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Transfer printing of electrodes for organic devices: nanoscale versus macroscale continuity

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Abstract

While transfer printing is a powerful technique to prepare micro- and nanostructured thin films, the preparation of continuous large-area electrodes via transfer printing is challenging. In this paper, we find discontinuity on the nanoscale as requirement for the successful transfer printing of large-area (marcoscale) continuous electrodes. We demonstrate that silver films deposited by physical vapor deposition or electroless deposition (ELD) can be used to form top electrodes for organic devices. However, the transfer of ELD films appears more promising. It enables vacuum-free room-temperature processing of metal top electrodes. As a case study, the top electrode of an organic solar cell was fabricated this way. The resulting power conversion efficiency (PCE) of 2.20 % is about 85 % of the PCE of the reference device with a vacuum-deposited silver electrode.

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References

  1. A. Carlson, A.M. Bowen, Y. Huang, R.G. Nuzzo, J.A. Rogers, Adv. Mater. 24, 5284 (2012)

    Article  Google Scholar 

  2. R.G. Nuzzo, Proc. Natl. Acad. Sci. U.S.A. 98, 4827 (2001)

    Article  ADS  Google Scholar 

  3. H. Schmid, H. Wolf, R. Allenspach, H. Riel, S. Karg, B. Michel, E. Delamarche, Adv. Funct. Mater. 13, 145 (2003)

    Article  Google Scholar 

  4. Y.-L. Loo, R.L. Willett, K.W. Baldwin, J.A. Rogers, J. Am. Chem. Soc. 124, 7654 (2002)

    Article  Google Scholar 

  5. Y.-L. Loo, R.L. Willett, K.W. Baldwin, J.A. Rogers, Appl. Phys. Lett. 81, 562 (2002)

    Article  ADS  Google Scholar 

  6. E. Menard, L. Bilhaut, J. Zaumseil, J.A. Rogers, Langmuir 20, 6871 (2004)

    Article  Google Scholar 

  7. Y.-L. Loo, D.V. Lang, J.A. Rogers, J.W.P. Hsu, B. Laboratories, L. Technologies, M. Hill, Nano Lett. 3, 913 (2003)

    Article  ADS  Google Scholar 

  8. Z. Wang, J. Yuan, J. Zhang, R. Xing, D. Yan, Y. Han, Adv. Mater. 15, 1009 (2003)

    Article  Google Scholar 

  9. H. Jin, J.C. Sturm, S.I.D. Symp, Dig. Tech. Pap. 40, 597 (2009)

    Article  Google Scholar 

  10. S. Kim, W.S. Lee, J. Lee, I. Park, Nanotechnology 23, 285301 (2012)

    Article  Google Scholar 

  11. K. Chan-mo, C. Hyunduck, L. Hyunkoo, L. Changhee, J. Korean Phys. Soc. 59, 470 (2011)

    Article  ADS  Google Scholar 

  12. D.R. Hines, V.W. Ballarotto, E.D. Williams, Y. Shao, S.A. Solin, J. Appl. Phys. 101, 024503 (2007)

    Article  ADS  Google Scholar 

  13. X. Feng, M.A. Meitl, A.M. Bowen, Y. Huang, R.G. Nuzzo, J.A. Rogers, Langmuir 23, 12555 (2007)

    Article  Google Scholar 

  14. M.A. Meitl, Z.-T. Zhu, V. Kumar, K.J. Lee, X. Feng, Y.Y. Huang, I. Adesida, R.G. Nuzzo, J.A. Rogers, Nat. Mater. 5, 33 (2005)

    Article  ADS  Google Scholar 

  15. T.-W. Lee, J. Zaumseil, S.H. Kim, J.W.P. Hsu, Adv. Mater. 16, 2040 (2004)

    Article  Google Scholar 

  16. T.-W. Lee, J. Zaumseil, Z. Bao, J.W.P. Hsu, J.A. Rogers, J. Womens, Health (Larchmt) 22, 469 (2013)

    Article  Google Scholar 

  17. A.R. Madaria, A. Kumar, C. Zhou, Nanotechnology 22, 245201 (2011)

    Article  ADS  Google Scholar 

  18. C. Shimada, S. Shiratori, A.C.S. Appl, Mater. Interfaces 5, 11087 (2013)

    Article  Google Scholar 

  19. Y. Saito, J.J. Wang, D.A. Smith, D.N. Batchelder, A simple chemical method for the preparation of silver surfaces for efficient SERS. Langmuir 18(8), 2959–2961 (2002). doi:10.1021/la011554y

    Article  Google Scholar 

  20. K. Zilberberg, F. Gasse, R. Pagui, A. Polywka, A. Behrendt, S. Trost, R. Heiderhoff, P. Görrn, T. Riedl, Adv. Funct. Mater. 24, 1671 (2014)

    Article  Google Scholar 

  21. O. Graudejus, P. Görrn, S. Wagner, A.C.S. Appl, Mater. Interfaces 2, 1927 (2010)

    Article  Google Scholar 

  22. W. Cao, P. Görrn, S. Wagner, Appl. Phys. Lett. 98, 212112 (2011)

    Article  ADS  Google Scholar 

  23. S.P. Lacour, D. Chan, S. Wagner, T. Li, Z. Suo, Appl. Phys. Lett. 88, 204103 (2006)

    Article  ADS  Google Scholar 

  24. H. Schmidt, K. Zilberberg, S. Schmale, H. Flügge, T. Riedl, W. Kowalsky, Appl. Phys. Lett. 96, 243305 (2010)

    Article  ADS  Google Scholar 

  25. S.W. Kettlitz, S. Valouch, U. Lemmer, Appl. Phys. A Mater. Sci. Process. 99, 805 (2010)

    Article  ADS  Google Scholar 

  26. W. Quan, C. Cheng, J. Liu, J. Zhang, D. Yan, D. Qin, Appl. Phys. A Mater. Sci. Process. 104, 47 (2011)

    Article  ADS  Google Scholar 

  27. A. Polywka, A. Vereshchaeva, T. Riedl, P. Görrn, Part. Part. Syst. Charact. 31, 342 (2014)

    Article  Google Scholar 

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Acknowledgments

The authors acknowledge funding by the Emmy-Noether-Programm of the Deutsche Forschungsgemeinschaft (DFG). Honeywell Specialty Chemicals Seelze GmbH is acknowledged for the generous supply with P3HT.

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Authors and Affiliations

  1. Chair of Large Area Optoelectronics, University of Wuppertal, 42119, Wuppertal, Germany

    Timo Jakob, Andreas Polywka, Luca Stegers, Engin Akdeniz, Stephan Kropp, Michael Frorath, Tobias Schneider & Patrick Görrn

  2. Institute of Electronic Devices, University of Wuppertal, 42119, Wuppertal, Germany

    Sara Trost & Thomas Riedl

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  1. Timo Jakob
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  2. Andreas Polywka
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  3. Luca Stegers
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Correspondence to Patrick Görrn.

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Jakob, T., Polywka, A., Stegers, L. et al. Transfer printing of electrodes for organic devices: nanoscale versus macroscale continuity. Appl. Phys. A 120, 503–508 (2015). https://doi.org/10.1007/s00339-015-9299-5

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  • DOI: https://doi.org/10.1007/s00339-015-9299-5

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