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Efficient exfoliation N-doped graphene from N-containing bamboo-like carbon nanotubes for anode materials of Li-ion battery and Na-ion battery

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Abstract

Nanosize N-doped graphene is prepared from N-containing carbon nanotubes (CNTs) by chemical exfoliation. The CNTs adopted for graphene are characterized by a discontinuous wall that consists of nanosize graphite layers, exhibiting a bamboo-like appearance. Take advantage of this characterization, the most time-consuming process of chemical oxidation that involves intercalation in graphene from CNT has been markedly reduced. The reduction in processing time is attributed to the diffusion distance of chemical oxidation intercalation into nanosize graphite composed of a bamboo-like carbon nanotube (BCNT) wall being far less than that of conventional chemical exfoliation into microsize graphite. The as-prepared nanosize N-doped graphene from BCNTs has shown an excellent electrochemical performance for Li-ion battery and Na-ion battery anode materials.

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Acknowledgments

This work is supported by The National Basic Research Program of China (Grant Nos. 51272176 and 51472180), Key Project of Tianjin Municipal Natural Science Foundation of China (13JCZDJC33900 and 14JCZDJC32200), National Basic Research Program of China (973 Program, 2012CB933600), Tianjin City High School Science and Technology Fund Planning Project (20140310), and the Youth Foundation of Tianjin Normal University (5RL128).

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Authors and Affiliations

  1. Energy and Materials Engineering Center, Institute of Physics and Materials Science, Tianjin Normal University, Extension of Bin Shui West Road 393, Xi Qing District, Tianjin, 300387, People’s Republic of China

    Jian-Min Feng, Lei Dong, Yan Han, Xi-Fei Li & De-Jun Li

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  1. Jian-Min Feng
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  2. Lei Dong
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  3. Yan Han
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Correspondence to De-Jun Li.

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Feng, JM., Dong, L., Han, Y. et al. Efficient exfoliation N-doped graphene from N-containing bamboo-like carbon nanotubes for anode materials of Li-ion battery and Na-ion battery. Appl. Phys. A 120, 471–478 (2015). https://doi.org/10.1007/s00339-015-9245-6

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