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Hydrothermal synthesis of hierarchical WO3 nanostructures for dye-sensitized solar cells

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Abstract

Hierarchical architectures consisting of one-dimensional (1D) nanostructures are of great interest for potential use in energy and environmental applications in recent years. In this work, hierarchical tungsten oxide (WO3) has been synthesized via a facile hydrothermal route from ammonium metatungstate hydrate and implemented as photoelectrode for dye-sensitized solar cells. The urchin-like WO3 micro-patterns are constructed by self-organized nanoscale length 1D building blocks, which are single crystalline in nature, grown along (001) direction and confirm an orthorhombic crystal phase. The obtained powders were investigated by XRD, SEM, TEM and UV–Vis Spectroscopy. The photovoltaic performance of dye-sensitized solar cells based on WO3 photoanodes was investigated. With increasing the calcination temperature of the prepared nanopowders, the light-electricity conversion efficiency (η) was increased. The results were attributed to increase the crystallinity of the particles and ease of electron movement. The DSSC based on hierarchical WO3 showed a short-circuit current, an open-circuit voltage, a fill factor, and a conversion efficiency of 4.241 mA/cm2, 0.656 V, 66.74, and 1.85 %, respectively.

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References

  1. B. Oregan, M. Gratzel, Nature 353, 737 (1991)

    Article  ADS  Google Scholar 

  2. A.E. Shalan, M.M. Rashad, Y. Yu, M. Lira-Cantu, M.S.A. Abdel-Mottaleb, Electrochim. Acta 89, 469 (2013)

    Article  Google Scholar 

  3. M.M. Rashad, A.E. Shalan, M. Lira-Cantu, M.S.A. Abdel-Mottaleb, J. Ind. Eng. Chem. 19, 2052 (2013)

    Google Scholar 

  4. A.E. Shalan, M.M. Rashad, Appl. Surf. Sci. 283, 975 (2013)

    Article  ADS  Google Scholar 

  5. A. Yella, H.-W. Lee, H.N. Tsao, C. Yi, A.K. Chandiran, M.K. Nazeeruddin, E.W.-G. Diau, C.-Y. Yeh, S.M. Zakeeruddin, M. Grätzel, Science 334, 629 (2011)

    Article  ADS  Google Scholar 

  6. N. Memarian, I. Concina, A. Braga, S.M. Rozati, A. Vomiero, G. Sberveglieri, Angew. Chem. Int. Ed. 50, 12321 (2011)

    Article  Google Scholar 

  7. K. Sayama, H. Sugihara, H. Arakawa, Chem. Mater. 10, 3825 (1998)

    Article  Google Scholar 

  8. J. Bandara, H.C. Weerasinghe, Sol. Energy Mater. Sol. Cells 88, 341 (2005)

    Article  Google Scholar 

  9. F. Lenzmann, J. Krueger, S. Burnside, K. Brooks, M. Gratzel, D. Gal, S. Rauhle, D. Cahen, J. Phys. Chem. B 105, 6347 (2001)

