Abstract
Total reflection X-ray fluorescence (TXRF) analysis is an excellent tool to determine major, minor and trace elements in minuscule amounts of samples, making this technique very suitable for pigment analysis. Collecting minuscule amounts of pigment material from precious works of art by means of a cotton swab is a well-accepted sampling method, but poses specific challenges when TXRF is to be used for the characterization of the unknown material.
Similar content being viewed by others
References
Y. Yoneda, T. Horiuchi, Rev. Sci. Instrum. 42, 169 (1971)
H. Aiginger, P. Wobrauschek, Nucl. Instrum. Methods 114, 157 (1974)
R. Klockenkämper, Total Reflection X-ray Fluorescence Analysis (Wiley, New York, 1997)
A. von Bohlen, E-Preserv. Sci. 1, 23 (2004)
R. Klockenkämper, A. von Bohlen, L. Moens, W. Devos, Spectrochim. Acta B At. Spectrosc. 48, 239 (1993)
R. Klockenkämper, A. von Bohlen, Total-Reflection X-ray Fluorescence Analysis and Related Methods, 2nd edn. (Wiley, New York, 2014)
P. Wobrauschek, X-Ray Spectrom. 36, 289 (2007)
L. Ying, Adv. X-Ray Chem. Anal. 46, 13 (2015)
L. Moens, W. Devos, R. Klockenkämper, A. von Bohlen, Trends Anal. Chem. 13, 198 (1994)
A. von Bohlen, F. Meyer, Spectrochim. Acta B At. Spectrosc. 52, 1053 (1997)
G. Van Hooydonk, M. De Reu, L. Moens, J. Van Aelst, L. Milis, Eur. J. Inorg. Chem. 1998, 639 (1998)
P. Vandenabeele, B. Wehling, L. Moens, B. Dekeyzer, B. Cardon, A. von Bohlen, R. Klockenkämper, Analyst 124, 169 (1999)
B. Wehling, P. Vandenabeele, L. Moens, R. Klockenkämper, A. von Bohlen, G. Van Hooydonk, M. De Reu, Microchim. Acta 130, 253 (1999)
R. Klockenkämper, A. von Bohlen, L. Moens, X-Ray Spectrom. 29, 119 (2000)
N. Civici, O. Demko, R. Clark, J. Cult. Herit. 6, 157 (2005)
R. Fernández-Ruiz, M. García-Heras, Spectrochim. Acta B At. Spectrosc. 62, 1123 (2007)
R. Fernández-Ruiz, M. Garcia-Heras, Spectrochim. Acta B At. Spectrosc. 63, 975 (2008)
C. Vázquez, A. Albornoz, A. Hajduk, D. Elkin, G. Custo, A. Obrustky, Spectrochim. Acta B At. Spectrosc. 63, 1415 (2008)
I. Domingo, P. García-Borja, C. Roldan, Archaeometry 54, 868 (2012)
L. Bonizzoni, A. Galli, M. Gondola, M. Martini, X-Ray Spectrom. 42, 262 (2013)
D. Lauwers, A. Hutado, V. Tanevska, L. Moens, D. Bersani, P. Vandenabeele, Spectrochim. Acta A Mol. Biomol. Spectrosc. 118, 294 (2014)
L. Van De Voorde, J. Van Pevenage, K. De Langhe, R. De Wolf, B. Vekemans, L. Vincze, P. Vandenabeele, M.P.J. Martens, Spectrochim. Acta B At. Spectrosc. 97, 1 (2014)
B. Brunetti, C. Miliani, F. Rosi, B. Doherty, Top. Curr. Chem. 374, 10 (2016)
B. Vekemans, K. Janssens, L. Vincze, F. Adams, P. Van Espen, X-Ray Spectrom. 23, 278 (1994)
M. Dargie, A. Markowicz, A. Tajani, V. Valkovic, Fresenius J. Anal. Chem. 357, 589 (1997)
E. Towett, K. Shepherd, G. Cadisch, Sci. Total Environ. 463–464, 374 (2013)
H. Stosnach, Spectrochim. Acta B. At. Spectrosc. 61, 1141 (2006)
E. Marguí, A. Marques, M. Prisal, M. Hidalgo, I. Queralt, M.L. Carvalho, Appl. Spectrosc. 68, 1241 (2014)
P. Vandenabeele, A. Von Bohlen, L. Moens, R. Klockenkämper, F. Joukes, G. Dewispelaere, Anal. Lett. 33, 3315 (2000)
Acknowledgements
The authors thank Ghent University for its financial support through the concerted research actions (GOA) programme. Sylvia Lycke is also acknowledged for the support in the laboratory.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Coccato, A., Vekemans, B., Vincze, L. et al. Pigment particles analysis with a total reflection X-ray fluorescence spectrometer: study of influence of instrumental parameters. Appl. Phys. A 122, 1051 (2016). https://doi.org/10.1007/s00339-016-0581-y
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-016-0581-y