Abstract
The crystallization characteristic, electrical, and optical properties of ZnSb-doped Sb3Te thin films have been systematically investigated. The results show that the crystalline phase, grain size, and the preferred orientation are influenced by ZnSb addition. Meanwhile, ZnSb doping can effectively increase the thermal stability of Sb3Te films such as crystallization temperature and crystallization activation energy, and maintain fast crystallization speed. Among ZnSb-doped Sb3Te films, Zn5.3Sb72.7Te22.0 film exhibits both shorter complete crystallization time (135 ns at 70 mW) and appropriate thermal stability (keeping the amorphous state at 107.2 °C for 10 years).
References
N. Yamada, E. Ohno, K. Nishiuchi, N. Akahira, M. Takao, J. Appl. Phys. 69, 2849 (1991)
F. Wei, L. Wang, T. Kong, L. Shi, R. Huang, J. Zhang, G. Cheng, Appl. Phys. Lett. 103, 181908 (2013)
J.-H. Seo, K.-H. Song, H.-Y. Lee, J. Appl. Phys. 108, 064515 (2010)
J. Fu, X. Shen, Q. Nie, G. Wang, L. Wu, S. Dai, T. Xu, R.P. Wang, Appl. Surf. Sci. 264, 269–272 (2013)
L. Tong, L. Xu, Y. Jiang, F. Yang, L. Geng, J. Xu, W. Su, Z. Ma, K. Chen, J. Non Cryst. Solids 358, 2402–2404 (2012)
T. Zhang, Z. Song, B. Liu, S. Feng, B. Chen, Solid State Electron. 51, 950–954 (2007)
M. Zhu, L. Wu, F. Rao, Z. Song, K. Ren, X. Ji, S. Song, D. Yao, S. Feng, Appl. Phys. Lett. 104, 053119 (2014)
S.J. Wei, H.F. Zhu, K. Chen, D. Xu, J. Li, F.X. Gan, X. Zhang, Y.J. Xia, G.H. Li, Appl. Phys. Lett. 98, 231910 (2011)
D. Yao, X. Zhou, L. Wu, Z. Song, L. Cheng, F. Rao, B. Liu, S. Feng, Solid State Electron. 79, 138–141 (2013)
M. Zhu, L. Wu, F. Rao, Z. Song, X. Li, C. Peng, X. Zhou, K. Ren, D. Yao, S. Feng, J. Alloys Compd. 509, 10105–10109 (2011)
M.H. Jang, S.J. Park, D.H. Lim, M.H. Cho, K.H. Do, D.H. Ko, H.C. Sohn, Appl. Phys. Lett. 95, 012102 (2009)
G. Wang, Q. Nie, X. Shen, R.P. Wang, L. Wu, J. Fu, T. Xu, S. Dai, Appl. Phys. Lett. 101, 051906 (2012)
X. Shen, G. Wang, R.P. Wang, S. Dai, L. Wu, Y. Chen, T. Xu, Q. Nie, Appl. Phys. Lett. 102, 131902 (2013)
Y. Chen, G. Wang, X. Shen, T. Xu, R.P. Wang, L. Wu, Y. Lu, J. Li, S. Dai, Q. Nie, Cryst. Eng. Comm. 16, 757 (2014)
M. Wuttig, C. Steimer, Phase change materials: from material science to novel storage devices. Appl. Phys. A 87, 411–417 (2007)
T.J. Park, S.J. Park, D.H. Kim, I.S. Kim, S.K. Kim, S.Y. Choi, Curr. Appl. Phys. 8, 716–719 (2008)
Acknowledgments
This work was financially supported by the National Program on Key Basic Research Project (973 Program) (Grant No. 2012CB722703), the Natural Science Foundation of China (Grant No. 61306147), the Key Program for International S&T Cooperation Projects of China (Grant No. 2001DFA12040), the Young Leaders of academic climbing project of the Education Department of Zhejiang Province (pd2013092).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shen, X., Chen, Y., Wang, Z. et al. Improved phase change behavior of Sb3Te material by ZnSb doping for phase change memory. Appl. Phys. A 119, 425–429 (2015). https://doi.org/10.1007/s00339-014-8938-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-014-8938-6