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Rapid fabrication and trimming of nanostructured backside reflectors for enhanced optical absorption in a-Si:H solar cells

Abstract

Nanostructured metallic backside reflectors (BSRs) are crucial for enhanced optical absorption in thin-film amorphous silicon solar cells. The structural fabrication based on rapid aluminum (Al) anodization has a potential for roll-to-roll processes, which are promising for low-cost and large-scale fabrication of BSRs. In this regard, the short fabrication time via appropriate choice of acid, acid concentration, temperature, and time-dependent voltage control is very important. In addition, we first demonstrate the trimming of structural height by using conventional Al anodization, so the best pore size of BSRs with the same structural height can be determined. According to integrated external quantum efficiency (IEQE) calculations, the nanostructured BSR with 430-nm pore size shows 51.6 % IEQE improvement compared with the value of the flat BSR. Moreover, it is interesting that the absorption spectra of a-Si:H on nanostructured Al BSRs with and without the 100-nm Ag coating are highly similar even if the optical properties of Al and Ag are different.

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Acknowledgments

The authors acknowledge the assistance of M. Bellettato for solar cell fabrication at IMM CNR-Bologna, Italy, the technical support of D. Wang at Department of Physics and Nanotechnology, Aalborg University, Denmark, and the support by the QUSCOPE center from the Villum foundation. This work was supported by the Danish strategic research council under the project named thin-film solar cell based on nanocrystalline silicon and structured backside reflectors—THINC.

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Correspondence to Yao-Chung Tsao.

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Tsao, YC., Søndergaard, T., Kristensen, P.K. et al. Rapid fabrication and trimming of nanostructured backside reflectors for enhanced optical absorption in a-Si:H solar cells. Appl. Phys. A 120, 417–425 (2015). https://doi.org/10.1007/s00339-015-9205-1

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Keywords

  • Localize Surface Plasmon Resonance
  • External Quantum Efficiency
  • Large Pore Size
  • Citric Acid Solution
  • Phosphoric Acid Solution