Abstract
Self-seeding polyol synthesis method, without additives, was employed for the fabrication of different copper nanostructures. The pertinent parameters including temperature, copper concentration and molar ratio of poly(vinylpyrrolidone) (PVP) to copper were assessed for achieving different size and morphology of copper nanostructures, i.e., nanowire, nanosphere and nanocube. It was found that PVP-to-copper molar ratio has the most significant effect on the geometry of the copper nanostructures.
Graphical Abstract
Similar content being viewed by others
References
K.J. Ziegler, R.C. Doty, K.P. Johnston, B.A. Korgel, Synthesis of organic monolayer-stabilized copper nanocrystals in supercritical water. J. Am. Chem. Soc. 123(32), 7797–7803 (2001)
C.F. Monson, A.T. Woolley, DNA-templated construction of copper nanowires. Nano Lett. 3(3), 359–363 (2003)
Y. Feng, X. Zheng, Plasma-enhanced catalytic CuO nanowires for CO oxidation. Nano Lett. 10(11), 4762–4766 (2010)
A.R. Rathmell, S.M. Bergin, Y.L. Hua, Z.Y. Li, B.J. Wiley, The growth mechanism of copper nanowires and their properties in flexible, transparent conducting films. Adv. Mater. 22(32), 3558–3563 (2010)
M. Mohl, P. Pusztai, A. Kukovecz, Z. Konya, J. Kukkola, K. Kordas, R. Vajtai, P.M. Ajayan, Low-temperature large-scale synthesis and electrical testing of ultralong copper nanowires. Langmuir 26(21), 16496–16502 (2010)
A. Rathmell, B. Wiley, The synthesis and coating of long, thin copper nanowires to make flexible, transparent conducting films on plastic substrates. Adv. Mater. 23(41), 4798–4803 (2011)
H. Guo, L. Na, Y. Chen, Zh Wang, Q. Xie, T. Zheng, N. Gao, Sh Li, J. Kang, D. Cai, D.L. Peng, Copper nanowires as fully transparent conductive electrodes. Sci. Rep. 3, 2323 (2013)
H.H. Huang, F.Q. Yan, Y.M. Kek, C.H. Chew, G.Q. Xu, W. Ji, P.S. Oh, S.H. Tang, Synthesis, characterization, and nonlinear optical properties of copper nanoparticles. Langmuir 13(2), 172–175 (1997)
R.V. Kumar, Y. Mastai, Y. Diamant, A. Gedanken, Sonochemical synthesis of amorphous Cu and nanocrystalline Cu2O embedded in a polyaniline matrix. J. Mater. Chem. 11(4), 1209–1213 (2001)
G. Vitulli, M. Bermini, S. Bertozzi, E. Pitzalis, P. Salvadori, S. Coluccia, G. Martra, Nanoscale copper particles derived from solvated Cu atoms in the activation of molecular oxygen. Chem. Mater. 14(3), 1183–1186 (2002)
C.L. Kitchens, C.B. Roberts, Copper nanoparticle synthesis in compressed liquid and supercritical fluid reverse micelle systems. Ind. Eng. Chem. Res. 43(19), 6070–6081 (2004)
Y. Chang, M.L. Lye, H.C. Zeng, Large-scale synthesis of high-quality ultralong copper nanowires. Langmuir 21(9), 3746–3748 (2005)
Y.Q. Liu, M. Zhang, F.X. Wang, G.B. Pan, Facile microwave-assisted synthesis of uniform single-crystal copper nanowires with excellent electrical conductivity. RSC Adv. 2, 11235–11237 (2012)
S. Xu, X. Sun, H. Ye, T. You, X. Song, S. Sun, Selective synthesis of copper nanoplates and nanowires via a surfactant-assisted hydrothermal process. Mater. Chem. Phys. 120(1), 1–5 (2010)
Zh Yuxin, Y. Zhang, Y. Li, Z. Yan, Soft synthesis of single-crystal copper nanowires of various scales. New J. Chem. 36, 130–138 (2012)