    Article  Google Scholar 

  10. R.A. Dixon, J.J. Williams, D. Morris, J. Rebane, F.H. Jones, R.G. Egdell, S.W. Downes, Surf. Sci. 399, 199 (1998)

    Article  ADS  Google Scholar 

  11. E. Washizu, A. Yamamoto, Y. Abe, M. Kawamura, K. Sasaki, Solid State Ionics 165, 175 (2003)

    Article  Google Scholar 

  12. L. Weinhardt, M. Blum, M. Bar, C. Heske, B. Cole, B. Marsen, E.L. Miller, J. Phys. Chem. C 112, 3078 (2008)

    Article  Google Scholar 

  13. F.G. Wang, C. Di Valentin, G. Pacchioni, Chemcatchem 4, 476 (2012)

    Article  Google Scholar 

  14. S.K. Deb, Sol. Energy Mater. Sol. Cells 92, 245 (2008)

    Article  Google Scholar 

  15. S.J. Yoo, Y.H. Jung, J.W. Lim, H.G. Choi, D.K. Kim, Y.E. Sung, Sol. Energy Mater. Sol. Cells 92, 179 (2008)

    Article  Google Scholar 

  16. H.S. Shim, J.W. Kim, Y.E. Sung, W.B. Kim, Sol. Energy Mater. Sol. Cells 93, 2062 (2009)

    Article  Google Scholar 

  17. S.M. Yong, T. Nikolay, B.T. Ahn, D.K. Kim, J. Alloys Comp. 547, 113 (2013)

    Article  Google Scholar 

  18. X.L. Li, T.J. Lou, X.M. Sun, Y.D. Li, Inorg. Chem. 43, 5442 (2004)

    Article  Google Scholar 

  19. J.H. Ha, P. Muralidharan, D.K. Kim, J. Alloys Comp. 475, 446 (2009)

    Article  Google Scholar 

  20. M.M. Rashad, E.M. Elsayed, M.S. Al-Kotb, A.E. Shalan, J. Alloys Comp. 581, 71 (2013)

    Article  Google Scholar 

  21. A.E. Shalan, M.M. Rashad, Y. Yu, M. Lira-Cantu, M.S.A. Abdel-Mottaleb, Appl. Phys. A 110, 111 (2013)

    Google Scholar 

  22. J. Li, J. Huang, C. Yu, J. Wu, L. Cao, K. Yanagisawa, Chem. Lett. 40, 579 (2011)

    Article  Google Scholar 

  23. B.S. Liu, X.J. Zhao, Q.N. Zhao, X. He, J.Y. Feng, J. Electron Spectrosc. Relat. Phenom. 148, 158 (2005)

    Article  Google Scholar 

  24. Z.-D. Meng, L. Zhu, J.-G. Choi, C.-Y. Park, W.-C. Oh, Nanoscale Res. Lett. 6, 459 (2011)

    Article  ADS  Google Scholar 

  25. M.M. Rashad, A.E. Shalan, J. Mater. Sci.: Mater. Electron. 24, 3189 (2013)

    Google Scholar 

  26. J.S. Im, S.K. Lee, Y.S. Lee, Appl. Surf. Sci. 257, 2164 (2011)

    Article  ADS  Google Scholar 

  27. Y.N. Xia, P.D. Yang, Y.G. Sun, Y.Y. Wu, B. Mayers, B. Gates, Y.D. Yin, F. Kim, Y.Q. Yan, Adv. Mater. 15, 353 (2003)

    Article  Google Scholar 

  28. D.K. Kim, P. Muralidharan, H.W. Lee, R. Ruffo, Y. Yang, C.K. Chan, H. Peng, R.A. Huggins, Y. Cui, Nano Lett. 8, 3948 (2008)

    Article  ADS  Google Scholar 

  29. S.M. Yong, P. Muralidharan, S.H. Jo, D.K. Kim, Mater. Lett. 64, 1551 (2010)

    Article  Google Scholar 

  30. A. Hagfeldt, G. Boschloo, L.C. Sun, L. Kloo, H. Pettersson, Chem. Rev. 110, 6595 (2010)

    Article  Google Scholar 

  31. A. Annamalai, Y.D. Eo, C. Im, M.J. Lee, Mater. Charact. 62, 1007 (2011)

    Article  Google Scholar 

  32. M. Anik, T. Cansizoglu, J. Appl. Electrochem. 36, 603 (2006)

    Article  Google Scholar 

  33. H.D. Zheng, Y. Tachibana, K. Kalantar-zadeh, Langmuir 26, 19148 (2010)

    Article  Google Scholar 

  34. M.M. Rashad, A.E. Shalan, L.-C. Monica, M.S.A. Abdel-Mottaleb, Appl Nanosci 3, 167 (2013)

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Central Metallurgical Research and Development Institute (CMRDI), Helwan, P.O. Box 87, Cairo, Egypt

    M. M. Rashad & A. E. Shalan

  2. Institute of Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-University of Erlangen-Nuremberg, Martensstraße 7, 91058, Erlangen, Germany

    A. E. Shalan

Authors
  1. M. M. Rashad
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  2. A. E. Shalan
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Correspondence to M. M. Rashad.

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Rashad, M.M., Shalan, A.E. Hydrothermal synthesis of hierarchical WO3 nanostructures for dye-sensitized solar cells. Appl. Phys. A 116, 781–788 (2014). https://doi.org/10.1007/s00339-013-8148-7

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  • DOI: https://doi.org/10.1007/s00339-013-8148-7

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