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Applied Physics A

, 124:298 | Cite as

Effect of Ti species dosage on the photocatalytic performance of HNbMoO6

  • Lifang Hu
  • Jichao Zhu
  • Liangguo Da
  • Jie He
Article
  • 98 Downloads

Abstract

A series of Ti species pillared HNbMoO6 composites with different Ti/Mo ratios were prepared via an intercalation–pillaring route. The effect of Ti species on the photocatalytic performance of HNbMoO6 and the reason were investigated by means of physicochemical methods such as powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), N2 adsorption–desorption isotherms, laser Raman spectroscopy (LRS) and UV–Vis diffuse reflectance spectroscopy (UV–Vis DRS). The results showed that the effects of Ti species dosage on the disperse state, the interaction model, spectral response characteristic and photocatalytic performance were significant. When the Ti/Mo ratio was less than 1, Ti species were uniformly dispersed on the interlayer of HNbMoO6, and presented the obvious interaction with the host laminates. The specific surface area of the as-prepared Ti-HNbMoO6 (with Ti/Mo ratio 1) was 4 times than that of the host material. The narrower band gap and more excellent photocatalytic performance of T1-HNbMoO6 were derived from the obvious synergistic effect between the host and the guest.

Notes

Acknowledgements

This work was supported by the Natural Science Foundation of China (no. 21271008).