Y. Zhao, Y. Zhang, Y. Li, Zh He, Z. Yan, Rapid and large-scale synthesis of Cu nanowires via a continuous flow solvothermal process and its application in dye-sensitized solar cells (DSSCs). RSC Advances 2(11), 1544–11551 (2012)
F. Fievet, J.P. Lagier, B. Beaudoin, M. Filgarz, B. Blin, Homogeneous and heterogeneous nucleations in the polyol process for the preparation of micron and submicron size metal particles. Solid State Ionics 32(33), 198–205 (1989)
Y. Sun, Y. Xia, Large-scale synthesis of uniform silver nanowires through a soft, self-seeding, polyol process. Adv. Mater. 14(11), 833–837 (2002)
B. Wiley, Y. Sun, B. Mayers, Y. Xia, Shape-controlled synthesis of metal nanostructures: the case of silver. Chem. Eur. J. 11(2), 454–463 (2005)
B.K. Park, S. Jeong, D. Kim, J. Moon, S. Lim, J.S. Kim, Synthesis and size control of monodisperse copper nanoparticles by polyol method. J. Colloid. Interf. Sci. 311(2), 417–424 (2007)
W.J. Zhang, P. Chen, Q.S. Gao, Y.H. Zhang, Y. Tang, High-concentration preparation of silver nanowires: restraining in situ nitric acidic etching by steel-assisted polyol method. Chem. Mater. 20(5), 1699–1704 (2008)
P.Y. Silvert, K. Tekaia-Elhissen, Synthesis of monodisperse submicronic gold particles by the polyol process. Solid State Ionics 82(1–2), 53–60 (1995)
J. Xiong, Y.W.Q. Xue, X. Wu, Synthesis of highly stable dispersions of nanosized copper particles using l-ascorbic acid. Green Chem. 13(4), 900–904 (2011)
Q.L. Zhang, Z.M. Yang, B.J. Ding, X.Z. Lan, Y.J. Guo, Preparation of copper nanoparticles by chemical reduction method using potassium borohydride. Trans. Nanferrous Met. Soc. China 20, 240–244 (2010)
H.X. Zhang, U. Siegert, R. Liu, W.B. Cai, Facile fabrication of ultrafine copper nanoparticles in organic solvent. Nanoscale Res. Lett. 4(7), 705–708 (2009)
M. Blosi, S. Albonetti, M. Dondi, C. Maretelli, G. Baldi, Microwave-assisted polyol synthesis of Cu nanoparticles. J. Nanopart. Res. 13(1), 127–138 (2011)
Y. Wang, P. Chen, M. Liu, Synthesis of well-defined copper nanocubes by a one-pot solution process. Nanotechnology 17(24), 6000–6006 (2006)
S. Chang, K. Chen, Q. Hua, Y. Ma, W. Huang, Evidence for the growth mechanisms of silver nanocubes and nanowires. J. Phys. Chem. C 115(16), 7979–7986 (2011)
Y.G. Sun, B. Mayers, T. Herricks, Y.N. Xia, Polyol synthesis of uniform silver nanowires: a plausible growth mechanism and the supporting evidence. Nano Lett. 3(7), 955–960 (2003)
L. Samiee, M. Dehghani Mobarake, R. Karami, M. Ayazi, Developing of ethylene glycol as a new reducing agent for preparation of Pd-Ag/PSS composite membrane for hydrogen separation. J. Petrol Sci. Technol. 2(2), 25–32 (2012)
C.C. Luo, Y.H. Zhang, X.W. Zeng, Y.W. Zeng, Y.G. Wang, The role of poly(ethylene glycol) in the formation of silver nanoparticles. J. Colloid. Interf. Sci. 288(2), 444–448 (2005)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hosseini, M., Fatmehsari, D.H. & Marashi, S.P.H. Synthesis of different copper nanostructures by the use of polyol technique. Appl. Phys. A 120, 1579–1586 (2015). https://doi.org/10.1007/s00339-015-9358-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-015-9358-y