetoelectric effect in chromium oxide. Sov. Phys. JETP. 13, 729–733 (1961)
W. Eerenstein, N.D. Mathur, J.F. Scott, Multiferroic and magnetoelectric materials. Nature. 442, 759–765 (2006)
M. Fiebig, Revival of the magnetoelectric effect. J. Phys. D. Appl. Phys. 38, R123 (2005)
V.C. Flores, D.B. Baques, D.C. Flores, J.A.M. Aquino, Enhanced magnetoelectric effect in core-shell particulate composites. J. Appl. Phys. 99, 08J503 (2006)
R.A. Islam, Y. Ni, A.G. Khachaturyan, S. Priya, Giant magnetoelectric effect in sintered multilayered composite structures. J. Appl. Phys. 104, 044103 (2008)
K.P. Jayachandran, J.M. Guedes, H.C. Rodrigues, Solutions for maximum coupling in multiferroic magnetoelectric composites by material design. Sci. Rep. 8, 4866 (2018)
R.V. Krishnaiah, A. Srinivas, S.V. Kamat, T. Karthik, S. Asthana, Effect of CoFe2O4 mole percentage on multiferroic and magnetoelectric properties of Na0.5Bi0.5TiO3/CoFe2O4 particulate composites. Ceram. Int. 40, 7799–7804 (2014)
M. Liu, X. Li, J. Lou, S. Zheng, K. Dui, N.X. Sun, A modified sol-gel process for multiferroic nanocomposite films. J. Appl. Phys. 102, 083911 (2007)
L.W. Martin, A.M. Rappe, Thin-film ferroelectric materials and their applications. Nat. Rev. Mater. 2, 16087 (2016)
V.R. Mudinepalli, S.H. Song, B.S. Murty, Enhanced magnetoelectric properties in lead-free Ni0.83Co0.15Cu0.02Fe1.9O4 − δ-Na0.5Bi0.5TiO3 composites by spark plasma sintering. Scr. Mater. 82, 9–12 (2014)
C.W. Nan, M.I. Bichurin, S. Dong, D. Viehland, G. Srinivasan, Multiferroic magnetoelectric composites: historical perspective, status, and future directions. J. Appl. Phys. 103, 031101 (2008)
M. Naveed-Ul-Haq, V.V. Shvartsman, S. Salamon, H. Wende, H. Trivedi, A. Mumtaz, D.C. Lupascu, A new (Ba,Ca)(Ti,Zr)O3 based multiferroic composite with large magnetoelectric effect. Sci. Rep. 6, 32164 (2016)
V.M. Petrov, G. Srinivasan, T.A. Galkina, Microwave magnetoelectric effects in bilayers of single crystal ferrite and functional graded piezoelectric. J. Appl. Phys. 104, 113910 (2008)
E.V. Ramana, F. Figueiras, M.P.F. Graca, M.A. Valente, Observation of magnetoelectric coupling and local piezoresponse in modified (Na0.5Bi0.5)TiO3-BaTiO3-CoFe2O4 lead-free composites. Dalton. Trans. 43, 9934–9943 (2014)
J. Ryu, A.V. Carazo, K. Uchino, H.E. Kim, Piezoelectric and magnetoelectric properties of lead zirconate titanate/Ni-ferrite particulate composites. J. Electroceram. 7, 17–24 (2001)
J. Van den Boomgaard, D.R. Terrell, R.A.J. Born, et al. An in situ grown eutectic magnetoelectric composite material. J. Mater. Sci. 9, 1705–1709 (1974)
J. Van den Boomgaard, A.M.J.G. van Run, J. van Suchtelen, Piezoelectric-piezomagnetic composite with magnetoelectric effect. Ferroelectrics. 14, 727–728 (1976)
J. Vanden Boomgaard, R.A.J. Born, A sintered magnetoelectric composite material BaTiO3-Ni(Co,Mn)Fe2O4. J. Mater. Sci. 13, 1538–1548 (1978)
J. Van Suchtelen, Product properties: a new application of composite materials. Philips. Res. Rep. 27, 28–37 (1972)
J. Zhai, Z. Xing, S. Dong, J. Li, D. Viehland, Magnetoelectric laminate composites: an overview. J. Am. Ceram. Soc. 91, 351–358 (2008)
Acknowledgements
Authors like to thank Dr. Amarendra, IGCAR, India, for his constant help and useful discussions. Authors acknowledge support from Homi Bhabha National Institute (HBNI). Author MSRR acknowledges the Department of Science and Technology, India (Project no. SR/CMP-23/2005).
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Geramilla, M., Balakrishnan, R., Natarajan, S.T. et al. Nanoscale studies of magnetoelectric coupling in multiferroic BTO–CFO composite. Appl. Phys. A 125, 39 (2019). https://doi.org/10.1007/s00339-018-2333-7
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DOI: https://doi.org/10.1007/s00339-018-2333-7