Abstract
A simple and controllable method was reported for the decoration of CuO nanoplate arrays with Au nanoparticles. It had been achieved through the reaction between Sn2+ and AuCl4 − in the presence of CuO nanoplate arrays. The structure and electron field emission properties of CuO nanoplate arrays decorated with different amounts of Au nanoparticles were investigated. The results demonstrated a remarkable enhancement of field emission performance of CuO nanoplate arrays decorated with Au nanoparticles. The effect of Au amount on the field emission performance was studied in detail, and excellent field emission properties such as a low turn-on electric field of 6.7 V/μm and a high field enhancement factor of 516 could be realized from the optimized sample. On the basis of experimental results, a possible mechanism for the formation of the CuO nanoplate arrays decorated with Au nanoparticles was speculated.
Similar content being viewed by others
References
W. Sugimoto, S. Sugita, Y. Sakai, H. Goto, Y. Watanabe, Y. Ohga et al., J. Appl. Phys. 108, 044507 (2010)
D.R. Whaley, B.M. Gannon, C.R. Smith, C.M. Armstrong, C.A. Spindt, IEEE Trans. Plasma Sci. 28, 727–747 (2000)
N.S. Liu, G.J. Fang, X.X. Yang, W. Zeng, C. Li, M.J. Wang et al., Diam. Relat. Mater. 18, 1375–1380 (2009)
K.F. Huo, X.M. Zhang, J.J. Fu, G.X. Qian, Y.C. Xin, B.Q. Zhu et al., J. Nanosci. Nanotechnol. 9, 3341–3346 (2009)
H.C. Wu, T.Y. Tsai, F.H. Chu, N.H. Tai, H.N. Lin, H.T. Chiu et al., J. Phys. Chem. C 114, 130–133 (2010)
Y.J. Su, L.Q. Hu, X.D. Zheng, Y.H. Xu, T.L. Guo, Optoelectron. Technol. 30, 80–83 (2010)
R.Z. Zhan, J. Chen, S.Z. Deng, N.S. Xu, J. Vac. Sci. Technol. B 28, 558–561 (2010)
Y.L. Liu, L. Zhong, Z.Y. Peng, Y.B. Song, W. Chen, J. Mater. Sci. 45, 3791–3796 (2010)
Y.Y. Hu, K. Wang, J.P. Liu, J. Jiang, R.M. Ding, X.X. Ji et al., J. Solid State Chem. 183, 662–667 (2010)
S. Dagher, Y. Haik, A.I. Ayesh, N. Tit, J. Lumin. 151, 149–154 (2014)
V.K. Patel, J. Clust. Sci. 24, 821–828 (2013)
M.M.R. Khan, Y.K. Wee, W.A.K. Mahmood, Int. J. Chem. React. Eng. 12, 215–221 (2014)
P.R. Shao, S.Z. Deng, J. Chen, J.A. Chen, N.S. Xu, J. Appl. Phys. 109, 023710 (2009)
W.Y. Sung, W.J. Kim, S.M. Lee, H.Y. Lee, Y.H. Kim, K.H. Park et al., Vacuum 81, 851–856 (2007)
Y.M. Juan, H.T. Hsueh, T.C. Cheng, C.W. Wu, S.J. Chang, ECS Solid State Lett. 3, 30–32 (2014)
Y.H. Zhou, E.W. Peterson, J. Zhou, Catal. Today 240, 201–205 (2015)
X.J. Wang, W. Wang, Y.L. Liu, Sens. Actuators B 168, 39–45 (2012)
L. Wu, F. Li, Y.Y. Xu, J.W. Zhang, D.Q. Zhang, G.S. Li et al., Appl. Catal. B 164, 217–224 (2015)
M. Liu, Z.Y. Wang, S.F. Zong, H. Chen, D. Zhu, Y. Zhong et al., J. Biomed. Nanotechnol. 11, 979–987 (2015)
F. Li, X.Q. Liu, Q. Zhang, T. Kong, Y.H. Jin, Cryst. Res. Technol. 47, 1140–1147 (2012)
G.Y. Wang, T.Y. Zhang, J. Colloid Interface Sci. 377, 438–441 (2012)
S. Krishnan, A.S.M.A. Haseeb, M.R. Johan, J. Alloy. Compd. 586, 360–367 (2014)
X.M. Hou, Mater. Lett. 137, 319–322 (2014)
M.A. Dar, Q. Ahsanulhaq, Y.S. Kim, J.M. Sohn, W.B. Kim, H.S. Shin, Appl. Surf. Sci. 255, 6279–6284 (2009)
A.Z. Liao, W.D. Zhu, J.B. Chen, X.Q. Zhang, C.W. Wang, J. Alloy. Compd. 609, 253–261 (2014)
H. Jin, Y.L. Li, J.J. Li, C.Z. Gu, Microelectron. Eng. 86, 1159–1161 (2009)
Y.W. Zhu, T. Yu, F.C. Cheong, X.J. Xu, C.T. Lim, V.B.C. Tan et al., Nanotechnology 16, 88–92 (2005)
Y.M. Chang, M.L. Lin, T.Y. Lai, H.Y. Lee, C.M. Lin, Y.C.S. Wu et al., ACS Appl. Mater. Interface 4, 6676–6682 (2012)
A.Z. Liao, W.D. Zhu, J.B. Chen, X.Q. Zhang, C.W. Wang, J. Alloy. Compd. 609, 253–261 (2014)
H. Hu, D. Zhang, Y. Liu, W. Yu, T. Guo, Vacuum 115, 70–74 (2015)
T.Y. Tsai, C.L. Hsu, S.J. Chang, S.I. Chen, H.T. Hsueh, T.J. Hsueh, IEEE Electron Device Lett. 33, 887–889 (2012)
Y.M. Juan, H.T. Hsueh, T.C. Cheng, C.W. Wu, S.J. Chang, ECS Solid State Lett. 3, 30–32 (2014)
Acknowledgments
This work was supported by National Natural Science Foundation of China (21201156) and the Fundamental Research Founds for National University, China University of Geosciences (Wuhan, CUG130401). The financial support is gratefully appreciated.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Li, F., Wu, S., Zhang, L. et al. Enhanced electron field emission from CuO nanoplate arrays decorated with Au nanoparticles. Appl. Phys. A 120, 1383–1389 (2015). https://doi.org/10.1007/s00339-015-9321-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-015-9321-y