References

  1. 1.
    Y. Zhang, N. Wang, J. He et al., Synthesis of CeO2/e-HTiNbO5 nanocomposite and its application for photocatalytic oxidation desulfurization. NANO 11(2), 1650018 (2016)CrossRefGoogle Scholar
  2. 2.
    Y. Zhou, J. Hu, B. Dang et al., Effect of different nanoparticles on tuning electrical properties of polypropylene nanocomposites. IEEE Trans. Dielectr. Electr. Insul. 24(3), 1380–1389 (2017)CrossRefGoogle Scholar
  3. 3.
    X.Q. Xu, L. Zhao, X.J. Guo et al., Intercalation of layered HMMoO6, (M=Ta, Nb) with oligomeric polyhydroxyacetato-Cr(III) species and propping up of HMMoO6, with chromium oxide as pillars. Polyhedron 97, 208–214 (2015)CrossRefGoogle Scholar
  4. 4.
    J. He, L.F. Hu, Y. Tang et al., Adsorption features and photocatalytic oxidation performance of M1/3NbMoO6 (M=Fe, Ce) for ethyl mercaptan. RSC Adv. 4(43), 22334–22341 (2014)CrossRefGoogle Scholar
  5. 5.
    W. Hou, B. Peng, Q. Van et al., The first silica-pillared layered niobate. Chem. Commun. 14(3), 253–254 (1993)CrossRefGoogle Scholar
  6. 6.
    W. Hou, J. Ma, Q. Yan et al., Highly thermostable, porous, layered titanoniobate pillared by silica. Chem. Commun. 3(14), 1144–1145 (1993)CrossRefGoogle Scholar
  7. 7.
    Z. Zhai, X. Yang, L. Xu et al., Novel mesoporous NiO/HTiNbO5 nanohybrids with high visible-light photocatalytic activity and good biocompatibility. Nanoscale 4(2), 547–556 (2012)ADSCrossRefGoogle Scholar
  8. 8.
    C. Liu, R. Han, H. Ji et al., S-doped mesoporous nanocomposite of HTiNbO5 nanosheets and TiO2 nanoparticles with enhanced visible light photocatalytic activity. Phys. Chem. Chem. Phys. 18(2), 801–810 (2016)CrossRefGoogle Scholar
  9. 9.
    J. Wu, S. Uchida, Y. Fujishiro et al., Synthesis and photocatalytic properties of HNbWO6/TiO2, and HNbWO6/Fe2O3 nanocomposites. J. Photochem. Photobiol. A Chem. 128(1–3), 129–133 (1999)CrossRefGoogle Scholar
  10. 10.
    J. Wu, S. Uchida, Y. Fujishiro et al., Synthesis and photocatalytic properties of HTaWO6/(Pt,TiO2) and HTaWO6/(Pt,Fe2O3) nanocomposites. Int. J. Inorg. Mater. 1(3–4), 253–258 (1999)CrossRefGoogle Scholar
  11. 11.
    J. Wu, Y. Shu, L. Yu et al., Hydrothermal synthesis of HNbWO6/MO series nanocomposites and their photocatalytic properties. J. Mater. Sci. 36(12), 3055–3059 (2001)ADSCrossRefGoogle Scholar
  12. 12.
    L. Wang, J. Wu, T. Li et al., Synthesis and photocatalytic properties of HTaWO6 intercalated with oxide materials. J. Porous Mater. 12(1), 23–27 (2005)CrossRefGoogle Scholar
  13. 13.
    J. He, Q.J. Li, Y. Tang et al., Characterization of HNbMoO6, HNbWO6, and HTiNbO5 as solid acids and their catalytic properties for esterification reaction. Appl. Catal. A Gen. 443444, 145–152 (2012)Google Scholar
  14. 14.
    C. Tagusagawa, A. Takagaki, S. Hayashi et al., Efficient utilization of nanospace of layered transition metal oxide HNbMoO6 as a strong, water-tolerant solid acid catalyst. J. Am. Chem. Soc. 130(23), 7230–7231 (2008)CrossRefGoogle Scholar
  15. 15.
    C. Tagusagawa, A. Takagaki, S. Hayashi et al., Evaluation of strong acid properties of layered HNbMoO6 and catalytic activity for Friedel–Crafts alkylation. Catal. Today 142(3–4), 267–271 (2009)CrossRefGoogle Scholar
  16. 16.
    A. Takagaki, C. Tagusagawa, K. Domen, Glucose production from saccharides using layered transition metal oxide and exfoliated nanosheets as a water-tolerant solid acid catalyst. Chem. Commun. 42(42), 5363 (2008)CrossRefGoogle Scholar
  17. 17.
    A. Takagaki, R. Sasaki, C. Tagusagawa et al., Intercalation-induced esterification over a layered transition metal oxide. Top. Catal. 52(6–7), 592–596 (2009)CrossRefGoogle Scholar
  18. 18.
    L.F. Hu, Y. Tang, J. He et al., Regioselective toluene nitration catalyzed with layered HNbMoO6. Russ. J. Phys. Chem. A 91(3), 511–516 (2017)CrossRefGoogle Scholar
  19. 19.
    L.F. Hu, J. He, L. Xu et al., Titania species on two-dimensional HNbMoO6 nanosheets: structural feature, interaction model and synergistic effect for photocatalytic degradation of methylene blue. J. Nanophotonics 10(4), 046015 (2016)ADSCrossRefGoogle Scholar
  20. 20.
    L.F. Hu, J. He, Y. Liu et al., Structural features and photocatalytic performance of TiO2–HNbMoO6 composite. Acta Phys. Chim. Sin. 32(3), 737–744 (2016)Google Scholar
  21. 21.
    X. Fan, B. Lin, H. Liu et al., Remarkable promotion of photocatalytic hydrogen evolution from water on TiO2-pillared titanoniobate. Int. J. Hydrogen Energy 38(2), 832–839 (2013)CrossRefGoogle Scholar
  22. 22.
    P. Botella, B. Solsona, J.M.L. Nieto et al., Mo–W-containing tetragonal tungsten bronzes through isomorphic substitution of molybdenum by tungsten. Catal. Today 158(1–2), 162–169 (2010)CrossRefGoogle Scholar
  23. 23.
    T. Murayama, J. Chen, J. Hirata et al., Hydrothermal synthesis of octahedra-based layered niobium oxide and its catalytic activity as a solid acid. Catal. Sci. Technol. 4(12), 4250–4257 (2014)CrossRefGoogle Scholar
  24. 24.
    H. Zhang, X. Liu, R. Wang et al., Coating of α-MoO3 on nitrogen-doped carbon nanotubes by electrodeposition as a high-performance cathode material for lithium-ion batteries. J. Power Sources 274, 1063–1069 (2015)ADSCrossRefGoogle Scholar
  25. 25.
    L.O. Alemán-Vázquez, F. Hernández-Pérez, J.L. Cano-Domínguez et al., Binder effect on the catalytic activity of MoO3, bulk catalyst reduced by H2, for n-heptane hydroisomerization. Fuel 117(1), 463–469 (2014)CrossRefGoogle Scholar
  26. 26.
    K. Kioka, T. Honma, T. Komatsu, Fabrication of (K, Na)NbO3 glass–ceramics and crystal line patterning on glass surface. Opt. Mater. 33(8), 1203–1209 (2011)ADSCrossRefGoogle Scholar
  27. 27.
    S.M. Hsu, J.J. Wu, S.W. Yung et al., Evaluation of chemical durability, thermal properties and structure characteristics of Nb–Sr-phosphate glasses by Raman and NMR spectroscopy. J. Non Cryst. Solids 358(1), 14–19 (2012)ADSCrossRefGoogle Scholar
  28. 28.
    F. Idrees, C. Cao, F.K. Butt et al., Synthesis of novel hollow microflowers (NHMF) of Nb3O7F, their optical and hydrogen storage properties. Int. J. Hydrogen Energy 39(25), 13174–13179 (2014)CrossRefGoogle Scholar
  29. 29.
    L. Wei, G.D. Meitzner, R.W.B. Iii et al., Raman and X-ray absorption studies of Mo species in Mo/H-ZSM5 catalysts for non-oxidative CH4, reactions. J. Catal. 191(2), 373–383 (2000)CrossRefGoogle Scholar
  30. 30.
    H. Huang, C. Wang, J. Huang et al., Structure inherited synthesis of N-doped highly ordered mesoporous Nb2O5 as robust catalysts for improved visible light photoactivity. Nanoscale 6(13), 7274–7280 (2014)ADSCrossRefGoogle Scholar
  31. 31.
    N. Usha, R. Sivakumar, C. Sanjeeviraja, Electrochromic properties of radio frequency magnetron sputter deposited mixed Nb2O5:MoO3 (95:5) thin films cycled in H+ and Li+ ions. Mater. Sci. Semicond. Process. 30(30), 31–40 (2015)CrossRefGoogle Scholar
  32. 32.
    J.Z. Ou, J.L. Campbell, D. Yao et al., In situ Raman spectroscopy of H2 Gas interaction with layered MoO3. J. Phys. Chem. C 115(21), 10757–10763 (2011)CrossRefGoogle Scholar
  33. 33.
    M. Thommes, K. Kaneko, A.V. Neimark et al., Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl. Chem. 87, 1051–1069 (2015)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Chemical EngineeringAnhui University of Science and TechnologyHuainanPeople’s Republic of China
  2. 2.School of Earth and EnvironmentAnhui University of Science and TechnologyHuainanPeople’s Republic of China

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