Abstract
We fabricate surface plasmon resonance (SPR) device using a modified ZnO/Au-Kretschmann configuration to investigate the possibility of using ZnO for CO2 gas sensing at room temperature. Here, nanostructured ZnO/Au layer was deposited on the flat surface of the prism and then gas chamber was placed on the ZnO/Au surface to observe the gas response. The ZnO structures were characterized by X-ray diffraction, scanning electron microscope, and energy dispersive spectroscopy. We found that ZnO structures have two types of nanostructures, i.e., individual nanorods and flower-like structures, which have hexagonal crystal structure. The ZnO nanorod has a diameter ranged from 200 to 300 nm and length ranged from 3 to 5 μm. The effect of gas response is demonstrated by a shift of SPR spectra and a change in light reflectance. It is found that the adsorption of gas molecules on the ZnO nanorods produces the shift of SPR angle to the lower light incident angle. A consistent sensing behavior over repetitive circles is also demonstrated.
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References
J. Dostálek, J. Ladd, S. Jiang, J. Homola, SPR biosensors for detection of biological and chemical analytes, in Springer Series on Chemical Sensors and Biosensors, ed. by O.S. Wolfbeis (Springer, Berlin, 2006), pp. 177–190
R.P.H. Kooyman, Physics of surface plasmon resonance, in Surface Plasmon Resonance, ed. by R.B.M. Schasfoort, A.J. Tudos (RSC Publishing, Cambridge, 2008), pp. 15–34
A.K. Sharma, B.D. Gupta, On the performance of different bimetallic combinations in surface plasmon resonance based fiber optic sensors. J. Appl. Phys. 101(9), 093111_1–093111_6 (2007)
K.J. Krane, H. Raether, Measurement of surface plasmon dispersion in aluminum and indium. Phys. Rev. Lett. 37, 1355–1357 (1976)
P. Tobiska, O. Hugon, A. Trouillet, H. Gagnaire, An integrated optic hydrogen sensor based on SPR on palladium. Sens. Actuators B Chem. 74, 168–172 (2001)
A. Abdelghani, J.M. Chovelon, N. Jaffrezic-Renault, C. Ronot-Trioli, C. Veillas, H. Gagnaire, Surface plasmon resonance fibre-optic sensor for gas detection. Sens. Actuators B Chem. 39, 407–410 (1997)
M.G. Manera, G. Leo, M.L. Curri, P.D. Cozzoli, R. Rella, P. Siciliano, A. Agostiano, L. Vasanelli, Investigation on alcohol vapours/TiO2 nanocrystal thin films interaction by SPR technique for sensing application. Sens. Actuators B Chem. 100(1–2), 75–80 (2004)
D. Yang, H.H. Lu, B. Chen, C.W. Lin, Surface plasmon resonance of SnO2/Au Bi-layer films for gas sensing applications. Sens. Actuators B Chem. 145(2), 832–838 (2010)
R. Tabassum, S.K. Mishraa, B.D. Gupta, Surface plasmon resonance-based fiber optic hydrogen sulphide gas sensor utilizing Cu–ZnO thin films. Phys. Chem. Chem. Phys. 15, 11868–11874 (2013)
R. Tabassum, B.D. Gupta, Surface plasmon resonance based fiber optic detection of chlorine utilizing polyvinylpyrolidone supported zinc oxide thin films. Analyst 140, 1863–1870 (2015)
K. Watanabe, K. Matsumoto, T. Ohgaki, I. Sakaguchi, N. Ohashi, S. Hishita, H. Haneda, Development of ZnO-based surface plasmon resonance gas sensor and analysis of UV irradiation effect on NO2 desorption from ZnO thin films. J. Ceram. Soc. Jpn. 118, 193–196 (2010)
V.P. Dinesh, P. Biji, A.K. Prasad, A.K. Tyagi, Enhanced ammonia sensing properties using Au decorated ZnO nanorods, in Proceeding of IEEE Sensors 2013, vol. 1(4), pp. 1–4 (2013)
M.G. Manera, J. Spadavecchia, D. Buso, C. de Julián Fernández, G. Mattei, A. Martucci, P. Mulvaney, J. Pérez-Juste, R. Rella, L. Vasanelli, P. Mazzoldi, Optical gas sensing of TiO2 and TiO2/Au nanocomposite thin films. Sens. Actuators B Chem. 132, 107–115 (2008)
H. Li, X. Mu, Y. Yang, A.J. Mason, Low power multimode electrochemical gas sensor array system for wearable health and safety monitoring. IEEE Sens. J. 14(10), 3391–3399 (2014)
W.Y. Fenga, N.F. Chiub, H.H. Lub, H.C. Shihc, D. Yang, Surface plasmon resonance biochip based on ZnO thin film for nitric oxide sensing, in 30th Annual International IEEE EMBS Conference, Canada, pp. 5757–5760 (2008)
G.J. Ashwell, M.P.S. Roberts, Highly selective surface plasmon resonance sensor for NO2. Electron. Lett. 33(22), 2089–2091 (1996)
P.S. Vukusic, J.R. Sambles, Cobalt phthalocyanine as a basis for the optical sensing of nitrogen dioxide using surface plasmon resonance. Thin Solid Films 221, 311–317 (1992)
K. Kurihara, K. Nakamura, K. Suzuki, Asymmetric SPR sensor response curve-fitting equation for the accurate determination of SPR resonance angle. Sens. Actuators B Chem. 86, 49–57 (2002)
L. Leutz, A. Suzuki, Nonimaging Fresnel Lenses: Design and Performance of Solar Concentration (Springer, Heidelberg, 2001), pp. 46–47
K.M. McPeak, S.V. Jayanti, S.J.P. Kress, S. Iotti, A. Rossinelli, B.J. Norris, Plasmonic films can easily be better: rules and recipes. ACS Photonics 2, 326–333 (2015)
M.A. Bodea, G. Sbarcea, G.V. Naik, A. Boltasseva, T.A. Klar, J.D. Pedarnig, Negative permittivity of ZnO thin films prepared from aluminum and gallium doped ceramics via pulsed-laser deposition. Appl. Phys. A 110(2), 929_1–929_6 (2013)
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We would like to thank Ms. Lia Aprilia, Ms. Putri Amalia Pondoh, Ms. Sonya Retno Mange, and Mr. Mochammad Aldi Mauludin for their technical support in the experiment.
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Nuryadi, R., Mayasari, R.D. ZnO/Au-based surface plasmon resonance for CO2 gas sensing application. Appl. Phys. A 122, 33 (2016). https://doi.org/10.1007/s00339-015-9536-y
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DOI: https://doi.org/10.1007/s00339-015-9536-y