Applied Physics A

, Volume 111, Issue 1, pp 91–97 | Cite as

Medieval glass from the Cathedral in Paderborn: a comparative study using X-ray absorption spectroscopy, X-ray fluorescence, and inductively coupled laser ablation mass spectrometry

  • J. Hormes
  • A. Roy
  • G.-L. Bovenkamp
  • K. Simon
  • C.-Y. Kim
  • N. Börste
  • S. Gai
Invited paper

Abstract

We have investigated four stained glass samples recovered from an archaeological excavation at the Cathedral in Paderborn (Germany) between 1978 and 1980. On two of the samples there are parts of paintings. Concentrations of major elements were determined using two independent techniques: LA–ICP–MS (a UV laser ablation microsampler combined with an inductively coupled plasma mass spectrometer) and synchrotron radiation X-ray excited X-ray fluorescence (SR-XRF). The SR-XRF data were quantified by using the program package PyMCA developed by the software group of the ESRF in Grenoble. Significant differences were found between the concentrations determined by the two techniques that can be explained by concentration gradients near the surface of the glasses caused, for example, by corrosion/leaching processes and the different surface sensitivities of the applied techniques. For several of the elements that were detected in the glass and in the colour pigments used for the paintings X-ray absorption near edge structure (XANES) spectra were recorded in order to determine the chemical speciation of the elements of interest. As was expected, most elements in the glass were found as oxides in their most stable form. Two notable exceptions were observed: titanium was not found as rutile—the most stable form of TiO2—but in the form of anatase, and lead was not found in one defined chemical state but as a complex mixture of oxide, sulphate, and other compounds.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2013

Authors and Affiliations

  • J. Hormes
    • 1
    • 2
  • A. Roy
    • 2
  • G.-L. Bovenkamp
    • 2
  • K. Simon
    • 3
  • C.-Y. Kim
    • 1
  • N. Börste
    • 4
  • S. Gai
    • 5
  1. 1.Canadian Light Source Inc.University of SaskatchewanSaskatoonCanada
  2. 2.CAMDLouisiana State UniversityBaton RougeUSA
  3. 3.Geochemistry, Centre for GeosciencesUniversity of GöttingenGöttingenGermany
  4. 4.Faculty for Theology PaderbornPaderbornGermany
  5. 5.LWL—Archäologie für WestfalenMünsterGermany

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