Skip to main content
Log in

Electrochemical polarisation studies on plasma-sprayed nickel-based superalloy

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

The plasma-sprayed NiCr–Cr2O3 and Al2O3–40 % TiO2 powders are deposited as coating on nickel-based superalloy. The electrochemical polarisation studies were carried out with 1.0 M H2SO4 solution as a corrosive medium. The corrosion current density of the coated sample was found to be decreased and exhibits better corrosion resistance than bare metal. The characterisation studies on the exposed sample result reveal that the bare metal has undergone severe intergranular attack and segregation on austenitic phase. The corrosion products formed are in the form of sulphides, and contribution of sulphur was noticed through EDS analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. J.-J. Park, S.-I. Pyun, Pit formation and growth of alloy 600 in Cl ion-containing thiosulphate solution at temperatures 298–573 K using fractal geometry. Corros. Sci. 45, 995–1010 (2003)

    Article  Google Scholar 

  2. L. Liu, Y. Li, F. Wang, Influence of nanocrystallization on passive behaviour of Ni-based superalloy in acidic solutions. Electrochim. Acta 52, 2392–2400 (2007)

    Article  Google Scholar 

  3. M. Taheri, Z. Valefi, K. Zangeneh-Madar, Influence of HVOF process parameters on microstructure and bond strength of NiCrAlY coatings. Surf. Eng. 28(4), 266–272 (2012)

    Article  Google Scholar 

  4. D. Thirumalaikumarasamy, K. Shanmugam, V. Balasubramanian, Effect of atmospheric plasma spraying parameters on porosity level of alumina coatings. Surf. Eng. 28(10), 759–766 (2012)

    Article  Google Scholar 

  5. P.K. Samantaroy, S. Girija, R. Kaul, U. Kamachi Mudali, Enhancement of corrosion resistance of nickel based superalloys by laser surface melting. Surf. Eng. 29(7), 522–530 (2013)

    Article  Google Scholar 

  6. C. Monticelli, A. Balbo, F. Zucchi, Corrosion and tribocorrosion behaviour of thermally sprayed ceramic coatings on steel. Surf. Coat. Technol. 205, 3683–3691 (2011)

    Article  Google Scholar 

  7. G. Mauer, R. Vaßen, Current developments and challenges in thermal barrier coatings. Surf. Eng. 27(7), 477–479 (2011)

    Article  Google Scholar 

  8. M. Adam Khan, S. Sundarrajan, S. Natarajan, Influence of plasma coatings on Inconel 617 for gas turbine applications. Surf. Eng. 30(9), 656–661 (2014)

    Article  Google Scholar 

  9. C. Che, G.Q. Wu, H.Y. Qi, Z. Huang, X.G. Yang, Effect of bond coat surface roughness on oxidation behaviour of air plasma sprayed thermal barrier coatings. Surf. Eng. 24(4), 276–279 (2008)

    Article  ADS  Google Scholar 

  10. Y. Wang, M.X. Li, H.L. Suo, Mechanical properties of YSZ thermal barrier coatings with segmented structure. Surf. Eng. 28(5), 329–333 (2012)

    Article  Google Scholar 

  11. G. Carac, L. Benea, C. Iticescu, T. Lampke, S. Steinhauser, B. Wielage, Codeposition of cerium oxide with nickel and cobalt: correlation between microstructure and microhardness. Surf. Eng. 20, 353 (2004)

    Article  Google Scholar 

  12. M. Srivastava, J.N. Balaraju, B. Ravishankar, K.S. Rajam, Improvement in the properties of nickel by nano-Cr2O3 incorporation. Surf. Coat. Technol. 205, 66–75 (2010)

    Article  Google Scholar 

  13. K. Kumar, R. Chandramohan, D. Kalyanaraman, Effect of heat treatment on cobalt and nickel electroplated surfaces with Cr2O3 dispersions. Appl. Surf. Sci. 227, 383 (2004)

    Article  ADS  Google Scholar 

  14. R.A. Mahesh, R. Jayaganthan, S. Prakash, Evaluation of hot corrosion behaviour of HVOF sprayed Ni–5Al and NiCrAl coatings in coal fired boiler environment. Surf. Eng. 26(6), 413–421 (2010)

    Article  Google Scholar 

  15. X.I.E. Xiaoyun, G.U.O. Hongbo, G.O.N.G. Shengkai, X.U. Huibin, Hot corrosion behavior of double-ceramic-layer LaTi2Al9O19/YSZ thermal barrier coatings. Chin. J. Aero. 25, 137–142 (2012)

    Article  Google Scholar 

  16. G. Kaushal, N. Kaur, H. Singh, S. Prakash, Effect of zirconium addition in HVOF sprayed Ni–20Cr coating. Surf. Eng. 29(1), 46–54 (2013)

    Article  Google Scholar 

  17. S. Matthews, B. James, M. Hyland, High temperature erosion–oxidation of Cr3C2–NiCr thermal spray coatings under simulated turbine conditions. Corr. Sci. 70, 203–211 (2013)

    Article  Google Scholar 

  18. F. Vargas, H. Ageorges, P. Fournier, P. Fauchais, M.E. López, Mechanical and tribological performance of Al2O3–TiO2 coatings elaborated by flame and plasma spraying. Surf. Coat. Technol. 205(4), 1132–1136 (2010)

    Article  Google Scholar 

  19. K.A. Habib, J.J. Saura, C. Ferrer, M.S. Damra, E. Giménez, L. Cabedo, Comparison of flame sprayed Al2O3/TiO2 coatings: their microstructure, mechanical properties and tribology behavior. Surf. Coat. Technol. 201, 1436–1443 (2006)

    Article  Google Scholar 

  20. K.G. Thirugnanasambantham, S. Natarajan, Degradation mechanism for high temperature erosion in surface modified IN718 superalloy. Surf. Eng. 31(1), 24–28 (2014)

    Article  Google Scholar 

  21. Sandrine Zanna, Sanna Tervakangas, Jukka Kolehmainen, Philippe Marcus, Chromium and tantalum oxide nanocoatings prepared by filtered cathodic arc deposition for corrosion protection of carbon steel. Surf. Coat. Technol. 206, 3903–3910 (2012)

    Article  Google Scholar 

  22. Canan U. Hardwicke, Yuk-Chiu Lau, Advances in thermal spray coatings for gas turbines and energy generation: a review. J. Therm. Spray Technol. 22(5), 564–576 (2013)

    Article  ADS  Google Scholar 

  23. P. Gibot, L. Vidal, Original synthesis of chromium (III) oxide nanoparticles. J. Eur. Ceram. Soc. 30, 911 (2010)

    Article  Google Scholar 

  24. M. Adam Khan, S. Sundarrajan and S. Natarajan, Hot corrosion behaviour of Inconel 617 in Mixed salt environment at 900 and 1000 °C for gas turbine applications. High Temp. Mater. Process. 34(3), 221–225 (2015)

    ADS  Google Scholar 

  25. B. Subramanian, K. Prabakaran, V.V. Anusha Thampi, M. Jayachandran, Electrochemical noise analysis on sputtered chromium nitride coated D9 steels. Int. J. Electrochem. Sci. 8, 12015–12027 (2013)

    Google Scholar 

  26. M.J. Donachie, S.J. Donachie, SUPERALLOYS: A Technical Guide, 2nd edn. (ASM International, Ohio, 2002)

    Google Scholar 

  27. S.D. Cramer, B.S. Covino (eds.), in ASM Handbook. Corrosion: Environments and Industries, vol 13C (ASTM International: Materials Park, Ohio, USA, 2006)

  28. R.C. Reed, The Superalloys Fundamentals and Applications (Cambridge University Press, Cambridge, 2006), pp. 245–283

    Book  Google Scholar 

  29. R.A. Mulford, Grain boundary segregation in Ni and binary Ni alloys doped with sulphur. Metallurgical Transactions 14A, 865–870 (1983)

    Article  ADS  Google Scholar 

  30. J.G. Smeggil, A.W. Funkenbusch, N.S. Bornstein, A relationship between indigenous impurity elements and protective oxide scale adherence characteristics. Metall. Trans. 17A, 923–932 (1986)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Adam Khan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Khan, M.A. Electrochemical polarisation studies on plasma-sprayed nickel-based superalloy. Appl. Phys. A 120, 801–808 (2015). https://doi.org/10.1007/s00339-015-9291-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-015-9291-0

Keywords

Navigation